2014-05-05_HYDROLOGY - M1977348

• Permit No: M1977348
• IBM Index Class Name: HYDROLOGY
• Doc Date: 5/5/2014
• Doc Name: Groundwater characterization report
• From: Golder Associates
• To: DRMS
• Email Name: ECS
• Media Type: D
• Archive: No

i ApH 2014
Table 4: Summary of Monitoring Results for MW -2
_i
Notes:
B = Estimated value, less than the practical quantitation limit for that analyte, but greater than the method detection limit
U = Analyle not detected, reported less than the practical quantitation limit
H = Analysis exceeded method hold time. pH is a field test with an immediate hold time.
NA = Analyte not analyzed
Values in Bold exceeded benchmark level:
Determination of benchmark levels presented m Golder 2011, Results of the September 2010 Groundwater Monitoring Event near the Cement Kiln Dust Disposal Area A2 at the Boettcher Limestone Quarry, La Porte Colomdo (January 6)
Date Benchmark Benchmark Basis 5/2611999 7/21/1999 9/16/7999 77/1017999 1119/2000 3/13/2000 5/1612000 111012000 9127/2010 3/31/2011 6128/2011 8/3112011 11/1112011 312712012 612112012 9/73/2012 11113/2012 3/79/2073 5/2812013 9126/2013 1111412013
Level
Metals
Aluminum, Dissolved m /L none 10.8 U c 0.8 U 1 0.8 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Antimon ,Dissolvedm L none 10.01 U 10.01 U 10.01 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Arsenic, Dissolved m 0.15 Statistical Limit NA 0.003 B 0.004 B 0.0587 0.05 B 0.045 0.062 0.042 0.036 0.021 0003 00036 <0.01 U <0.01 U <0.01 U <0.005 U 0.001 B 0.002 B 0.001 B 0.002 B 0.001 B
Arsenic, Total m IL none 041 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Banum, Dissolved m 2.0 Regulatory Limit 0.4 0.42 0.41 041 0.4 0042 041 04398 2.09 1.33 1609 0.96 1.09 1.42 1.55 1.72 1.28 1.3 1.07 1.23 122
Be Ilium, Dissolved m none -0.003 U <0.003 U <0.003 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Boron, Dissolved m 0.75 Statistical Limit 0.73 0.74 0472 0.74 0.69 0673 0.74 0.67 0.7 0.64 0669 0.78 0.64 0.73 0.72 0.70 0079 0.71 0.76 0070 0.74
Cadmium, Dissolved m /L none -0.08 U <0.08 U <0,08 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Chromium, Dissolved m 0.3 Slalistical Limit 10.3 U 1063 U <0.3 U <0.3 U 10.3 U <0.3 U <0.3 U 10.05 U <0.01 U <0,01 U 10.01 U <0.01 U <0.01 U <0.01 U <0.01 U <0.01 U <0.01 U <0.01 U <0.01 U 10.01 U 10.01 U
Cobalt, Dissolved m none <0.3 U <0.3 U 10.3 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Co er, Dissolved m2 063 Statistical Limit 1063 U 1063 U 1063 U 1063 U 1063 U 1063 U 1063 U <0.05 U 1063 U 1063 U 10.05 U 1063 U 1063 U 10.05 U 1063 U 1063 U 1063 U <0.05 U 1063 U 1063 U 10.05 U
C anide, Free m none <0.5 U 10.5 U 10.5 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Iron, Dissolved m/L 0.71 Statistical Limit <0.3 U 10.3 U 0.27 B 0011 B 0.16 B 02 B 005 007 <0.3 U 0.1 B 0.15 <0.3 U 043 B 0.91 0.8 0.7 016 1.1 0.2 B 0.9 1.32
Lead, Dissolved m/L 0.05 Regulatory Limit -0.005 U <0.005 U 0.001 B <0.005 U -0.005 U -0.005 U 0.005 B 0.002 B -0.003 U -0.003 U 0.0011 B 0.0006 8 <0.003 U -0.003 U <0.003 U <0,003 U <O.003 U <0.003 U -0.003 U <0,003 U <0.003 U
Lithium, Dissolved m 2.5 Statistical Limit 1.0 1.0 1.0 1.0 1.0 1.1 1.0 0.91 163 1.2 1.12 1.1 IT 1016 162 1.2 1.38 NA NA NA NA
