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<br />Upstream from Terrace Reservoir, total-zinc loads
<br />increased substantially during rainstorms during the
<br />summer period. Most of the total-zinc loads that
<br />entered the reservoir during rainstorm runoff did not
<br />appear to have been transported out of the reservoir
<br />(fig. 15). The smallest daily zinc loads occurred
<br />during the base-flow period between November 1994
<br />and February 1995 (fig. 15).
<br />During most of the study, zinc was transported
<br />into and out of the reservoir mostly in the dissolved
<br />fraction (fig. 10). However, during the pre-peak and
<br />peak snowmelt periods, about 30 percent of the zinc
<br />generally was transported into the reservoir in the
<br />suspended fraction (fig. 10).
<br />During the study, about 90 percent of the
<br />20 tons of total zinc that entered the reservoir was
<br />transported out of the reservoir, indicating that the
<br />reservoir was a sink for only a small fraction of zinc
<br />(table 5; fig. 15). About 60 percent of the annual
<br />total-zinc load was transported out of the reservoir
<br />between May 15 and July 14,1994, during the peak
<br />and post-peak snowmelt periods. Another 23 percent
<br />of the annual total-zinc load was transported out of the
<br />reservoir during the summer-flow period from July IS
<br />through the end of September 1994.
<br />
<br />SUMMARY
<br />
<br />Terrace Reservoir is a small irrigation reservoir
<br />located on the Alamosa River at an elevation of about
<br />8,550 ft above sea level in the San Juan Mountains in
<br />Conejos County, Colorado. The Alamosa River and
<br />Terrace Reservoir are the primary sources of water
<br />for crops and livestock in the southwestern part of
<br />the San Luis Valley. Much of the drainage basin
<br />upstream from Terrace Reservoir contains extensive
<br />areas of mineralized rocks that in some places have
<br />been mined and that contribute a substantial metal
<br />load to Terrace Reservoir. Gold, silver, copper,
<br />and lead mining have occurred in the basin for more
<br />than 100 years, and extensive mining activities have
<br />occurred intermittently at the Summitville Mine.
<br />Historically, the Summitville Mine site has produced
<br />highly acidic, metal-enriched water that drained from
<br />the mine site into Wightman Fork and flowed to the
<br />Alamosa River and Terrace Reservoir.
<br />A comparison of the streamflow hydrographs
<br />upstream and downstream from Terrace Reservoir
<br />indicated that from April I through June 8, 1994,
<br />the volume of water released from Terrace Reservoir
<br />
<br />was within 5 percent of the volume of water that
<br />entered the reservoir. During the post-peak snowmelt
<br />and summer-flow periods, more water was released
<br />from the reservoir than entered the reservoir due
<br />to downstream irrigation demand. During the
<br />base-flow and early spring snowmelt periods from
<br />October I, 1994, through March 31, 1995,46 percent
<br />more water entered the reservoir than was released
<br />from the reservoir. Over the entire study period, there
<br />was only a small difference between the volume of
<br />water that entered the reservoir and the volume of
<br />water that was released from the reservoir.
<br />During the study period, pH immediately
<br />upstream from Terrace Reservoir ranged from 4.3
<br />to 7.8. The highest pH occurred during the pre-peak
<br />snowmelt period; the lowest pH occurred during storm
<br />runoff during summer. Downstream from Terrace
<br />Reservoir, pH ranged from 4.6 to 7.6. The highest pH
<br />occurred during the pre-peak snowmelt period, and the
<br />lowest pH occurred during summer in mid-July.
<br />Large spatial and temporal variations in concen-
<br />trations of the metals of concern occurred during the
<br />study. The median and maximum concentrations of
<br />dissolved and total aluminum, iron, copper, cadmium,
<br />manganese, and zinc were larger upstream from the
<br />reservoir than downstream from the reservoir.
<br />Upstream and downstream from Terrace Reservoir, the
<br />largest concentrations of dissolved aluminum, iron,
<br />copper, cadmium, manganese, and zinc generally
<br />occurred between mid-June and November. Upstream
<br />from the reservoir, the largest concentrations of total
<br />aluminum, iron, copper, cadmium, manganese, and
<br />zinc generally occurred between July and September
<br />during storm runoff. After November, dissolved-
<br />and total-metal concentrations generally decreased
<br />downstream from the reservoir after the closure of
<br />the reservoir outlet works.
<br />Throughout the study, aluminum was
<br />transported into the reservoir predominantly in
<br />the particulate or suspended form. Downstream
<br />from the reservoir, the suspended-aluminum fraction
<br />was predominant only during the pre-peak snowmelt
<br />and peak snowmelt periods. After June 8, most of
<br />the aluminum that was transported out of Terrace
<br />Reservoir was in the dissolved fraction. During the
<br />pre-peak snowmelt and peak snowmelt periods, more
<br />than 90 percent of the iron was transported into the
<br />reservoir in the suspended fraction. However, the
<br />dissolved fraction of iron generally increased to more
<br />than 50 percent during the post-peak snowmelt and
<br />
<br />36 Assessment 01 Metal Tnlnsport Into Ind Out 01 TlrrlCl RISlrvolr, Conllos County, Colorodo,
<br />April 1994 Through Mlrch 1995
<br />
<br />r'0319~1
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