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<br />Upstream from Terrace Reservoir, total-zinc loads <br />increased substantially during rainstorms during the <br />summer period. Most of the total-zinc loads that <br />entered the reservoir during rainstorm runoff did not <br />appear to have been transported out of the reservoir <br />(fig. 15). The smallest daily zinc loads occurred <br />during the base-flow period between November 1994 <br />and February 1995 (fig. 15). <br />During most of the study, zinc was transported <br />into and out of the reservoir mostly in the dissolved <br />fraction (fig. 10). However, during the pre-peak and <br />peak snowmelt periods, about 30 percent of the zinc <br />generally was transported into the reservoir in the <br />suspended fraction (fig. 10). <br />During the study, about 90 percent of the <br />20 tons of total zinc that entered the reservoir was <br />transported out of the reservoir, indicating that the <br />reservoir was a sink for only a small fraction of zinc <br />(table 5; fig. 15). About 60 percent of the annual <br />total-zinc load was transported out of the reservoir <br />between May 15 and July 14,1994, during the peak <br />and post-peak snowmelt periods. Another 23 percent <br />of the annual total-zinc load was transported out of the <br />reservoir during the summer-flow period from July IS <br />through the end of September 1994. <br /> <br />SUMMARY <br /> <br />Terrace Reservoir is a small irrigation reservoir <br />located on the Alamosa River at an elevation of about <br />8,550 ft above sea level in the San Juan Mountains in <br />Conejos County, Colorado. The Alamosa River and <br />Terrace Reservoir are the primary sources of water <br />for crops and livestock in the southwestern part of <br />the San Luis Valley. Much of the drainage basin <br />upstream from Terrace Reservoir contains extensive <br />areas of mineralized rocks that in some places have <br />been mined and that contribute a substantial metal <br />load to Terrace Reservoir. Gold, silver, copper, <br />and lead mining have occurred in the basin for more <br />than 100 years, and extensive mining activities have <br />occurred intermittently at the Summitville Mine. <br />Historically, the Summitville Mine site has produced <br />highly acidic, metal-enriched water that drained from <br />the mine site into Wightman Fork and flowed to the <br />Alamosa River and Terrace Reservoir. <br />A comparison of the streamflow hydrographs <br />upstream and downstream from Terrace Reservoir <br />indicated that from April I through June 8, 1994, <br />the volume of water released from Terrace Reservoir <br /> <br />was within 5 percent of the volume of water that <br />entered the reservoir. During the post-peak snowmelt <br />and summer-flow periods, more water was released <br />from the reservoir than entered the reservoir due <br />to downstream irrigation demand. During the <br />base-flow and early spring snowmelt periods from <br />October I, 1994, through March 31, 1995,46 percent <br />more water entered the reservoir than was released <br />from the reservoir. Over the entire study period, there <br />was only a small difference between the volume of <br />water that entered the reservoir and the volume of <br />water that was released from the reservoir. <br />During the study period, pH immediately <br />upstream from Terrace Reservoir ranged from 4.3 <br />to 7.8. The highest pH occurred during the pre-peak <br />snowmelt period; the lowest pH occurred during storm <br />runoff during summer. Downstream from Terrace <br />Reservoir, pH ranged from 4.6 to 7.6. The highest pH <br />occurred during the pre-peak snowmelt period, and the <br />lowest pH occurred during summer in mid-July. <br />Large spatial and temporal variations in concen- <br />trations of the metals of concern occurred during the <br />study. The median and maximum concentrations of <br />dissolved and total aluminum, iron, copper, cadmium, <br />manganese, and zinc were larger upstream from the <br />reservoir than downstream from the reservoir. <br />Upstream and downstream from Terrace Reservoir, the <br />largest concentrations of dissolved aluminum, iron, <br />copper, cadmium, manganese, and zinc generally <br />occurred between mid-June and November. Upstream <br />from the reservoir, the largest concentrations of total <br />aluminum, iron, copper, cadmium, manganese, and <br />zinc generally occurred between July and September <br />during storm runoff. After November, dissolved- <br />and total-metal concentrations generally decreased <br />downstream from the reservoir after the closure of <br />the reservoir outlet works. <br />Throughout the study, aluminum was <br />transported into the reservoir predominantly in <br />the particulate or suspended form. Downstream <br />from the reservoir, the suspended-aluminum fraction <br />was predominant only during the pre-peak snowmelt <br />and peak snowmelt periods. After June 8, most of <br />the aluminum that was transported out of Terrace <br />Reservoir was in the dissolved fraction. During the <br />pre-peak snowmelt and peak snowmelt periods, more <br />than 90 percent of the iron was transported into the <br />reservoir in the suspended fraction. However, the <br />dissolved fraction of iron generally increased to more <br />than 50 percent during the post-peak snowmelt and <br /> <br />36 Assessment 01 Metal Tnlnsport Into Ind Out 01 TlrrlCl RISlrvolr, Conllos County, Colorodo, <br />April 1994 Through Mlrch 1995 <br /> <br />r'0319~1 <br />