Man anese, Dissolved m 2 049 Statistical Limit 0.49 0.44 0.4 0.33 0.33 0.33 0.33 0.329 0008 B 0.12 0.139 0.1 0.12 0.102 0.06 B 006 B 0.114 0.121 0.09 0.11 () 7
Merou ,Dissolved m none -0.001 U -0.001 U <0.001 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Nickel, Dissolved m L none <0.3 U 10.3 U -0.3 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Selenium, Dissolved m 0.02 Statistical Limit -0.005 U 0.002 B -0.005 U <0.005 U <0.005 U <0.005 U -0.005 U <0.005 U 090008 B 000015 0.0006 B <0.001 U -0.001 U <0.001 U <0.001 U 000008 B 0.0007 B 000011 0.0032 -0.001 U 0.0008 B
Silver, Dissolved m none <0.1 U 1061 U <0.1 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Thallium, Dissolved m 0.01 Statistical Limit -0.01 U -0.01 U <5 U <0.0003 U -0.005 U <0.001 U -0.003 U <O.003 U 10.003 U 0.0007 B -0.003 U -0.003 U -0.003 U <0.003 U -0.003 U <0. 3 U -0.003 U -0.003 U <0.003 U -0.003 U <0.003 U
Uranium, Dissolved 0.03 Statistical Limit NA NA NA 0.00465 0.005 0.0041 0.0037 0.0042 0.0048 0.0033 0.6025 B -0.003 U 0.0011 B 0.0009 B 0.0012 B 0.0012 B 0.0012 B NA NA NA NA
Uranium, Total m none 0.004 B 0.0049 0.00456 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Vanadium, Dissolved m 2 none 10.1 U 10.1 U <0.1 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Zinc, Dissolved m 2.0 Statistical Limit <0.3 U 10.3 U <0.3 U <0.3 U <0.3 U 10.3 U <0.3 U -0.05 U 10.3 U 10.3 U <0.05 U <043 U 10.3 U <0.05 U <0,3 U 10.3 U <0.3 U <0.05 U 10.3 U 10.3 U <0.05 U
Other rx
Chloride m /L 3,640 Statistical Limit 2890 2260 2670 2700 2240 2880 3100 2730 3,050 3.100 39090 3,240 3,017 3,052 31079 3,188 2,968 3,227 3,220 2,960 3,080
Fluoride
"Ill-) 2.1 Statistical Limit 1.7 1.8 1.7 1.5 1.8 1.7 2.1 1.8 1.7 1.5 1.5 1.4 1.6 1.5 1.6 1.5 197 1.7 1.6 1.6 1.5
Nitrate as m 10 Statistical Limit <0.1 U <0.1 U <0.1 U <0.1 U 0903 B NA 10.1 U <0.1 U 0.14 0907 B 0.06 B 0.03 B 10.1 U 0004 B 0.04 B 0.03 B 0.04 B NA NA NA NA
Nitrate as m 1.0 Statistical Limit -0.05 U -0.05 U <0,05 U -0.05 U <0.05 U NA <0,05 U <0.05 U <0.05 U <0.05 U <0.05 U <0.05 U <0.05 U <0.05 U <005 U <0.05 U -0.05 U NA NA NA NA
Nitrate+Nitnte asN m 10 Statistical Limit <0.1 U <0.1 U 10.1 U <001 U 0003 B NA <0.1 U <0.1 U 0614 0.07 B 0606 B 0.03 B 10.1 U 0004 B 0.04 B 0.03 B 0.04 B NA NA NA NA
Lab H s.0 74-8.8 Statistical Limit 8.2 8.2 8.1 8 805 7.9 8 8.1 8.6 H 8.2 H 8.4 H 8.3 H 8.2 H 8.3 H 8.3 H 8.6 H 8.3 H 893 H 803 H 862 H 8.1 H
Total Dissolved Solids, fi8erable residue m 6,971 Regulatory Limit 5680 5640 5680 5700 5600 5740 5600 5700 6,270 6,390 6,350 6,320 6,140 6,340 6,120 6,270 6,180 6,300 6,400 6,210 H 9.1 50 H
Sulfate m 250 Regulatory Limit 140 160 190 210 240 220 220 220 <300 U 60 B 90 B <100 U -250 U <250 U <250 U -250 U <250 U -250 U <250 U <250 U -250 U
Gross Al ha UL 15 Statistical Limit 27 320 44 349 0327 140 ±62 0.9 322 0 328 7 321 8.4 ±34 75 326 9.8 x25 18 324 0 x26 38 x38 -1.1 x21 5.1 312 -6.2 373 -/2 x21 NA NA NA NA
Gross Beta CUL none 8 x28 87 x33 52 x19 80 x37 52 x29 19 x13 2fi x23 0 ±35 4.5 x30 42 ±31 12 x29 0 ±27 73 ±q4) 8.5 29 82 x30 21 x28 11 x28 NA NA NA NA
Thi ante (m ) 1.1 1.0 <0.5 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
none
Supplementary Ana Not Historisal -W-d) -- -
.,..
