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2021-05-18_HYDROLOGY - C1981019
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2021-05-18_HYDROLOGY - C1981019
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Last modified
5/19/2021 11:03:49 AM
Creation date
5/19/2021 5:59:02 AM
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Template:
DRMS Permit Index
Permit No
C1981019
IBM Index Class Name
Hydrology
Doc Date
5/18/2021
Doc Name
Correspondence
From
Tri-State Generation and Transmission Association, Inc.
To
DRMS
Email Name
ZTT
JDM
Media Type
D
Archive
No
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DocuSign Envelope ID: D07924E6-3D94-4398-AO66-B683COBAB33E <br /> February 24,2021 <br /> Angela Aalbers,Chantell Johnson <br /> Page 12 of 12 <br /> Reference: Biological Sulfate Reduction Bench-Scale Test Results-Revision 1 <br /> a reduction in overall TDS. The biological sulfate reduction process essentially exchanges sulfate ions for <br /> carbonate ions. Observations during testing of white sediment in the treated effluents further support calcite <br /> supersaturation as a potential toxicant. <br /> The calcite oversaturation toxicity theory is based on Langelier Saturation Index(LSI) calculations which <br /> indicate that calcite will precipitate from BSR effluent overtime. Calcite precipitation is known to be toxic in <br /> WET testing due to scale formation on the test species. Toxicity due to calcite precipitation is the subject of <br /> research currently being conducted in western Canada. However, despite identifying these two potential <br /> toxicity sources, the two supplemental treatment approaches to reduce the overall calcite saturation level <br /> have not produced satisfactory results. The complete Whole Effluent Toxicity Testing Report performed by <br /> GEI Consultants is included as Attachment 3. <br /> RECOMMENDATIONS <br /> It is evident from these bench-scale test results that the passive BSR treatment is not sufficient to treat the <br /> mine water to an acceptable level. It is reasonable to conclude that the reduction of sulfate concentrations <br /> and/or calcite saturation does not adequately reduce toxicity. Reduction of TDS requires an active treatment <br /> approach. <br /> At present, the only treatment technology evaluated that passes WET testing is membrane separation <br /> (reverse osmosis or nanofiltration) as indicated by the TIE. In addition, deep-well injection, which would not <br /> discharge to the permitted outfall, is another approach that has been independently evaluated. Blending of <br /> these two approaches, membrane separation and brine discharge by deep-well injection would allow for a <br /> 75% recovery of the treated water(to be returned to the environment), thus requiring a smaller discharge well. <br /> This approach would eliminate the brine evaporation pond which was a requirement in the previous THE <br /> evaluation. The evaporation pond for brine management is considered to be a labor-intensive activity to <br /> maintain and operate. If the deep well injection is approved, either of these approaches can be pursued <br /> without the requirement of an additional WET test evaluation. <br /> An alternative approach for TDS reduction would be ettringite precipitation. This approach has been <br /> extensively evaluated by Freeport McMoRan in conjunction with a technology company located in Pueblo, <br /> CO. This process uses pH adjustments and elemental aluminum metal as the primary treatment method with <br /> published results indicating reduction between 60-90% depending on the rate of aluminum dosing. This <br /> approach is still considered experimental and is also an active treatment system. <br /> Desic th community in mir <br /> dpg llus0321-ppfss01lshared_projects\233001407\reports\6_bench_scale_report\rpLbench_scale_report_24feb2O20_final_rl.docx <br />
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