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ADZ Laboratories, Inc. <br />Rio Grande Silver, Inc. ACZ Project ID: L25209 <br />Calcium, dissolved M200.7 ICP <br />WG386555 <br />WG3865551CV <br />ICV <br />07/09/1516:33 <br />11150616-3 <br />100 <br />100.13 <br />mg/L <br />100 <br />95 <br />105 <br />WG386555ICB <br />ICB <br />07/09/1516:39 <br />Sample Found <br />Units <br />U <br />mg/L <br />Upper•D Limit Quaf <br />-0.3 <br />0.3 <br />WG386555PQV <br />PQV <br />07/09/1516:42 <br />11150618-2 <br />.50095 <br />.54 <br />mg/L <br />108 <br />70 <br />130 <br />WG386555SIC <br />SIC <br />07/09/1516:45 <br />11150619-1 <br />200.88095 <br />196.2 <br />mg/L <br />98 <br />1 <br />200 <br />WG386555LFS <br />LFB <br />07/09/1516:52 <br />11150707-8 <br />68.01261 <br />70.45 <br />mg/L <br />104 <br />85 <br />115 <br />WG386555CCV1 <br />CCV <br />07/09/1517:23 <br />11150623-1 <br />50 <br />51.78 <br />mg/L <br />104 <br />90 <br />110 <br />WG386555CCB1 <br />CCB <br />07/09/1517:26 <br />4.2 <br />mg/L <br />U <br />mg/L <br />130 <br />-0.3 <br />0.3 <br />L25209-01AS <br />AS <br />07/09/1517:42 <br />11150707-8 <br />68.01261 8.7 <br />78.51 <br />mg/L <br />103 <br />85 <br />115 <br />L25209-01ASD <br />ASD <br />07/09/1517:45 <br />11150707-8 <br />68.01261 8.7 <br />79.51 <br />mg/L <br />104 <br />85 <br />115 1 20 <br />WG386555CCV2 <br />CCV <br />07/09/1518:00 <br />11150623-1 <br />50 <br />51.15 <br />mg/L <br />102 <br />90 <br />110 <br />WG386555CCB2 <br />CCB <br />07/09/1518:03 <br />47.7 <br />mg/L <br />U <br />mg/L <br />110 <br />-0.3 <br />0.3 <br />WG386555CCV3 <br />CCV <br />07/09/1518:22 <br />11150623-1 <br />50 <br />50.71 <br />mg/L <br />101 <br />90 <br />110 <br />WG386555CCB3 <br />CCB <br />07/09/1518:25 <br />48.2 <br />mg/L <br />U <br />mg/L <br />110 <br />-0.3 <br />0.3 <br />Carbon, dissolved organic (DOC) <br />SM5310B <br />101 <br />90 <br />110 <br />WG3862911CV <br />ICV <br />07/06/1510:00 <br />ACZ ID <br />Type <br />Analyzed <br />PCNISCN <br />QC <br />Sample Found <br />Units <br />Rec <br />Lower <br />Upper•D Limit Quaf <br />90 <br />110 <br />WG386291LFB1 <br />LFB <br />07/06/1510:27 <br />WC150414-3 <br />50 <br />WG386291CCV1 <br />CCV <br />07/06/1511:48 <br />WG387348 <br />400 <br />WG386291CCB1 <br />CCB <br />07/06/1511:57 <br />90 <br />110 <br />WG386291CCV2 <br />CCV <br />07/06/1513:36 <br />WG387348CCV1 <br />CCV <br />07/23/1515:33 <br />W1150623-3 <br />50 <br />49.2 <br />mg/L <br />98 <br />90 <br />110 <br />WG387348CCB1 <br />CCB <br />07/23/1515:33 <br />LFB <br />07/06/1514:57 <br />U <br />mg/L <br />WG386291CCV3 <br />-3 <br />3 <br />WG387348PQV <br />PQV <br />07/23/1515:33 <br />W1150623-5 <br />5 <br />4.2 <br />mg/L <br />84 <br />70 <br />130 <br />WG387348LFB <br />LFB <br />07/23/1515:33 <br />W1150623-4 <br />50 <br />48 <br />mg/L <br />96 <br />90 <br />110 <br />L25098-01DUP <br />DUP <br />07/23/1515:33 <br />CCB <br />07/06/1516:45 <br />U U <br />mg/L <br />0 20 RA <br />L25098-02AS <br />AS <br />07/23/1515:33 <br />W1150623-4 <br />50 <br />U 48.4 <br />mg/L <br />97 <br />90 <br />110 <br />WG387348CCV2 <br />CCV <br />07/23/1515:33 <br />W1150623-3 <br />50 <br />47.7 <br />mg/L <br />95 <br />90 <br />110 <br />WG387348CCB2 <br />CCB <br />07/23/1515:33 <br />U <br />mg/L <br />-3 <br />3 <br />WG387348CCV3 <br />CCV <br />07/23/1515:33 <br />W1150623-3 <br />50 <br />48.2 <br />mg/L <br />96 <br />90 <br />110 <br />WG387348CCB3 <br />CCB <br />07/23/1515:33 <br />U <br />mg/L <br />-3 <br />3 <br />WG387348CCV4 <br />CCV <br />07/23/1515:33 <br />W1150623-3 <br />50 <br />48 <br />mg/L <br />96 <br />90 <br />110 <br />WG387348CCB4 <br />CCB <br />07/23/1515:33 <br />U <br />mg/L <br />-3 <br />3 <br />Chemical Oxygen Demand M410.4 <br />WG386291 <br />mg/L <br />101 <br />90 <br />110 <br />WG3862911CV <br />ICV <br />07/06/1510:00 <br />WC150107-2 <br />200 <br />WG386291ICB <br />ICB <br />07/06/1510:09 <br />-20 <br />20 <br />WG386291LRB1 <br />LRB <br />07/06/1510:18 <br />90 <br />110 <br />WG386291LFB1 <br />LFB <br />07/06/1510:27 <br />WC150414-3 <br />50 <br />WG386291CCV1 <br />CCV <br />07/06/1511:48 <br />WC150414-2 <br />400 <br />WG386291CCB1 <br />CCB <br />07/06/1511:57 <br />90 <br />110 <br />WG386291CCV2 <br />CCV <br />07/06/1513:36 <br />WC150414-2 <br />400 <br />WG386291CCB2 <br />CCB <br />07/06/1513:45 <br />-20 <br />20 <br />WG386291LRB2 <br />LRB <br />07/06/1514:48 <br />90 <br />110 <br />WG386291LFB2 <br />LFB <br />07/06/1514:57 <br />WC150414-3 <br />50 <br />WG386291CCV3 <br />CCV <br />07/06/1515:24 <br />WC150414-2 <br />400 <br />WG386291CCB3 <br />CCB <br />07/06/1515:33 <br />L25209-03DUP <br />DUP <br />07/06/1516:18 <br />90 <br />U <br />L25209-03AS <br />AS <br />07/06/1516:27 <br />WC150414-3 <br />50 U <br />WG386291CCV4 <br />CCV <br />07/06/1516:36 <br />WC150414-2 <br />400 <br />WG386291CCB4 <br />CCB <br />07/06/1516:45 <br />202 <br />mg/L <br />101 <br />90 <br />110 <br />U <br />mg/L <br />-20 <br />20 <br />U <br />mg/L <br />-20 <br />20 <br />52 <br />mg/L <br />104 <br />90 <br />110 <br />408 <br />mg/L <br />102 <br />90 <br />110 <br />U <br />mg/L <br />-20 <br />20 <br />408 <br />mg/L <br />102 <br />90 <br />110 <br />U <br />mg/L <br />-20 <br />20 <br />U <br />mg/L <br />-20 <br />20 <br />53 <br />mg/L <br />106 <br />90 <br />110 <br />409 <br />mg/L <br />102 <br />90 <br />110 <br />U <br />mg/L <br />-20 <br />20 <br />U <br />mg/L <br />50 <br />mg/L <br />100 <br />90 <br />110 <br />409 <br />mg/L <br />102 <br />90 <br />110 <br />U <br />mg/L <br />-20 <br />20 <br />0 20 RA <br />L25209-1507241357 Page 18 of 45 <br />