Bicarbonate as CaCO3 m none NA NA NA NA NA NA NA NA 993 965 978 953 914 995 968 964 978 955 963 979 1,020
Carbonate as CaCO3 m none NA NA NA NA NA NA NA NA 108 1 20 U 37 22 57 <20 U 21 120 U 23 29 22 1 20 U -20 U
Calcium, Dissolved m none NA NA NA NA NA NA NA NA 14 14 10.4 16 15 15.5 14 16 16.3 15.1 18 17 16.9
Ma nesium, Dissolved m none NA NA NA NA NA NA NA NA 8 8 7.8 7 7 74 8 8 8 7.5 8 7 7.4
Potassium, Dissolved m L none NA NA NA NA NA NA NA NA 7 B 8 B 7.4 4 B 6 B 6.6 7 B 7 B 10.8 B 7.0 7 6 8 6.1
Sodium, Dissolv
103- 81640A
Cr0111lC[
�{ Aswciates
ed m
none
NA
NA
NA
NA
NA
NA
NA
I NA
1 2,480
1 2,430
1 2.470
2,410
2,260
2,470
2,420
2420
2,310
2,550
2,500
2,540
2,490
_i
Notes:
B = Estimated value, less than the practical quantitation limit for that analyte, but greater than the method detection limit
U = Analyle not detected, reported less than the practical quantitation limit
H = Analysis exceeded method hold time. pH is a field test with an immediate hold time.
NA = Analyte not analyzed
Values in Bold exceeded benchmark level:
Determination of benchmark levels presented m Golder 2011, Results of the September 2010 Groundwater Monitoring Event near the Cement Kiln Dust Disposal Area A2 at the Boettcher Limestone Quarry, La Porte Colomdo (January 6)
Date Benchmark Benchmark Basis 5/2611999 7/21/1999 9/16/7999 77/1017999 1119/2000 3/13/2000 5/1612000 111012000 9127/2010 3/31/2011 6128/2011 8/3112011 11/1112011 312712012 612112012 9/73/2012 11113/2012 3/79/2073 5/2812013 9126/2013 1111412013
Level
Metals
Aluminum, Dissolved m /L none 10.8 U c 0.8 U 1 0.8 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Antimon ,Dissolvedm L none 10.01 U 10.01 U 10.01 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Arsenic, Dissolved m 0.15 Statistical Limit NA 0.003 B 0.004 B 0.0587 0.05 B 0.045 0.062 0.042 0.036 0.021 0003 00036 <0.01 U <0.01 U <0.01 U <0.005 U 0.001 B 0.002 B 0.001 B 0.002 B 0.001 B
Arsenic, Total m IL none 041 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Banum, Dissolved m 2.0 Regulatory Limit 0.4 0.42 0.41 041 0.4 0042 041 04398 2.09 1.33 1609 0.96 1.09 1.42 1.55 1.72 1.28 1.3 1.07 1.23 122
Be Ilium, Dissolved m none -0.003 U <0.003 U <0.003 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Boron, Dissolved m 0.75 Statistical Limit 0.73 0.74 0472 0.74 0.69 0673 0.74 0.67 0.7 0.64 0669 0.78 0.64 0.73 0.72 0.70 0079 0.71 0.76 0070 0.74
