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ACZ Laboratories, Inc. <br />2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 <br />Inorganic Extended <br />Qualifier Report <br />ACZ Project ID:L64861ARCADIS <br />ACZ ID PARAMETER QUAL DESCRIPTIONMETHODWORKNUM <br />M3 The spike recovery value is unusable since the analyte <br />concentration in the sample is disproportionate to the spike <br />level. The recovery of the associated control sample (LCS <br />or LFB) was acceptable. <br />M200.7 ICPIron, totalWG5163541L64861-01 <br />MA Recovery for either the spike or spike duplicate was outside <br />of the acceptance limits; the RPD was within the <br />acceptance limits. <br />M200.7 ICPManganese, dissolvedWG516365 <br />RA Relative Percent Difference (RPD) was not used for data <br />validation because the concentration of the duplicated <br />sample is too low for accurate evaluation (< 10x MDL). <br />SM2540DResidue, Non-Filterable (TSS) @105CWG516298 <br />M3 The spike recovery value is unusable since the analyte <br />concentration in the sample is disproportionate to the spike <br />level. The recovery of the associated control sample (LCS <br />or LFB) was acceptable. <br />D516-02/-07/-11 - TurbidimetricSulfateWG517016 <br />DF Sample required dilution due to high sediment.M200.2 ICPTotal Hot Plate DigestionWG516268 <br />M3 The spike recovery value is unusable since the analyte <br />concentration in the sample is disproportionate to the spike <br />level. The recovery of the associated control sample (LCS <br />or LFB) was acceptable. <br />M200.7 ICPIron, totalWG5163542L64861-02 <br />MA Recovery for either the spike or spike duplicate was outside <br />of the acceptance limits; the RPD was within the <br />acceptance limits. <br />M200.7 ICPManganese, dissolvedWG516365 <br />RA Relative Percent Difference (RPD) was not used for data <br />validation because the concentration of the duplicated <br />sample is too low for accurate evaluation (< 10x MDL). <br />SM2540DResidue, Non-Filterable (TSS) @105CWG516298 <br />M3 The spike recovery value is unusable since the analyte <br />concentration in the sample is disproportionate to the spike <br />level. The recovery of the associated control sample (LCS <br />or LFB) was acceptable. <br />D516-02/-07/-11 - TurbidimetricSulfateWG517016 <br />DF Sample required dilution due to high sediment.M200.2 ICPTotal Hot Plate DigestionWG516268 <br />M3 The spike recovery value is unusable since the analyte <br />concentration in the sample is disproportionate to the spike <br />level. The recovery of the associated control sample (LCS <br />or LFB) was acceptable. <br />M200.7 ICPIron, totalWG5163543L64861-03 <br />MA Recovery for either the spike or spike duplicate was outside <br />of the acceptance limits; the RPD was within the <br />acceptance limits. <br />M200.7 ICPManganese, dissolvedWG516365 <br />RA Relative Percent Difference (RPD) was not used for data <br />validation because the concentration of the duplicated <br />sample is too low for accurate evaluation (< 10x MDL). <br />SM2540DResidue, Non-Filterable (TSS) @105CWG516298 <br />M3 The spike recovery value is unusable since the analyte <br />concentration in the sample is disproportionate to the spike <br />level. The recovery of the associated control sample (LCS <br />or LFB) was acceptable. <br />D516-02/-07/-11 - TurbidimetricSulfateWG517016 <br />DF Sample required dilution due to high sediment.M200.2 ICPTotal Hot Plate DigestionWG516268 <br />MA Recovery for either the spike or spike duplicate was outside <br />of the acceptance limits; the RPD was within the <br />acceptance limits. <br />M200.7 ICPManganese, dissolvedWG5163654L64861-04 <br />RA Relative Percent Difference (RPD) was not used for data <br />validation because the concentration of the duplicated <br />sample is too low for accurate evaluation (< 10x MDL). <br />SM2540DResidue, Non-Filterable (TSS) @105CWG516298 <br />M3 The spike recovery value is unusable since the analyte <br />concentration in the sample is disproportionate to the spike <br />level. The recovery of the associated control sample (LCS <br />or LFB) was acceptable. <br />D516-02/-07/-11 - TurbidimetricSulfateWG517016 <br />REPAD.15.06.05.01 <br />Page 9 of 14L64861-2104081104