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Title: Sampling and Analysis Plan for Environmental Control Number: Revision Date: Page 27 of 30 <br /> Groundwater Monitoring PUE.EN.D.026.04 2/19/2020 <br /> Tide: GCC Rio Grande Pueblo Plant Groundwater Control Number: Revision Date: <br /> Monitoring Well Compliance Sampling PUE.EN.P.003.01 2/1812020 Page 3 of 4 <br /> Alternatively,the labeling may be made by writing directly on the bottles. Information shall <br /> include: <br /> • Site or project name(GCC Rio Grande) <br /> • Sample ID <br /> • Sample collection date and time <br /> • Sampler's initials <br /> c) Bail to fill at least %the 1-gallon new, disposable poly cubitainer, which is the sample <br /> transfer container to be used for this groundwater bailer sample collection methodology. <br /> d) Load the 3/8" peristaltic tubing through the peristaltic pump head unit per manufacturer's <br /> instructions, keeping both tubing ends from touching any contaminating materials. <br /> e) Insert one end of the 3/8" peristaltic pump tubing into the cubitainer, keeping this suction <br /> end submerged. <br /> f) Attach the inlet side of the 0.45 pm filter(observe flow arrow on filter)to the other end of <br /> the peristaltic pump tubing. <br /> g) Operate the peristaltic pump per manufacturer's instructions producing water to flush air <br /> from the 0.45 pm filter and fill with sample water until the filter is producing water. Confirm <br /> there are no visible particulates flowing in the water from the filter outlet. <br /> h) Fill the 125 ml poly preserved bottle to the bottleneck and cap immediately. There is acid <br /> preservative in this container. Do not over-fill or spill the preservative—if this does happen <br /> then take a replacement 125 ml poly preserved bottle from a spare bottle set and repeat <br /> fill procedure. <br /> i) Fill the 250 ml poly unpreserved bottle from the 0.45 pm filter outlet to the bottleneck and <br /> cap immediately. <br /> j) Stop the peristaltic pump and remove the tubing from the cubitainer. <br /> k) Fill the 500 ml poly unpreserved bottle to the neck directly from the cubitainer and <br /> immediately cap. <br /> 1) Label each bottle with actual the sample time, coordinated with the final logged water <br /> quality field parameters readings. <br /> m) IF AT ANY POINT A BOTTLE CAP GETS DROPPED ON THE GROUND, RAINED ON, <br /> ETC.—simply triple rinse the cap(inside and out)with excess sample water from the bailer <br /> to decontaminate. Bail more water if necessary. Confirm no debris is on the cap and then <br /> screw it onto the bottle. If the cap is dropped into a known or suspected contaminant,then <br /> do not take a chance and simply replace the contaminated cap from a bottle from a spare <br /> bottle set. <br /> 11)Collect QAIQC field duplicate sample <br /> a) For each quarterly compliance groundwater monitoring event(up to 10 monitoring locations <br /> to meet 10% minimum QA/QC standard), one randomly selected, blind duplicate sample <br /> shall be collected and submitted for laboratory analysis by the"GW-Compliance"suite. <br /> b) Fill the bottles for the duplicate sample in sequence of the"normal" sample that is being <br /> duplicated by using the procedure instep 10. Batching is recommended for efficiency with <br /> field-filtered samples. <br /> c) Name the sample a unique ID(to make the sample ID is"blind"from the lab)and assign it <br /> a time +/- one hour of the duplicated sample collection time, also to aid in keeping the <br /> sample identification blind from the lab. <br /> 12) Rig down sampling equipment <br /> a) Reel up WLI and decontaminate probe and tape exposed to water with Liquinox solution <br /> spray and spray-rinse with distilled water. <br /> b) Place used bailer and cord, 0.45 pm filter, tubing, cubitainer and miscellaneous <br /> consumables into a trash bag for appropriate disposal. <br /> c) Decontaminate multi-parameter water quality meter probes by spraying with Liquinox <br /> solution followed by spraying with distilled water until no suds remain. Prepare meter <br /> probes for long-term storage per manufacturer's instructions. <br /> 13) Prep sample for submittal to analytical lab <br />