Cadmium, Dissolved m /L none -0.08 U <0.08 U <0,08 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Chromium, Dissolved m 0.3 Slalistical Limit 10.3 U 1063 U <0.3 U <0.3 U 10.3 U <0.3 U <0.3 U 10.05 U <0.01 U <0,01 U 10.01 U <0.01 U <0.01 U <0.01 U <0.01 U <0.01 U <0.01 U <0.01 U <0.01 U 10.01 U 10.01 U
Cobalt, Dissolved m none <0.3 U <0.3 U 10.3 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Co er, Dissolved m2 063 Statistical Limit 1063 U 1063 U 1063 U 1063 U 1063 U 1063 U 1063 U <0.05 U 1063 U 1063 U 10.05 U 1063 U 1063 U 10.05 U 1063 U 1063 U 1063 U <0.05 U 1063 U 1063 U 10.05 U
C anide, Free m none <0.5 U 10.5 U 10.5 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Iron, Dissolved m/L 0.71 Statistical Limit <0.3 U 10.3 U 0.27 B 0011 B 0.16 B 02 B 005 007 <0.3 U 0.1 B 0.15 <0.3 U 043 B 0.91 0.8 0.7 016 1.1 0.2 B 0.9 1.32
Lead, Dissolved m/L 0.05 Regulatory Limit -0.005 U <0.005 U 0.001 B <0.005 U -0.005 U -0.005 U 0.005 B 0.002 B -0.003 U -0.003 U 0.0011 B 0.0006 8 <0.003 U -0.003 U <0.003 U <0,003 U <O.003 U <0.003 U -0.003 U <0,003 U <0.003 U
Lithium, Dissolved m 2.5 Statistical Limit 1.0 1.0 1.0 1.0 1.0 1.1 1.0 0.91 163 1.2 1.12 1.1 IT 1016 162 1.2 1.38 NA NA NA NA
Man anese, Dissolved m 2 049 Statistical Limit 0.49 0.44 0.4 0.33 0.33 0.33 0.33 0.329 0008 B 0.12 0.139 0.1 0.12 0.102 0.06 B 006 B 0.114 0.121 0.09 0.11 () 7
Merou ,Dissolved m none -0.001 U -0.001 U <0.001 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Nickel, Dissolved m L none <0.3 U 10.3 U -0.3 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Selenium, Dissolved m 0.02 Statistical Limit -0.005 U 0.002 B -0.005 U <0.005 U <0.005 U <0.005 U -0.005 U <0.005 U 090008 B 000015 0.0006 B <0.001 U -0.001 U <0.001 U <0.001 U 000008 B 0.0007 B 000011 0.0032 -0.001 U 0.0008 B
Silver, Dissolved m none <0.1 U 1061 U <0.1 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Thallium, Dissolved m 0.01 Statistical Limit -0.01 U -0.01 U <5 U <0.0003 U -0.005 U <0.001 U -0.003 U <O.003 U 10.003 U 0.0007 B -0.003 U -0.003 U -0.003 U <0.003 U -0.003 U <0. 3 U -0.003 U -0.003 U <0.003 U -0.003 U <0.003 U
Uranium, Dissolved 0.03 Statistical Limit NA NA NA 0.00465 0.005 0.0041 0.0037 0.0042 0.0048 0.0033 0.6025 B -0.003 U 0.0011 B 0.0009 B 0.0012 B 0.0012 B 0.0012 B NA NA NA NA
Uranium, Total m none 0.004 B 0.0049 0.00456 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Vanadium, Dissolved m 2 none 10.1 U 10.1 U <0.1 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
