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<br /> <br />The lhree most l.:o01mon]) dl..,tccted herbicides at the two agricuhural monitoring sites in the L'COL (one sill.' <br />each inlhc Grand and Uncompahgre Valley~) also were among the lOp 10 herbicides detected in surface-water <br />samples at 61 agricultural "ill.''' in 35 nationally di<;tribulcd ;">.:AWQA Study Units. The percentages of samples <br />with detections for atrazine. ;lIaclllo(. and mctolachlor are shown beluw and are oast-.J on llIore than 1.550 sam- <br />ple., for the national sites and 39 samples at the L:COL ..ill'S. Alrazine. alachlor. and mt"lolachlor are commonly <br />w_ed fliT weed control in corn. Alachlor and metol;H.'hlor arc also u..ed for weed control in dry ~all". Other herbi- <br />cides Ihal wefe frequenll)' dCICi:tcd <br />(presentlll OWT onc-third of the ...am- <br />pIt's) in the veOL but not shown in <br />the gmph incluue tritluralin. DCPA. <br />~A-D, cyanazine, and deethylatrazine <br />~ (a breakuown product of atrazine). <br />0.045 a:: <br />Z uJ These herbicides also were commonly <br />0.040 0 l- <br />;::.;:; detected at other agricultural ~ites <br />. ~ <br />0035 a: w across !he l\ation, ~lcdian l.'oncentru- <br />, ~ <br />0,030 ~ ~ tions of the commonly delected herbi- <br />0,025 5 ~ ddes in Ihe UCOL were less than or <br /><.) 8 similar 10 (he median concentralion... <br />0,020 Z a: <br />.0- u for Ihe nalional sites. Concelllrations <br />0,015 ~ <br />~ of atrazine and metolachlor were less <br />0,010 <br />than the Canadian guidelincs for the <br />protectirm of aquatic life 11.& 1lg!L for <br />atrazine and 7.8 ~lglL for metolachlor <br />(Environment Canada. 1999)]. Guide- <br />lines have nOI been established for <br />alachlor. <br /> <br />"'v-~ <br /> <br />... <br />~ <br />N <br />~ <br /> <br />EXPLANATION <br />CJ 62 Agncullufe srtes l,om NAWQA Study Unrts <br />OJ 2 Agncult1Jre 511e& from the UCOL <br />. Median concentrahon <br />. Me<han iess than 0,002 j.lgtL <br /> <br />. I <br />I ~ I <br />I <br />I , ,.- <br />, , <br />I , <br />, - I <br /> I . <br /> , , <br /> I <br />I , <br />I . .' : - <br /> ,'. . <br /> <br />90 <br /> <br />r <br />~ <br /> <br />eo <br /> <br />~ <br />~ <br />w <br />~ <br />~ ~ <br />~ z <br />~ Q 50 <br />" ~ <br />old <br />&!i:i 40 <br />~ 0 <br />z <br />w <br />" <br />~ <br />w <br />~ <br /> <br />70 <br /> <br />60 <br /> <br />30 <br /> <br />20 <br /> <br />" <br /> <br />o <br /> <br />Atrazine <br /> <br />HERBICIDE <br /> <br />w.llcr ,.1I11pk, fftlm thl' :-ame :'IIC'. <br />Ph1hahly l1el..ause thl'...l' nmlpllunu, <br />arl' rd:lli\"el~ m...\lluhlc m \\atl'r. <br />lkl.urTl.'nl'e of organlll"hlorine pc'- <br />Ill..'idl'''. l.\en al hI\\' CllIll..l.'ntration..., <br />i.. Ix'cllming Inaca:o.lIlgl~ rl'k\':lnt <br />1x'l..:J.lhc of re...'enl evidence linking <br />the..e t'\lmpounJs 10 enuex.'rine Ji.,- <br />n1ptiolltGlloJhrl'd and (lther" <br />1997l. <br /> <br />:o...Ulrknt COlIl'l'ntralinn... in <br />...tn'mn... Olnd ri\l'r~ rl'lll'l't puint <br />and Illlllpoinl :-Olln.l'''i, :'\:ltlOnal <br />background ":l'IKenlfation.. have <br />been dt"ll'nnined for 'Otlll' form.. l)1 <br />nutrienl< 1l11~llllItwgen in "rream.. <br />{I,O mg/I.!. nitr:ilL' III ,tre:1m., <br />(0,6 mg,'Ll. and Illt:.!1 phlhphoru.. in <br /> <br />0050 <br /> <br />0,005 <br /> <br />o <br /> <br />AJacttlor <br /> <br />Metolachlor <br /> <br />,{re:1m, (0,1 mg/Ll (U,S. Gcologi- <br />cal Sur\cy. 1l.J99). Kelall\"l' ...mll.cn- <br />tration:o. of nulrients III ...urfilce <br />watl'r are IinkeJ !11thI.' amount-. and <br />type" Ilf ...uh..tance, u...l.'d and UiS4 <br />...'har!;t'd in difkrl'nt Ianu-u..l' ,el- <br />ling.... The...e ..utl..laIKe... can Ihen <br />real..h thl' ...trcam through poilll <br />..lIUrl.'e..l...u..:h:1'" wa...ll'\l;ller Ji.... <br />char,gclllr nonpoinl ...our..:e~ (...ul'h <br />a... prcl'ipit:llion or runoff (Will agri- <br />cultural area...!. E...tm1ated amllunb <br />01 fertiliz.cr applied during 1997 in <br />Ddta, ~Ie...a. and ~tontrme COlln- <br />tie,.. \\t"rt" al:lolll 1-l,IOO.OOO pounds <br />l,f IlItrogen and I.SOO.OOO pound.. <br />l'( pho...phoru, dcffre~ Stoner. <br />U.S Geol\lgil."al SUf\'e~. wrinen <br /> <br />L'OlllIllUII., ~oooJ. Fertili/er use in <br />the...l.' c(luntie... aC("(lulHl'd for aDout <br />77 pcrcl.'nt llf thl' tlltal e"tim:Hl'J <br />fi.'rtililr.:r usage for the UCOL. <br />:\ulril'nt l'lltln'ntroltioll_'" in <br />ana... llf agrkultural !ollld m.t' <br />l\crl' ~clIl'rall~ gn'atl'r than in <br />an.'<J"i of olhl'r hllld l"'C!I. ~ledi:1n <br />c,lncelllrauun' llf amtlllmia. nilrile <br />plu' nitrate, liltal phmphl1ru..., uis. <br />'\lln:d ph(l..plwru:o., and l'rtlwphlh- <br />phJtC' \\ ere gre:ltt"r :1t agnculture <br />sill'.. than :It Ihe C\lh'r:1do Plateau <br />referl.'nce and mixed land-u~e ~itt".. <br />Itig. l-l). The CilloT.lll,' Plalcau <br />referenct" ,jle ha.. some limiled <br />agrkulture upstream 11i\'C'stodJ <br />ha) meJdl.l\\'I. ,\.1 i~ nN repre!'.elHa- <br /> <br />~l:1JI.)r Finding... 17 <br />