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ACZ Laboratories, Inc. <br />2773 Downhill Drive Steamboat Sorinas CO 80487 (8001 3.44-549.4 <br />Rio Grande Silver, Inc. ACZ Project ID: L25209 <br />Iron, dissolved M200.7 ICP <br />Iron, total recoverable <br />M200.7 ICP <br />M200.8 ICP -MS <br />• <br />. <br />ACZ to <br />Ipper RPD Limit Qual <br />WG386555 <br />PCNISCN <br />Qc Sample <br />Found <br />Units <br />Rec <br />Lower <br />Upper RPD Limit Qual <br />Upper RPD Limit Qual <br />WG3865551CV <br />ICV <br />07/09/1516:33 <br />11150616-3 <br />2 <br />1.945 <br />mg/L <br />97 <br />95 <br />105 <br />WG386555ICB <br />ICB <br />07/09/1516:39 <br />U <br />mg/L <br />-0.06 <br />0.06 <br />WG386555PQV <br />PQV <br />07/09/1516:42 <br />11150618-2 <br />.050005 <br />.05 <br />mg/L <br />100 <br />70 <br />130 <br />WG386555SIC <br />SIC <br />07/09/1516:45 <br />11150619-1 <br />200.070005 <br />186.5 <br />mg/L <br />93 <br />1 <br />200 <br />WG386555LFB <br />LFB <br />07/09/1516:52 <br />11150707-8 <br />1.0001 <br />1.013 <br />mg/L <br />101 <br />85 <br />115 <br />WG386555CCV1 <br />CCV <br />07/09/1517:23 <br />11150623-1 <br />1 <br />1.01 <br />mg/L <br />101 <br />90 <br />110 <br />WG386555CCB1 <br />CCB <br />07/09/1517:26 <br />U <br />mg/L <br />U <br />mg/L <br />0.044 <br />-0.06 <br />0.06 <br />L25209-01AS <br />AS <br />07/09/1517:42 <br />11150707-8 <br />1.0001 .04 <br />1.018 <br />mg/L <br />98 <br />85 <br />115 <br />L25209-01ASD <br />ASD <br />07/09/1517:45 <br />11150707-8 <br />1.0001 .04 <br />1.028 <br />mg/L <br />99 <br />85 <br />115 1 20 <br />WG386555CCV2 <br />CCV <br />07/09/1518:00 <br />11150623-1 <br />1 <br />.986 <br />mg/L <br />99 <br />90 <br />110 <br />WG386555CCB2 <br />CCB <br />07/09/1518:03 <br />1.013 <br />mg/L <br />U <br />mg/L <br />110 <br />-0.06 <br />0.06 <br />WG386555CCV3 <br />CCV <br />07/09/1518:22 <br />11150623-1 <br />1 <br />.972 <br />mg/L <br />97 <br />90 <br />110 <br />WG386555CCB3 <br />CCB <br />07/09/1518:25 <br />1.019 <br />mg/L <br />U <br />mg/L <br />110 <br />-0.06 <br />0.06 <br />Iron, total recoverable <br />M200.7 ICP <br />M200.8 ICP -MS <br />ACZ to <br />Type <br />Analyzed <br />PCNISCN <br />Qc Sample <br />Found <br />Units <br />Rec <br />Lower <br />Upper RPD Limit Qual <br />Upper RPD Limit Qual <br />WG386529 <br />WG386680 <br />WG3865291CV <br />ICV <br />07/09/1510:50 <br />11150616-3 <br />2 <br />1.963 <br />mg/L <br />98 <br />95 <br />105 <br />WG386529ICB <br />ICB <br />07/09/1510:56 <br />07/10/1510:25 <br />U <br />mg/L <br />mg/L <br />-0.06 <br />0.06 <br />WG386529PQV <br />PQV <br />07/09/1510:59 <br />11150618-2 <br />.050005 <br />.046 <br />mg/L <br />92 <br />70 <br />130 <br />WG386529SIC <br />SIC <br />07/09/1511:02 <br />11150619-1 <br />200.070005 <br />190.7 <br />mg/L <br />95 <br />1 <br />200 <br />WG386464LRB <br />LRB <br />07/09/1511:12 <br />07/10/1511:01 <br />U <br />mg/L <br />mg/L <br />-0.044 <br />0.044 <br />WG386464LFB <br />LFB <br />07/09/1511:15 <br />11150617-2 <br />1.0001 <br />1.029 <br />mg/L <br />103 <br />85 <br />115 <br />L25139-01LFM <br />LFM <br />07/09/1511:21 <br />11150617-2 <br />1.0001 .47 <br />1.493 <br />mg/L <br />103 <br />70 <br />130 <br />L25139-01LFMD <br />LFMD <br />07/09/1511:24 <br />11150617-2 <br />1.0001 .47 <br />1.495 <br />mg/L <br />103 <br />70 <br />130 0 20 <br />WG386529CCV1 <br />CCV <br />07/09/1511:39 <br />11150623-1 <br />1 <br />1.013 <br />mg/L <br />101 <br />90 <br />110 <br />WG386529CCB1 <br />CCB <br />07/09/1511:42 <br />07/10/1511:56 <br />MS150706-4 <br />U <br />mg/L <br />mg/L <br />-0.06 <br />0.06 <br />WG386529CCV2 <br />CCV <br />07/09/1512:01 <br />11150623-1 <br />1 <br />1.019 <br />mg/L <br />102 <br />90 <br />110 <br />WG386529CCB2 <br />CCB <br />07/09/1512:04 <br />U <br />mg/L <br />-0.06 <br />0.06 <br />Lead, dissolved <br />M200.8 ICP -MS <br />ACZ to <br />Type <br />Analyzed <br />PCN/SCN <br />QC <br />Sample Found <br />Units <br />Rec <br />Lower <br />Upper RPD Limit Qual <br />WG386680 <br />WG3865801CV <br />ICV <br />07/10/1510:22 <br />MS150601-9 <br />.05 <br />.04892 <br />mg/L <br />98 <br />90 <br />110 <br />WG386580ICB <br />ICB <br />07/10/1510:25 <br />U <br />mg/L <br />-0.0003 <br />0.0003 <br />WG386580LFB <br />LFB <br />07/10/1510:28 <br />MS150625-6 <br />.05005 <br />.04649 <br />mg/L <br />93 <br />85 <br />115 <br />WG386580CCV1 <br />CCV <br />07/10/1510:58 <br />MS150706-4 <br />.25025 <br />.2526 <br />mg/L <br />101 <br />90 <br />110 <br />WG386580CCB1 <br />CCB <br />07/10/1511:01 <br />U <br />mg/L <br />-0.0003 <br />0.0003 <br />L25142-03AS <br />AS <br />07/10/1511:23 <br />MS150625-6 <br />1.001 <br />U .9522 <br />mg/L <br />95 <br />70 <br />130 <br />L25142-03ASD <br />ASD <br />07/10/1511:26 <br />MS150625-6 <br />1.001 <br />U .926 <br />mg/L <br />93 <br />70 <br />130 3 20 <br />WG386580CCV2 <br />CCV <br />07/10/1511:35 <br />MS150706-4 <br />.25025 <br />.2529 <br />mg/L <br />101 <br />90 <br />110 <br />WG386580CCB2 <br />CCB <br />07/10/1511:38 <br />U <br />mg/L <br />-0.0003 <br />0.0003 <br />WG386580CCV3 <br />CCV <br />07/10/1511:56 <br />MS150706-4 <br />.25025 <br />.2547 <br />mg/L <br />102 <br />90 <br />110 <br />WG386580CCB3 <br />CCB <br />07/10/1511:59 <br />U <br />mg/L <br />-0.0003 <br />0.0003 <br />L25209-1507241357 Page 22 of 45 <br />