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<br />salts residing in soil and substrata. The salt <br />concentrating is due to the evapotranspiration of the <br />water carrying a finite salt load or the export of <br />high-quality water out of the basin. Generally, the <br />application of irrigation water results in increased salt <br />concentrations because of both loading and <br />concentrating. The evaporated or transpired water is <br />free of salt, hence, the ground.water return flows carry <br />the total salt burden. Under some conditions, however, <br />salts may be precipitated and stored in the soil. These <br />processes operate through the geochemical cycle <br />depicted in Figure 1. As water is evaporated from the <br />ocean or other free water surfaces, alterations in the <br />composition and concentration of the dissolved <br />contituents begin to occur and continue as the <br />concentration progressively increases during movement <br />through the cycle. <br /> <br /> <br />CHAPTER II. THE SALlNTY ISSUE <br /> <br />W <br />Q <br />...... <br />00 <br /> <br />The waters of the Colorado River system serve millions <br />of people in many ways. It is a vital link in sustaining <br />cities and farms, mines and industry, recreational space <br />and wildlife, and areas of great esthetic value to the <br />Nation. The water is used for irrigating crops, <br />producing energy, providing recreation, sustaining <br />livestock and wildlife, supporting industry, and <br />supplying the common daily needs of people. It is the <br />source of water for cities with in the basin and larger <br />metropolitan areas outside the basin. A large variety of <br />crops, providing a needed diversity to the national diet, <br />are irrigated by its waters both within and outside the <br />basin. But the concentration of dissolved solids in the <br />river, now among the highest of the great rivers of <br />North America, is increasing. The increase will further <br />impair the usefulness of the water. <br /> <br />Rising high in the Rocky Mountains, the Colorado <br />River flows for most of its length through qrid and <br />semiarid regions of the United States and Mexico. The <br />great river and its tributaries have cut into mountains <br />and plateaus, formed alluvial valleys, carved <br />magnificent canyons, and produced a highly productive <br />delta. In the process, its waters accumulate the solution <br />products of erosion and weathering-from headwaters <br />to mouth, a distance of nearly 1,400 miles, the salinity <br />progressively increases. <br /> <br />The river drains 242,000 square miies-1/12 the <br />conterminous area of the United States-and 2,000 <br />square miles in Mexico. The basin includes parts of <br />seven states-southwestern Wyoming, western <br />Colorado, parts of Utah, Nevada, New Mexico, nearly <br />all of Arizona, and a small section of California. From <br />this area, it carries a salinity burden of 10 million tons <br />annually. Each square mile above the Grand Canyon <br />contributes an average of about 70 tons of salt to the <br />river each year. The salt loading arises from both <br />natural and manmade sources. The water is used and <br />reused several times along its length causing the volume <br />of available water to decrease while the salinity <br />increases. The potential demands on the river exceed <br />its dependable supply. The major overriding issue on <br />the Colorado River involves the interrelated matter of <br />inadequacy of water supply to meet all proposed uses <br />and deteriorating water quality. <br /> <br />SOURCES OF SALINITY <br /> <br />In any river system, salinity concentrations arise from a <br />salt loading effect and a salt concentrating effect. The <br />salt loading may be regarded as the pickup of salt due <br />to mineral weathering and dissolution of the soluble <br /> <br />While this process adds a large variety of dissolved <br />matter to the water, only 10 elements made up about <br />99 percent of the dissolved constituents. These are <br />hydrogen, sodium, magnesium, potassium, calcium, <br />silicon, chlorine, oxygen, carbon, and sulfur. The <br />elements occur in solution as various ions, molecules, <br />or radicals. The major part of the dissolved <br />constituents in Colorado River water is made up of the <br />cations: calcium, magnesium, and sodium; and the <br />anions: sulface, chloride, and bicarbonate. These, plus <br />minor amounts of other dissolved constituents, are <br />commonly referred to as salinity, "salt," dissolved <br />solids, or dissolved mineral content. <br /> <br />Studies of the operation of the geochemical cycle <br />suggest that about half the salinity concentration in the <br />waters at Hoover Dam is derived from natural sources <br />and the remaining half from manmade uses. The order <br />of magnitude from greatest to least is: natural sources, <br />irrigation, reservoir evaporation, out-of-basin export, <br />and municipal and industrial sources. <br /> <br />SALINITY LEVELS <br /> <br />HISTORIC AND MODIFIED CONDITIONS <br /> <br />The long,term 1941-1970 historic average annual <br />salinity concentration of the Colorado River at its <br />headwaters is less than 50 mg/1. At Imperial Dam, the <br />last major diversion point in the Un ited States, the. <br />concentration is 757 mg/I. Modifying this historic <br />condition to reflect all upstream existing projects to be <br />in operation for the full period 1941-1970 would again <br />show a concentration of less than 50 mg/l at <br />headwaters and a value of 851 mg/l at Imperial Dam. <br /> <br />13 <br />