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A CZ Laboratories, Inc. <br />2773 Downhill Drive Steamboat Sonnos CO R04R7 iRnnl A.44-.549.4 <br />Rio Grande Silver, Inc. ACZ Project ID: L25209 <br />Nitrogen, ammonia <br />ACZ ID Type <br />Analyzed <br />M350.1 <br />PCN/SCN <br />Units <br />WG386566 <br />WG386676 <br />Oc <br />Sample Found <br />Units <br />Rec <br />Lower <br />Upper RPD Limit Qual <br />WG3866761CV <br />ICV <br />07/13/1513:20 <br />W1150505-1 <br />11.988 <br />12.37 <br />mg/L <br />103 <br />90 <br />110 <br />WG386676ICB <br />ICB <br />07/13/1513:22 <br />U <br />mg/L <br />U <br />mg/L <br />0.3 <br />-0.15 <br />0.15 <br />WG386676CCV1 <br />CCV <br />07/13/1513:37 <br />W1150505-2 <br />10 <br />10.724 <br />mg/L <br />107 <br />90 <br />110 <br />WG386676CCB1 <br />CCB <br />07/13/1513:39 <br />2.71 <br />mg/L <br />U <br />mg/L <br />110 <br />-0.15 <br />0.15 <br />L25209-01AS <br />AS <br />07/13/1513:46 <br />W1150615-1 <br />10 <br />U 10.765 <br />m9/L <br />108 <br />90 <br />110 <br />L25209-02DUP <br />DUP <br />07/13/1513:49 <br />U <br />mg/L <br />U U <br />mg/L <br />0.3 <br />WG3865661CV1 <br />0 20 RA <br />WG386676CCV2 <br />CCV <br />07/13/1513:54 <br />W1150505-2 <br />10 <br />10.728 <br />mg/L <br />107 <br />90 <br />110 <br />WG386676CCB2 <br />CCB <br />07/13/1513:56 <br />U <br />mg/L <br />U <br />mg/L <br />0.3 <br />-0.15 <br />0.15 <br />WG3866761CV1 <br />ICV <br />07/13/1516:28 <br />W1150505-1 <br />11.988 <br />12.021 <br />mg/L <br />100 <br />90 <br />110 <br />WG3866761CB1 <br />ICB <br />07/13/1516:30 <br />2.69 <br />mg/L <br />U <br />mg/L <br />110 <br />-0.15 <br />0.15 <br />WG386676CCV6 <br />CCV <br />07/13/1516:45 <br />W1150505-2 <br />10 <br />9.984 <br />mg/L <br />100 <br />90 <br />110 <br />WG386676CCB6 <br />CCB <br />07/13/1516:47 <br />U <br />mg/L <br />U <br />mg/L <br />0.3 <br />-0.15 <br />0.15 <br />WG386676LFB1 <br />LFB <br />07/13/1517:00 <br />W1150615-1 <br />10 <br />9.953 <br />mg/L <br />100 <br />90 <br />110 <br />WG386676CCV7 <br />CCV <br />07/13/1517:03 <br />W1150505-2 <br />10 <br />9.981 <br />mg/L <br />100 <br />90 <br />110 <br />WG386676CCB7 <br />CCB <br />07/13/1517:04 <br />U <br />mg/L <br />U <br />mg/L <br />0.3 <br />-0.15 <br />0.15 <br />WG386676LFB2 <br />LFB <br />07/13/1517:17 <br />W1150615-1 <br />10 <br />10.041 <br />mg/L <br />100 <br />90 <br />110 <br />WG386676CCV8 <br />CCV <br />07/13/1517:20 <br />W1150505-2 <br />10 <br />9.982 <br />mg/L <br />100 <br />90 <br />110 <br />WG386676CCB8 <br />CCB <br />07/13/1517:21 <br />6.3 12.44 <br />mg/L <br />U <br />mg/L <br />110 M1 <br />-0.15 <br />0.15 <br />WG386676CCV9 <br />CCV <br />07/13/1517:47 <br />W1150505-2 <br />10 <br />9.993 <br />mg/L <br />100 <br />90 <br />110 <br />WG386676CCB9 <br />CCB <br />07/13/1517:49 <br />U <br />mg/L <br />.051 <br />mg/L <br />0.3 <br />-0.15 <br />0.15 <br />WG386676CCV10 <br />CCV <br />07/13/1517:56 <br />W1150505-2 <br />10 <br />10.052 <br />mg/L <br />101 <br />90 <br />110 <br />WG386676CCB10 <br />CCB <br />07/13/1517:58 <br />U <br />mg/L <br />-0.15 <br />0.15 <br />Nitrogen, total Kjeldahl <br />M351.2 - TKN by Block Digester <br />Sample Fotmd� <br />Units <br />WG386566 <br />WG3865661CV <br />ICV <br />07/09/15 22:35 <br />W1150629-1 <br />4 <br />3.63 <br />mg/L <br />91 <br />90 <br />110 <br />WG386566ICB <br />ICB <br />07/09/15 22:36 <br />U <br />mg/L <br />-0.3 <br />0.3 <br />WG386531LRB1 <br />LRB <br />07/09/1522:37 <br />U <br />mg/L <br />-0.3 <br />0.3 <br />WG386531LFB1 <br />LFB <br />07/09/1522:38 <br />W1150422-2 <br />2.5 <br />2.71 <br />mg/L <br />108 <br />90 <br />110 <br />WG386566CCV1 <br />CCV <br />07/09/15 22:49 <br />W1150703-2 <br />2.5 <br />2.72 <br />mg/L <br />109 <br />90 <br />110 <br />WG386566CCB1 <br />CCB <br />07/09/15 22:50 <br />U <br />mg/L <br />-0.3 <br />0.3 <br />WG3865661CV1 <br />ICV <br />07/09/15 22:59 <br />W1150629-1 <br />4 <br />4.03 <br />mg/L <br />101 <br />90 <br />110 <br />WG386566ICB1 <br />ICB <br />07/09/15 23:00 <br />U <br />mg/L <br />-0.3 <br />0.3 <br />L25205-01DUP <br />DUP <br />07/09/1523:10 <br />.6 .57 <br />mg/L <br />5 20 RA <br />WG386566CCV2 <br />CCV <br />07/09/1523:13 <br />W1150703-2 <br />2.5 <br />2.69 <br />mg/L <br />108 <br />90 <br />110 <br />WG386566CCB2 <br />CCB <br />07/09/15 23:14 <br />U <br />mg/L <br />-0.3 <br />0.3 <br />WG386531LRB2 <br />LRB <br />07/09/1523:22 <br />U <br />mg/L <br />-0.3 <br />0.3 <br />WG386531LFB2 <br />LFB <br />07/09/1523:23 <br />W1150422-2 <br />2.5 <br />2.64 <br />mg/L <br />106 <br />90 <br />110 <br />WG386566CCV3 <br />CCV <br />07/09/15 23:26 <br />W1150703-2 <br />2.5 <br />2.7 <br />mg/L <br />108 <br />90 <br />110 <br />WG386566CCB3 <br />CCB <br />07/09/1523:28 <br />U <br />mg/L <br />-0.3 <br />0.3 <br />WG386566CCV4 <br />CCV <br />07/09/1523:40 <br />W1150703-2 <br />2.5 <br />2.68 <br />mg/L <br />107 <br />90 <br />110 <br />WG386566CCB4 <br />CCB <br />07/09/15 23:41 <br />U <br />mg/L <br />-0.3 <br />0.3 <br />L25178-01LFM <br />LFM <br />07/09/1523:44 <br />W1150422-2 <br />2.5 <br />6.3 12.44 <br />mg/L <br />246 <br />90 <br />110 M1 <br />WG386566CCV5 <br />CCV <br />07/09/15 23:51 <br />W1150703-2 <br />2.5 <br />2.73 <br />mg/L <br />109 <br />90 <br />110 <br />WG386566CCB5 <br />CCB <br />07/09/15 23:52 <br />U <br />mg/L <br />-0.3 <br />0.3 <br />L25209-1507241357 Page 26 of 45 <br />