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<br />OOlH3 <br /> <br />Speci~l emphasis is warranted in regard to adequacy of sampling <br />for recordll of chemical quality. Inherently, a single analysis shows <br />only the chemical constituents at a single point within the body of <br />water sampled. Also, unless it represents a composite of samples <br />taken ove~ a period of time, it shows only the constituents momentarily <br />at that s8llIPling point. All too infrequently is a water body sampled <br />at enough points or at enough times to represent all the potential <br />variability within that body. All too few chemical-quality records <br />define point and time of sampling in relation to features of the <br />environment. Thus, an incautious hydrologist easily can be misled <br />into undefendable chemical and geochemical conclusions. The sole <br />defense is to "screen" all data for consistency, search out a full <br />explanation of any seemingly abnormal data, and draw no conclusion by <br />extrapolation. <br /> <br />The difficulties just outlined are compounded in regard to ground- <br />water quality. Here, available data generally are for samples withdrawn <br />from wells that may range widely in depth and that, when pumped, may <br />yield a blend of two or more waters of unlike chemical character, from <br />distinct aquifers. The possible ramifications go far beyond the scope <br />of this manual. Suffice it to point out that (1) a full explanation of <br />all variations in chemical quality may require comprehensive informatioh <br />on depth ahd casing records of wells, types and settings of pumps, and <br />regimen of. withdrawals for some indeterminate period prior to sampling; <br />but (2) rarely is such ancillary information reported as part of the <br />chemical-quality record. I <br /> <br />BIAS IN RECORDS OF LONG TERM <br /> <br />Some hydrologic records have been published over a long term of <br />years under a single station name when in actuality the statioh has <br />been relocated one or more times during the term. In this situation, <br />it is unwi~e to assume that the "same water" has been measured, and <br />that the comp.osite record is not "biased" by" environmental differences <br />among the several locations. For streamflow records in Water-3upply <br />Papers of the Geological Survey, the latest station description should <br />be scanned. to identify possible relevant changes in location. All such <br />records through October 1950 have been compiled and summarized in Water- <br />Supply Papers 1301 through 1319 and 1372; these reports include the <br />history of gage changes, if any, at stations discontinued prior to the <br />cut-off date of the compilation. For climatologic stations, changes in <br />location are listed in the Weather Bureau's "Substation Histories" (Key <br />to Meteorological Records Documentation No. 1.1). Each change of <br />location should be treated as though a new and independent record had <br />been started, unless the several partial records are shown to be consistent <br />one with another, by double-mass plotting against records for one or more <br />adjacent stations that are in the same environment and that have not been <br />relocated. <br /> <br />3 <br /> <br /> <br />" <br />