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Demonstration of Compliance Climax Molybdenum Company <br /> With Regulation 41 Permit M-1977-493 <br /> values, conditions are not allowed to deteriorate. The use of the entire data set from these wells <br /> considers the variability in observed concentrations over time in determining representative <br /> ambient quality. Furthermore, the available information (both water quality data and the <br /> operational and reclamation history) indicates that there have been no new or increased sources <br /> of groundwater contamination initiated subsequent to that date. In particular,the restart of Climax <br /> mining and milling activities in 2012 did not introduce a new or increased source of groundwater <br /> contamination in the Arkansas River Basin, as verified by the data trends in ARwell. <br /> 3.2.2 Ambient-Based Manganese and pH Values for ARwell <br /> Monitoring of ARwell began with four consecutive quarters of data from September 1993 through <br /> September 1994. Monitoring was suspended following the initial year of sampling, but resumed <br /> again in February 1997, and continued generally on a quarterly basis since then. All data were <br /> considered in establishing ambient quality. Compliance with Regulation 41 should therefore be <br /> based on consideration of all data collected over the period of record because the entire data set <br /> considers the full range of variability over the period of generally improving water quality in <br /> establishing an appropriately conservative estimation of ambient groundwater quality as of <br /> January 31, 1994. Based on the manganese and pH data available and the evidence that <br /> groundwater quality has improved over time, these data are appropriate for use in determining <br /> existing ambient quality for those parameters as of January 31, 1994, and are protective against <br /> further lowering of groundwater quality. Table 3-1, presents the summary statistics associated <br /> with all manganese and pH data from ARwell. For pH, the mean value represents the log <br /> transformed average of the hydrogen ion concentration (10-P"). The full data set for this well is <br /> included in Appendix B. <br /> Table 3.1: Ambient-Based Manganese and pH Calculations for ARwell <br /> Manganese, Field pH, <br /> Site Number: ARwell Dissolved Standard <br /> (mg/L) Units <br /> Summary Statistics—All data <br /> collected through 3rd Quarter - <br /> 2016 <br /> Number of Analyses 66 76 <br /> Number of Non-Detects 0 0 <br /> minimum 0.016 6.0 <br /> arithmetic mean 0.210 6.9 <br /> maximum 1.320 9.0 <br /> standard deviation(a) 0.201 0.48 <br /> Mean-/+2a 0.612 6.0 - 7.9 <br /> Monitoring data in Appendix B were compared against these values in accordance with Section <br /> 5.2.1 of the WQMP; maintaining manganese and pH at these levels would be in compliance with <br /> Regulation 41. <br /> December 2016 8 <br />