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ACZ Laboratories, Inc. <br />2773 Downhill Drive Steamboat Sorinas. CO 80487 /8001 334-5493 <br />Rio Grande Silver, Inc. ACZ Project ID: L25209 <br />Alkalinity as CaCO3 SM2320B - Titration <br />AL;/- 11 <br />rype <br />Analyzed <br />PCIUSCII <br />WC Sample <br />FoundEl <br />Rec <br />Lower <br />Upper RPD Limit • <br />WG386205 <br />QC Sample <br />Found <br />Units <br />Rec <br />Lower <br />Upper RPD Limit • <br />WG386529 <br />WG386205PBW1 <br />PBW <br />07/01/1516:38 <br />U <br />mg/L <br />WG3865291CV <br />-20 <br />20 <br />WG386205LCSW3 <br />LCSW <br />07/01/1516:55 <br />WC150630-7 <br />820.0001 <br />793 <br />mg/L <br />97 <br />90 <br />110 <br />WG386205PQV2 <br />PQV <br />07/01/1517:05 <br />WC150701-2 <br />20 <br />21.5 <br />mg/L <br />108 <br />50 <br />150 <br />WG386205LCSW6 <br />LCSW <br />07/01/15 20:06 <br />WC150630-7 <br />820.0001 <br />796 <br />mg/L <br />97 <br />90 <br />110 <br />WG386205PBW2 <br />PBW <br />07/01/15 20:14 <br />mg/L <br />103 <br />U <br />mg/L <br />WG386464LRB <br />-20 <br />20 <br />WG386205LCSW9 <br />LCSW <br />07/01/15 23:42 <br />WC150630-7 <br />820.0001 <br />807 <br />mg/L <br />98 <br />90 <br />110 <br />WG386205PBW3 <br />PBW <br />07/01/15 23:49 <br />mg/L <br />105 <br />U <br />mg/L <br />L25139-01LFM <br />-20 <br />20 <br />WG386205LCSW12 <br />LCSW <br />07/02/153:00 <br />WC150630-7 <br />820.0001 <br />815 <br />mg/L <br />99 <br />90 <br />110 <br />WG386205PBW4 <br />PBW <br />07/02/15 3:08 <br />mg/L <br />116 <br />U <br />mg/L <br />WG386529CCV1 <br />-20 <br />20 <br />L25209-03DUP <br />DUP <br />07/02/15 3:49 <br />mg/L <br />21 <br />21.3 <br />mg/L <br />WG386529CCB1 <br />CCB <br />1 20 <br />WG386205LCSW15 <br />LCSW <br />07/02/154:07 <br />WC150630-7 <br />820.0001 <br />818 <br />mg/L <br />100 <br />90 <br />110 <br />Aluminum, dissolved <br />1 <br />M200.7 ICP <br />mg/L <br />102 <br />90 <br />110 <br />WG386529CCB2 <br />CCB <br />07/09/1512:04 <br />Analyzed <br />PCNISCN <br />oc Sample <br />Found <br />Units <br />Rec <br />Lower <br />Upper RPD Limit Qual <br />WG386555 <br />WG3865551CV <br />ICV <br />07/09/1516:33 <br />11150616.3 <br />2 <br />1.964 <br />mg/L <br />98 <br />95 <br />105 <br />WG386555ICB <br />ICB <br />07/09/1516:39 <br />U <br />mg/L <br />-0.09 <br />0.09 <br />WG386555PQV <br />PQV <br />07/09/1516:42 <br />11150618-2 <br />.150225 <br />.155 <br />mg/L <br />103 <br />70 <br />130 <br />WG386555SIC <br />SIC <br />07/09/1516:45 <br />11150619-1 <br />200.450225 <br />208.6 <br />mg/L <br />104 <br />1 <br />200 <br />WG386555LFB <br />LFB <br />07/09/1516:52 <br />11150707-8 <br />1.0015 <br />1.062 <br />mg/L <br />106 <br />85 <br />115 <br />WG386555CCV1 <br />CCV <br />07/09/1517:23 <br />11150623-1 <br />1 <br />1.023 <br />mg/L <br />102 <br />90 <br />110 <br />WG386555CCB1 <br />CCB <br />07/09/1517:26 <br />U <br />mg/L <br />-0.09 <br />0.09 <br />L25209-01AS <br />AS <br />07/09/1517:42 <br />11150707-8 <br />1.0015 .07 <br />1.125 <br />mg/L <br />105 <br />85 <br />115 <br />L25209-01ASD <br />ASD <br />07/09/1517:45 <br />11150707-8 <br />1.0015 .07 <br />1.131 <br />mg/L <br />106 <br />85 <br />115 1 20 <br />WG386555CCV2 <br />CCV <br />07/09/1518:00 <br />11150623-1 <br />1 <br />1.015 <br />mg/L <br />102 <br />90 <br />110 <br />WG386555CCB2 <br />CCB <br />07/09/1518:03 <br />U <br />mg/L <br />-0.09 <br />0.09 <br />WG386555CCV3 <br />CCV <br />07/09/1518:22 <br />11150623-1 <br />1 <br />1.011 <br />mg/L <br />101 <br />90 <br />110 <br />WG386555CCB3 <br />CCB <br />07/09/1518:25 <br />U <br />mg/L <br />-0.09 <br />0.09 <br />Aluminum, total recoverable <br />M200.7 ICP <br />ACZ ID <br />Type <br />QC Sample <br />Found <br />Units <br />Rec <br />Lower <br />Upper RPD Limit • <br />WG386529 <br />WG3865291CV <br />ICV <br />07/09/1510:50 <br />11150616-3 <br />2 <br />1.993 <br />mg/L <br />100 <br />95 <br />105 <br />WG386529ICB <br />ICB <br />07/09/1510:56 <br />U <br />mg/L <br />-0.09 <br />0.09 <br />WG386529PQV <br />PQV <br />07/09/1510:59 <br />11150618-2 <br />.150225 <br />.156 <br />mg/L <br />104 <br />70 <br />130 <br />WG386529SIC <br />SIC <br />07/09/1511:02 <br />11150619-1 <br />200.450225 <br />206.9 <br />mg/L <br />103 <br />1 <br />200 <br />WG386464LRB <br />LRB <br />07/09/1511:12 <br />U <br />mg/L <br />-0.066 <br />0.066 <br />WG386464LFB <br />LFB <br />07/09/1511:15 <br />11150617-2 <br />1.0015 <br />1.05 <br />mg/L <br />105 <br />85 <br />115 <br />L25139-01LFM <br />LFM <br />07/09/1511:21 <br />11150617-2 <br />1.0015 .39 <br />1.567 <br />mg/L <br />118 <br />70 <br />130 <br />L25139-01LFMD <br />LFMD <br />07/09/1511:24 <br />11150617-2 <br />1.0015 .39 <br />1.552 <br />mg/L <br />116 <br />70 <br />130 1 20 <br />WG386529CCV1 <br />CCV <br />07/09/1511:39 <br />11150623-1 <br />1 <br />1.022 <br />mg/L <br />102 <br />90 <br />110 <br />WG386529CCB1 <br />CCB <br />07/09/1511:42 <br />U <br />mg/L <br />-0.09 <br />0.09 <br />WG386529CCV2 <br />CCV <br />07/09/1512:01 <br />11150623-1 <br />1 <br />1.019 <br />mg/L <br />102 <br />90 <br />110 <br />WG386529CCB2 <br />CCB <br />07/09/1512:04 <br />U <br />mg/L <br />-0.09 <br />0.09 <br />L25209-1507241357 Page 15 of 45 <br />