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Carbon dioxide, refrigerated liquid IR Safety Data Sheet P-4573 Making ourplanetmorepToductive' This SIDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. Date of issue:01/01/1997 Revision date: 10/13/2016 Supersedes: 12/18/2014 classification Contact with liquid may cause cold burns/frostbite. 2.4. Unknown acute toxicity(GHS US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Name Product identifier % Carbon dioxide,refrigerated liquid (CAS No) 124-38-9 100 (Main constituent) 3.2. Mixture Not applicable SECTION • measures 4.1. Description of first aid measures First-aid measures after inhalation Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep victim warm and rested. Call a doctor.Apply artificial respiration if breathing stopped. First-aid measures after skin contact The liquid may cause frostbite. For exposure to liquid,immediately warm frostbite area with warm water not to exceed 105°F(41°C). Water temperature should be tolerable to normal skin. Maintain skin warming for at least 15 minutes or until normal coloring and sensation have returned to the affected area. In case of massive exposure, remove clothing while showering with warm water. Seek medical evaluation and treatment as soon as possible. First-aid measures after eye contact Immediately flush eyes thoroughly with water for at least 15 minutes. Hold the eyelids open and away from the eyeballs to ensure that all surfaces are flushed thoroughly. Contact an ophthalmologist immediately.. Get immediate medical attention. First-aid measures after ingestion Ingestion is not considered a potential route of exposure. 4.2. Most important symptoms and effects, both acute and delayea No additional information available 4.3. Indication of any immediate medical attention and special treatment needed None. SECTION 5.1. Extinguishing media Suitable extinguishing media Use extinguishing media appropriate for surrounding fire. 5.2. Special hazards arising from the substance or mixture Reactivity No reactivity hazard other than the effects described in sub-sections below. 5.3. Advice for firefighters Firefighting instructions DANGER! Extremely cold liquid and gas under pressure. Take care not to direct spray onto vents on top of container. Do not discharge sprays directly into liquid;cryogenic liquid can freeze water rapidly Evacuate all personnel from the danger area. Use self-contained breathing apparatus(SCBA) and protective clothing. Immediately cool containers with water from maximum distance. Stop flow of gas if safe to do so,while continuing cooling water spray. Remove ignition sources if safe to do so. Remove containers from area of fire if safe to do so. On-site fire brigades must comply with OSHA 29 CFR 1910.156 and applicable standards under 29 CFR 1910 Subpart L—Fire Protection. Protection during firefighting Compressed gas:asphyxiant. Suffocation hazard by lack of oxygen. Special protective equipment for fire fighters Use self-contained breathing apparatus.Standard protective clothing and equipment(Self Contained Breathing Apparatus)for fire fighters. Specific methods Stop flow of product if safe to do so. Use fire control measures appropriate for the surrounding fire. Exposure to fire and heat radiation may cause gas containers to rupture. Cool endangered containers with water spray jet from a protected position. Prevent water used in emergency cases from entering sewers and drainage systems. Use water spray or fog to knock down fire fumes if possible. If leaking do not spray water onto container.Water surrounding area(from protected position)to contain fire. Exposure to fire may cause containers to rupture/explode. EN(English US) SIDS ID: P-4573 2/9 This document is only controlled while on the Praxair,Inc.website and a copy of this controlled version is available for download.Praxair cannot assure the integrity or accuracy of any version of this document after it has been downloaded or removed from our website.