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WSP07913
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Last modified
1/26/2010 2:29:24 PM
Creation date
10/12/2006 2:40:15 AM
Metadata
Fields
Template:
Water Supply Protection
File Number
8277.400.200
Description
Lower Virgin River Project
State
NV
Basin
Colorado Mainstem
Date
11/1/1986
Title
Study of Saline Water Use at the Harry Allen Generating Station - Final Report - November 1986
Water Supply Pro - Doc Type
Report/Study
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<br />regeneration efficiency. Problems with high suspended solids in the <br />regenerant have been avoided by conducting the regeneration upflow rather than <br />downflow. These streams are low in NaCI concentration (1% to 3%) as compared <br />with a saturated brine solution (10%). However, the "free" nature of the <br />regenerant provides favorable economics. <br /> <br />Ion exchange softening removes hardness only. Silica, another major scale <br />forming constituent in most waters, Is not removed. The ideal application for <br />this approach is on water supplies with high hardness, low sil ica, and low <br />suspended sol ids. If, however, the si Ilca content of the water is a limiting <br />factor for cycles of concentration, silica-specific removal techniques can be <br />appl ied to the circulating water system at a favorable overall cost. <br /> <br />Lime/Soda Softening <br /> <br /> <br />Lime softening Is one of the most common make-up treatment techniques. It in- <br />volves removal of Impurities by chemical reaction with combinations of lime, <br />soda ash, and caustic with the fol lowing effects: <br /> <br />. <br /> <br />Calcium hardness precipitates as <br />hardness as magnesium hydroxide; <br />phate as calcium phosphate <br /> <br />calcium carbonate and magnesium <br />calcium precipitates orthophos- <br /> <br />;.,: <br /> <br />" <br /> <br />. <br /> <br />Bicarbonate alkal inlty Is first converted to carbonate form and then <br />removed as calcium carbonate <br /> <br />;, <br /> <br />. Silica comes out as an Insoluble silicon-magnesium complex when it <br />reacts with, or is adsorbed on, sol id magnesium hydroxide. <br /> <br />. <br /> <br />Turbidity from suspended solids and magnesium hydroxide and calcium <br />carbonate sludge are removed by settling and/or filtration. <br /> <br />e <br />, <br /> <br />3 <br />" <br /> <br />A more recent appl icatlon of I ime softening Is for sidestream treatment. The <br />sidestream is taken from the recirculating line downstream from the condenser <br />to take advantage of the Increased efficiency of silica removal by magnesium <br />hydroxide and the lower calcium carbonate solubility at the higher temperature <br />prevail ing at this point In the system. Filters following the treating unit <br />assist in the removal of suspended calcium carbonate and magnesium hydroxide. <br />Filter wash water is recovered by returning it to the sidestream treating <br />unit. Generally a sldestream softener with associated chemical feed equipment <br />is several times smaller than a makeup softener for the same generating unit. <br />This Is accompl ished by the concentrating effect of the circulating water sys- <br />tem which provides the softener unit with a higher concentration of dissolved <br />sol ids than would be encountered in the makeup position. <br /> <br />-,: <br /> <br />;;.' <br /> <br />Sidestream I ime/soda softening has emerged through recent power plant ex- <br />periences at Martin Drake Station in Colorado, Coolwater Station In California <br />and North Valmy Station In Nevada as viable appl ications. Additional ex- <br />periences in domestic Industrial plants and In foreign power plants further <br />supports the viabll ity of sidestream softening. In the technology evaluations <br />for Task 3 sidestream lime/soda softening was considered a commercially proven <br /> <br />;~' <br /> <br />" <br /> <br />".',1 <br /> <br />4-3 <br /> <br />.' <br /> <br />'.', <br />~.~- <br />
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