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(545138) <br />form spontaneously combustible compounds. May react explosively with nitro- and chloro - organic compounds as well as <br />acids and reducing agents. Acidification liberates chlorine gas. <br />Hazardous Decomposition or Byproducts: Chlorine gas. Decomposes with heat and reacts with acids. <br />Hazardous gases /vapors produced are hypochlorous acid, chlorine and hydrochloric acid. Composition depends upon <br />temperature and decrease in pH. Additional decomposition products, which depend on pH, temperature and time, are <br />sodium chloride and chlorate, and ox ygen. <br />No Mechanical Shock or Impact <br />No Static Discharge <br />Oxidizer: No if <12% by weight, <br />preferably mouth -to -mouth if possible. If breathing is difficult, have <br />pulmonary edema and central nervous system <br />Yes if > than 12% by weight <br />Hazardous Polymer! ation <br />May Occur <br />Will Not Occur X <br />Note: Sodium Hypochlorite reacts violently with amines and ammonium salts. Solutions are reactive with common cleaning <br />products such as toilet bowl cleaners, rust removers, vinegar, acids, organics and ammonia products to produce hazardous <br />gases such as chlorine and other chlorinated species. <br />SECTION 5 POTENTIAL HEALTH EFFECTS AND FIRST AID INFORMATION <br />GENERAL: May cause immediate pain. Exposure to the skin may cause sensitization or other allergic responses. If the eye <br />is not irrigated immediately after it has been exposed permanent eye damage may occur. Strict adherence to first aid <br />measures followinq anv exposure is essential. SPEED IS ESSENTIAL! <br />ROUTE(S) OF ENTRY AND POTENTIAL <br />EMERGENCY & FIRST AIDE PROCEDURES <br />HEALTH EFFECTS <br />INHALATION: Strong irritating to mucous <br />If inhaled, move expose person to fresh air. If person is not <br />membranes in the nose, throat and respiratory tract. <br />breathing, call 911 or an ambulance, then give artificial respiration, <br />Prolonged contact can cause chronic irritation, <br />preferably mouth -to -mouth if possible. If breathing is difficult, have <br />pulmonary edema and central nervous system <br />trained person administer oxygen. Call a poison control center or <br />depression. Repeated inhalation exposure may <br />medical physician for further treatment advice. Have the product label <br />cause impairment of lung function and permanent <br />or MSDS with you when calling or going for medical treatment. <br />lung damage. <br />SKIN CONTACT: Prolonged and repeated <br />If on skin or clothing, take off all contaminated clothing and rinse <br />exposure to dilute solutions often causes irritation, <br />skin immediately with plenty of water for 15 -20 minutes. If irritation <br />redness, pain and drying and cracking of the skin. <br />persists, repeat flushing. Do not transport victim unless the <br />Human evidence has indicated that an ingredient in <br />recommended irrigation period is completed unless flushing can be <br />this product can cause skin sensitization. Depending <br />continued during transport. Call a poison control center or medical <br />upon the concentration and how soon after exposure <br />physician for treatment advice. Have the product label or MSDS with <br />the skin is washed with water, skin contact may cause <br />you when calling or going for medical treatment. <br />burns and tissue destruction. <br />EYE CONTACT: Strongly irritating to eyes. <br />If in eyes, hold eye open and rinse slowly and gently with plenty of <br />Exposure to vapor can cause tearing, conjunctivitis <br />water for 15 -20 minutes. Remove contact lenses, if present, after the <br />and burning of the eyes. Eye contact may cause a <br />first 5 minutes, then continue rinsing eye for 10 -15 minutes. Do not <br />corneal injury. The severity of the effects depend on <br />transport victim until the recommended flushing period is completed <br />the concentration and how soon after exposure the <br />unless irrigation can be continued during transport. Call a poison <br />eyes are washed with water. In severe exposure <br />control center or medical physician for further treatment advice. Have <br />cases, glaucoma, cataracts and permanent blindness <br />the product label and /or MSDS with you when calling or going to <br />may occur. <br />medical treatment. <br />INGESTION: Corrosive. Can cause severe <br />If swallowed, call poison control center or medical physician <br />corrosion of and damage to the gastrointestinal tract <br />immediately for treatment advice. Have the product label or MSDS <br />(including mouth, throat, and esophagus). Exposure <br />with you when calling or going for medical treatment. Have exposed <br />is characterized by nausea, vomiting, abdominal pain, <br />person sip a glass of water if able to swallow, and dilute immediately <br />diarrhea, bleeding, and /or tissue ulceration. <br />by giving milk, melted ice cream, starch paste or antacids such as milk <br />of magnesia. Avoid sodium bicarbonate because of carbon dioxide <br />release. DO NOT INDUCE VOMITING, LAVAGE OR ACIDIC <br />ANTIDOTES unless told to do so by poison control center or medical <br />physician. DO NOT give anything by mouth to an unconscious <br />person. If spontaneous vomiting occurs, have victim lean forward with <br />head down to avoid breathing in of vomitus, rinse mouth and <br />administer more water. <br />NOTE TO PHYSICIAN(S): Pre - existing medical conditions may be aggravated by exposures affecting target organs. There <br />are no known chronic effects. Probable mucosal damage may contraindicate the use of gastric lavage. In addition to the <br />alkalinity of this product, the continued generation of chlorine gas after ingestion can damage further the stomach mucous, <br />depending on the amount ingested. Consideration may be given to removal of the product from the stomach, taking care to <br />avoid perforation of esophagus or stomach. An ounce of 1 % sodium thiosulfate or milk of magnesia is helpful. <br />SECTION 6 TOXICOLOGICAL DATA <br />ANIMAL DATA: Inhalation 0.25 -hour LC50 - 10.5 mg /L in rats; Acute Dermal LD50 - 10,000 mg /kg in rabbits; <br />Acute Oral LD50 - 8910 mg /kg in rats <br />