Zinc, Dissolved m 2.0 Statistical Limit <0.3 U 10.3 U <0.3 U <0.3 U <0.3 U 10.3 U <0.3 U -0.05 U 10.3 U 10.3 U <0.05 U <043 U 10.3 U <0.05 U <0,3 U 10.3 U <0.3 U <0.05 U 10.3 U 10.3 U <0.05 U
Other rx
Chloride m /L 3,640 Statistical Limit 2890 2260 2670 2700 2240 2880 3100 2730 3,050 3.100 39090 3,240 3,017 3,052 31079 3,188 2,968 3,227 3,220 2,960 3,080
Fluoride
"Ill-) 2.1 Statistical Limit 1.7 1.8 1.7 1.5 1.8 1.7 2.1 1.8 1.7 1.5 1.5 1.4 1.6 1.5 1.6 1.5 197 1.7 1.6 1.6 1.5
Nitrate as m 10 Statistical Limit <0.1 U <0.1 U <0.1 U <0.1 U 0903 B NA 10.1 U <0.1 U 0.14 0907 B 0.06 B 0.03 B 10.1 U 0004 B 0.04 B 0.03 B 0.04 B NA NA NA NA
Nitrate as m 1.0 Statistical Limit -0.05 U -0.05 U <0,05 U -0.05 U <0.05 U NA <0,05 U <0.05 U <0.05 U <0.05 U <0.05 U <0.05 U <0.05 U <0.05 U <005 U <0.05 U -0.05 U NA NA NA NA
Nitrate+Nitnte asN m 10 Statistical Limit <0.1 U <0.1 U 10.1 U <001 U 0003 B NA <0.1 U <0.1 U 0614 0.07 B 0606 B 0.03 B 10.1 U 0004 B 0.04 B 0.03 B 0.04 B NA NA NA NA
Lab H s.0 74-8.8 Statistical Limit 8.2 8.2 8.1 8 805 7.9 8 8.1 8.6 H 8.2 H 8.4 H 8.3 H 8.2 H 8.3 H 8.3 H 8.6 H 8.3 H 893 H 803 H 862 H 8.1 H
Total Dissolved Solids, fi8erable residue m 6,971 Regulatory Limit 5680 5640 5680 5700 5600 5740 5600 5700 6,270 6,390 6,350 6,320 6,140 6,340 6,120 6,270 6,180 6,300 6,400 6,210 H 9.1 50 H
Sulfate m 250 Regulatory Limit 140 160 190 210 240 220 220 220 <300 U 60 B 90 B <100 U -250 U <250 U <250 U -250 U <250 U -250 U <250 U <250 U -250 U
Gross Al ha UL 15 Statistical Limit 27 320 44 349 0327 140 ±62 0.9 322 0 328 7 321 8.4 ±34 75 326 9.8 x25 18 324 0 x26 38 x38 -1.1 x21 5.1 312 -6.2 373 -/2 x21 NA NA NA NA
Gross Beta CUL none 8 x28 87 x33 52 x19 80 x37 52 x29 19 x13 2fi x23 0 ±35 4.5 x30 42 ±31 12 x29 0 ±27 73 ±q4) 8.5 29 82 x30 21 x28 11 x28 NA NA NA NA
Thi ante (m ) 1.1 1.0 <0.5 U NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
none
Supplementary Ana Not Historisal -W-d) -- -
.,..
Bicarbonate as CaCO3 m none NA NA NA NA NA NA NA NA 993 965 978 953 914 995 968 964 978 955 963 979 1,020
Carbonate as CaCO3 m none NA NA NA NA NA NA NA NA 108 1 20 U 37 22 57 <20 U 21 120 U 23 29 22 1 20 U -20 U
Calcium, Dissolved m none NA NA NA NA NA NA NA NA 14 14 10.4 16 15 15.5 14 16 16.3 15.1 18 17 16.9
Ma nesium, Dissolved m none NA NA NA NA NA NA NA NA 8 8 7.8 7 7 74 8 8 8 7.5 8 7 7.4
Potassium, Dissolved m L none NA NA NA NA NA NA NA NA 7 B 8 B 7.4 4 B 6 B 6.6 7 B 7 B 10.8 B 7.0 7 6 8 6.1
Sodium, Dissolv
103- 81640A
Cr0111lC[
�{ Aswciates