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<br /> <br />Agti4tZ~ Standards Laboratory for Jli.t.J:llte for <br />quality control evaluation. <br /> <br />In addition to the inorganic parameters, all of <br />the groundwater samples collected were analyzed <br />for selected pesticides, The pesticide analysis was <br />performed by the Colorado Department of <br />Agriculture Standards Laboratory, A listing of <br />pesticides was compiled for analysis based on those <br />substances that have recently been, or are currently <br />being utilized in the Arkansas Valley according to <br />agricultural officials there. Budget restrictions <br />would not allow testing for all pesticides used in the <br />study area, To reduce the analysis cost, each <br />pesticide was weighted according to its chemical <br />properties of persistence and mobility in the <br />environment, amount of active ingredient used per <br />acre, and the amount of acreage within the study <br />area that pesticide was used on, Pesticides were <br />then selected according to their final score and the <br />ability of the laboratory to detect their presence. <br /> <br />The results from this sampling program have <br />been entered into the C.OPHE Grollnrlwater Quality <br />Data System, a database located at CDPHE. A <br />detailed reoort describing the area sampled, the <br />(Protocol fui- sampling and analysis, and the results <br />of the analvsis was provided to the Commissioner <br />of Agriculture in early 1997. <br /> <br />~ <br /> <br /> <br />.Re$'ult$~f~~esticideAn~I~ <br />, ':F"i".t ^ , , <br /> <br />, 'Pesticicl~: . <br /> <br />Use <br /> <br />Herbicidlil' <br />Herbicide' <br />Herbicide <br /> <br />Atrazine' . <br />MetolacHlbl" <br />2;4-D ' <br /> <br />Analysis of laboratory results for the Arkansas <br />Valley indicates that ground water in parts of the <br />study area has been impacted by various <br />agricultural chemicals. The maior inorganic <br />contaminant of concern is nitrate. Nineteen of the <br />one hundred thirty nine wells sampled (1~) <br />showed nitrate levels in excess of the EP A standard <br />- <br />for drinking water (10 mg/L). The drinking water <br />standard is used as a benchmark for nitrate levels in <br />all wells regardless of use because the alluvial <br />aquifer is a significant source of drinking water in <br />the valley. Twelve of the one hundred thirty nine <br />samples ( 9%) showed oositive for the herbicide <br />Atrazine. One sample detected the herbicide <br />Metolachlor and one sample detected the herbicide <br />2,4-D. AILPesticide detections where well below <br />the drinking water standard. <br />" <br /> <br />A confirmation sampling was performed on <br />those wells that had a nitrate level above 10 mg/L, <br />or a pesticide detection in 1994. The confirmation <br />sampling tested 32 wells and found little change <br />from 1994, indicating a high level of confidence in <br />the initial work. Nitrate levels were statistically <br />unchanged and the only pesticide detected was <br />Atrazine. One well did contain Atrazine at a level <br />above the standard of 3.0 ug/L. <br /> <br />""'ot;i;~:>~"; 0 <br /> <br />~'o',o /~ <br /> <br />,(j):O$ <br />'OM <br />'0' c'O"2^" <br />0, ,.,. _' '0:,-', <br />, " .". ,. <br />,m, ,0 '. '., ' <br /> <br />'>1>2 '.. <br />,.'m;,i'.',' <br />'1",' <br />-'-,-,' <br /> <br />~m()unts aregivenih'Mi~rograms peiHter.orp~~^~'r/ilet::billion\", .. <br />, .', -', ,,'_,,-, '_ :..._ -, \_ c~'_,' j<J':'<'",_ _ _ ,,_ ~ _"':-"-"^"<,^ _, '//e"o,,;Lx^' ;,:,,,-:,:-,'0_',,_,>:,_ ___'__',__':_"_,<, <br />DLi-MinimUmc\ln~~fI~.~tion that canOedi'll' -'\ ":ffjell3,bOratorY <br />Met~The maximum:'iimountallowed'inarfhkln Sr" \' <br />, ", ., .: " :,J~~~:~L": -, " "- -, -":'''':::<' .;.<.H <br /> <br />, :"'-,,., <br />,J,' ):5.:~~::t}~:Y;- <br /> <br /> <br />Page 3 <br /> <br />l . <br />),--"",'--.-_;~~'(:J!_:,~" . <br />'., ",-.' ,-,,t.,,,-lnk:, . _ -"'<<,,, , <br />~_".:,.<J,~.l_.',-'tfi-"):t>' "'_"~."'_ <br /> <br />-"";:0"_,0 <br /> <br />