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AraZ Laboratories, Inc. • • - - • - • <br /> 2773 Downhill Drive Steamboat Springs, CO 80487 (800)334-5493 0 - • • <br /> Rio Grande Silver, Inc. ACZ Project ID: L26556 <br /> METHOD QUAL DESCRIPTION <br /> L26566-02 WG390371 Aluminum,total recoverable M200.7 ICP M1 Matrix spike recovery was high,the recovery of the <br /> associated control sample(LCS or LFB)was acceptable. <br /> Iron,total recoverable M200.7 ICP M3 The spike recovery value is unusable since the analyte <br /> concentration in the sample is disproportionate to the spike <br /> level.The recovery of the associated control sample(LCS <br /> or LFB)was acceptable. <br /> Manganese,total recoverable M200.7 ICP M3 The spike recovery value is unusable since the analyte <br /> concentration in the sample is disproportionate to the spike <br /> level.The recovery of the associated control sample(LCS <br /> or LFB)was acceptable. <br /> WG390944 Zinc,dissolved M200.8 ICP-MS M3 The spike recovery value is unusable since the analyte <br /> concentration in the sample is disproportionate to the spike <br /> level.The recovery of the associated control sample(LCS <br /> or LFB)was acceptable. <br /> WG391821 Zinc,total recoverable M200.8 ICP-MS M3 The spike recovery value is unusable since the analyte <br /> concentration in the sample is disproportionate to the spike <br /> level.The recovery of the associated control sample(LCS <br /> or LFB)was acceptable. <br /> WG390787 Chloride M300.0-Ion Chromatography RA Relative Percent Difference(RPD)was not used for data <br /> validation because the sample concentration is too low for <br /> accurate evaluation(<1 Ox MDL). <br /> WG390792 Fluoride SM450OF-C M2 Matrix spike recovery was low,the recovery of the <br /> associated control sample(LCS or LFB)was acceptable. <br /> SM450OF-C RA Relative Percent Difference(RPD)was not used for data <br /> validation because the sample concentration is too low for <br /> accurate evaluation(<1 Ox MDL). <br /> WG390186 Nitrate/Nitrite as N,dissolved M353.2-Automated Cadmium RA Relative Percent Difference(RPD)was not used for data <br /> Reduction validation because the sample concentration is too low for <br /> accurate evaluation(<1 Ox MDL). <br /> Nitrite as N,dissolved M353.2-Automated Cadmium RA Relative Percent Difference(RPD)was not used for data <br /> Reduction validation because the sample concentration is too low for <br /> accurate evaluation(<1 Ox MDL). <br /> WG390801 Nitrogen,ammonia M350.1 RA Relative Percent Difference(RPD)was not used for data <br /> validation because the sample concentration is too low for <br /> accurate evaluation(<1 Ox MDL). <br /> WG390774 Nitrogen,total Kjeldahl M351.2-TKN by Block Digester RA Relative Percent Difference(RPD)was not used for data <br /> validation because the sample concentration is too low for <br /> accurate evaluation(<1 Ox MDL). <br /> WG390363 Suede as S SM4500S2-D QD Reported value is the background-corrected concentration, <br /> as described by the method. <br /> WG390634 Total Alkalinity SM2320B-Titration RA Relative Percent Difference(RPD)was not used for data <br /> validation because the sample concentration is too low for <br /> accurate evaluation(<1 Ox MDL). <br /> SM2320B-Titration RO The duplicate originally assigned to this sample was not <br /> used for precision assessment because residue density <br /> exceeded the method limits. Another duplicate in the batch <br /> was used to assess precision. Method required duplicate <br /> frequency was not met. <br /> REPAD.15.06.05.01 <br /> L26556-1510071448 Page 25 of 37 <br />