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<br />per liter. Mud Creek contributed about 74 percent <br />of the selenium load to the upper Mancos River in <br />March 1994. Selenium concentrations were much <br />higher in Navajo Wash; a sample collected in <br />March had 97 micrograms per liter of selenium. <br />Bottom-sediment samples from two ponds in the <br />Mancos Project exceeded the concentration of <br />concern of 4 micrograms per gram. <br />The highest selenium concentrations in <br />biota samples from streams in the Mancos River <br />Basin were for samples from Navajo Wash. Most <br />concentrations in biota in the upper Mancos River <br />Basin were less than guidelines. Mean selenium <br />concentrations in eggs from aquatic birds <br />collected at three ponds in the Mancos Project <br />slightly exceeded the guideline associated with <br />reduced hatchability. Five bird livers had a mean <br />selenium concentration of 32.6 micrograms per <br />gram dry weight, which slightly exceeded the <br />mean concentration of 30 micrograms per gram <br />dry weight that is associated with reproductive <br />impairment. Two of the ponds had a high <br />selenium-hazard rating; however, mallard <br />reproduction was observed in 1994 at one of the <br />ponds that had a high selenium-hazard rating. <br /> <br />INTRODUCTION <br /> <br />During 1990-91, water, bottom-sediment, and <br />biota samples were collected for a reconnaissance <br />investigation of the Dolores Project area in <br />southwestern Colorado (fig. I). The investigation was <br />part of the National Irrigation Water Quality Program <br />(NIWQP), which was started by the U.S. Department <br />of the Interior in 1985 to identitY the nature and extent <br />of irrigation-induced water-quality problems in the <br />Western United States. Results of the reconnaissance <br />investigation were published in Butler and others <br />(1995). <br /> <br />Background <br /> <br />Selenium was elevated in some water, bottom- <br />sediment, and biota samples collected in 1990 in the <br />Dolores Project area (Butler and others, 1995). Many <br /> <br />of the water and biota samples collected in the newly <br />irrigated area (since 1987) of the Dolores Project <br />between Cortez and Dove Creek (the Dove Creek <br />area in fig. 1) had elevated selenium concentrations. <br />Samples of irrigation drainage from three washes in <br />the Dove Creek area had selenium concentrations <br />ranging from 3 to 12 14g/L (Butler and others, 1995). <br />Selenium concentrations in 10 of 11 aquatic- <br />invertebrate samples from the Dove Creek area <br />exceeded a guideline for food items consumed by <br />fish and wildlife. Selenium in bird eggs was in the <br />range of uncertainty for biological risk. The highest <br />selenium concentration in a biota sample collected <br />for the study in 1990 was 37.5 l1g/g dry weight in a <br />mallard liver collected from a pond in Woods Canyon <br />in the newly irrigated area of the Dolores Project <br />(fig. 1). <br />The long-lenn irrigated area of the Dolores <br />Project is the service area of the Montezuma Valley <br />Irrigation Company (MVIC) shown in figure 1. The <br />MVIC area also was sampled in 1990, and generally, <br />selenium concentrations in water, bottom sediment, <br />and bi!>ta were not elevated in samples collected from <br />streams and ponds north of Mc Elmo Creek (Butler <br />and others, 1995). However, samples from Navajo <br />Wash, which receives irrigation drainage from <br />areas on Mancos Shale in the southern part of the <br />Montezuma Valley, had high selenium concentrations. <br />The maximum selenium concentration in water <br />samples collected for the reconnaissance investigation <br />was 88 14g/L in a sample from Navajo Wash (Butler <br />and others, 1995). <br />Selenium concentrations were elevated in some <br />water and biota samples collected from the lower <br />Mancos River in 1990 (Butler and others, 1995). <br />During 1989, the U.S. Fish and Wildlife Service <br />(USFWS) collected biota samples at five sites in the <br />Mancos River Basin, and some samples had selenium <br />concentrations that exceeded guideline concentrations. <br />Bird livers collected from a pond in the irrigated <br />area of the Mancos Project (fig. I) in 1989 had high <br />selenium concentrations; one liver had a concentration <br />of 69 l4g/g dry weight (Butler and others, 1995). <br />No sampling was done in the upper part of the basin <br />in the Mancos Project area for the reconnaissance <br />investigation in 1990. <br /> <br />2 FIeld ScrMnlnll of W_, SoIl, Botlom Secllm8ll1, end Blo,," Auoclellld with Irrlgallon Dnllnege In the Dolo.- ProJ80t <br />..d the Mule... River Belin, SouthwMlllm Coloredo, 1994 <br />