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I iV <br /> ACZ Laboratories, Inc. ® I <br /> 2773 Downhill Drive Steamboat Springs, CO 80487 (800)334-5493 <br /> Rio Grande Silver, Inc. ACZ Project ID: L26557 <br /> Alkalinity as CaCO3 SM2320B-Titration <br /> ACZ • Qc Sample Found Units Rec Lower Upper RPD Limit Qua[ <br /> WG390634 <br /> WG390634PBW1 PBW 09/17/1517:00 U mg/L -20 20 <br /> WG390634LCSW3 LCSW 09/17/1517:17 WC150908-15 820 807 mg/L 98 90 110 <br /> WG390634LCSW6 LCSW 09/17/15 20:37 WC150908-15 820 811 mg/L 99 90 110 <br /> WG390634PBW2 PBW 09/17/15 20:44 U mg/L -20 20 <br /> L26542-13DUP DUP 09/17/15 22:41 346 346 mg/L 0 20 <br /> WG390634LCSW9 LCSW 09/18/151:11 WC150908-15 820 799 mg/L 97 90 110 <br /> WG390634PBW3 PBW 09/18/151:19 U mg/L -20 20 <br /> WG390634LCSW12 LCSW 09/18/15 8:53 WC150908-15 820 826 mg/L 101 90 110 <br /> WG390634PBW4 PBW 09/18/15 9:01 U mg/L -20 20 <br /> WG390634LCSW15 LCSW 09/18/1512:23 WC150908-15 820 825 mg/L 101 90 110 <br /> Aluminum,dissolved M200.7 ICP <br /> ACZ ID-;--- Type Analyzed PCNISCN ac -Sample Fou- Rec Lower Upper RPD- Limit ou-al <br /> WG390711 <br /> WG3907111CV ICV 09/1811512:41 11150908-1 2 1.989 mg/L 99 95 105 <br /> WG390711ICB ICB 09/18/1512:47 U mg/L -0.09 0.09 <br /> WG390711PQV PQV 09/18/1512:51 11150818-3 .150225 .152 mg/L 101 70 130 <br /> WG390711SIC SIC 09/18/1512:54 11150725-2 200.450225 207.5 mg/L 104 1 200 <br /> WG390711LFB LFB 09/1811513:00 11150917-2 1.0015 1.018 mg/L 102 85 115 <br /> WG390711CCV1 CCV 09/18/1513:31 11150908-2 1 .94 mg/L 94 90 110 <br /> WG390711CCB1 CCB 09/18/1513:34 U mg/L -0.09 0.09 <br /> WG390711CCV2 CCV 09/18/1514:07 11150908-2 1 .945 mg/L 95 90 110 <br /> WG390711CCB2 CCB 09/18/1514:10 U mg/L -0.09 0.09 <br /> L26530-01AS AS 09/18/1514:14 11150917-2 5.0075 2.4 7.4 mg/L 100 85 115 <br /> L26530-01ASD ASD 09/18/1514:17 11150917-2 5.0075 2.4 7.45 mg/L 101 85 115 1 20 <br /> WG390711CCV3 CCV 09/18/1514:29 11150908-2 1 .95 mg/L 95 90 110 <br /> WG390711CCB3 CCB 09/18/1514:32 U mg/L -0.09 0.09 <br /> Aluminum,total recoverable M200.7 ICP <br /> • e -• <br /> WG390371 <br /> WG3903711CV ICV 09/15/1510:20 11150908-1 2 1.982 mg/L 99 95 105 <br /> WG390371ICB ICB 09/15/1510:26 U mg/L -0.09 0.09 <br /> WG390371PQV PQV 09/1511510:29 11150818-3 .150225 .161 mg/L 107 70 130 <br /> WG390371SIC SIC 09/15/1510:32 11150725-2 200.450225 206.3 mg/L 103 1 200 <br /> WG390294LRB LRB 09/15/1510:41 U mg/L -0.066 0.066 <br /> WG390294LFB LFB 09/15/1510:44 11150901-3 1.0015 1.027 mg/L 103 85 115 <br /> WG390371CCV1 CCV 09/15/1511:09 11150908-2 1 .965 mg/L 97 90 110 <br /> WG390371CCB1 CCB 09/15/1511:12 U mg/L -0.09 0.09 <br /> WG390371CCV2 CCV 09/15/1511:45 11150908-2 1 .967 mg/L 97 90 110 <br /> WG390371CCB2 CCB 09/15/1511:49 U mg/L -0.09 0.09 <br /> L26577-01LFM LFM 09/15/1512:07 11150901-3 1.0015 .07 1.128 mg/L 106 70 130 <br /> L26577-01LFMD LFMD 09/15/1512:10 11150901-3 1.0015 .07 1.089 mg/L 102 70 130 4 20 <br /> WG390371CCV3 CCV 09/15/1512:13 11150908-2 1 .975 mg/L 98 90 110 <br /> WG390371CCB3 CCB 09/15/1512:16 U mg/L -0.09 0.09 <br /> L26557-1510011525 Page 13 of 48 <br />