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ADZ Laboratories, Inc. • • - • - • <br /> 2773 Downhill Drive Steamboat Springs, CO 80487 (800)334-5493 - • • <br /> Ensero Solutions ACZ Project ID: L71577 <br /> METHODACZ ID WORKNUM PARAMETER QUAL DESCRIPTION <br /> L71577.01 NG537399 Cyanide,WAD SM4500-CN I,E-Colorimetric wl RA Relative Percent Difference(RPD)was not used for data <br /> distillation validation because the concentration of the duplicated <br /> sample is too low for accurate evaluation(<10x MDL). <br /> WG538012 Nitrate/Nitrite as N M353 2-H2SO4 preserved RA Relative Percent Difference(RPD)was not used for data <br /> validation because the concentration of the duplicated <br /> sample is too low for accurate evaluation(<lox MDL) <br /> WG537423 Phosphorus,total M365 1-Auto Ascorbic Acid RA Relative Percent Difference(RPD)was not used for data <br /> (digest) validation because the concentration of the duplicated <br /> sample is too low for accurate evaluation(<lox MDL). <br /> WG537195 Residue,Non-Fifterable(TSS)@105C SM2540D RA Relative Percent Difference(RPD)was not used for data <br /> validation because the concentration of the duplicated <br /> sample is too low for accurate evaluation(<lox MDL). <br /> SM2540D Z3 Sample volume yielded a residue less than 2 5 mg <br /> WG538118 Sulfate D516-02/-07/-11- M2 Matrix spike recovery was low,the recovery of the <br /> TURBIDIMETRIC associated control sample(I-CS or LFB)was acceptable <br /> WG537643 Total Hot Plate Digestion M200 2 ICP OA Sample container with preservation type specified by the <br /> method was not available for analysis. Altemate sample <br /> container was used. <br /> WG537403 Total Recoverable Digestion M200 2 ICP-MS DJ Sample dilution required due to insufficient sample. <br /> L71577-02 NG537399 Cyanide,WAD SM4500-CN I,E-Colonmetric w/ RA Relative Percent Difference(RPD)was not used for data <br /> distillation validation because the concentration of the duplicated <br /> sample is too low for accurate evaluation(<lox MDL) <br /> WG538012 Nftrate/Ndrde as N M353 2-H2SO4 preserved RA Relative Percent Difference(RPD)was not used for data <br /> validation because the concentration of the duplicated <br /> sample is too low for accurate evaluation(<lox MDL). <br /> WG537423 Phosphorus,total M365.1-Auto Ascorbic Acid RA Relative Percent Difference(RPD)was not used for data <br /> (digest) validation because the concentration of the duplicated <br /> sample is too low for accurate evaluation(<1 Ox MDL) <br /> WG537195 Residue,Non-Fifterable(TSS)@105C SM2540D RA Relative Percent Difference(RPD)was not used for data <br /> validation because the concentration of the duplicated <br /> sample is too low for accurate evaluation(<lox MDL). <br /> SM2540D Z3 Sample volume yielded a residue less than 2 5 mg <br /> WG537570 Silver,dissolved M200 8 ICP-MS RF Relative Percent Difference(RPD)for Ag in spiked samples <br /> exceeded limit In the absence of HCI,precipitation of Ag <br /> may occur at different rates <br /> WG538118 Sulfate D516-02/-07/-11- M2 Matrix spike recovery was low,the recovery of the <br /> TURBIDIMETRIC associated control sample(I-CS or LFB)was acceptable. <br /> RE PAD.15.06.05.01 <br /> L71577-2204201449 Page 12 of 22 <br />