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<br /> <br />ether, ethyl tert-butyl ether (ETBE), <br />ethyl benzene, toluene, xylene, <br />methyl tert-butyl ether (MTBE), <br />and methyl tert-pentyl ether. Three <br />samples were collected from the <br />Tar River at sites 14 (two samples) <br />and 16. A sample also was collected <br />at site 40 on the Cape Fear River. <br />The only compound detected was <br />MTBE at sites 16 (57,8 ng/L) and <br />40 (36.3 ng/L). However, such lim- <br />ited sampling, in terms of frequency <br />and areal coverage, cannot provide <br />an accurate assessment of the <br />impact of fuel spills on floodwater <br />quality. <br /> <br />Nitrogen and Phosphorus <br />Loads <br /> <br />A load is an estimate of the total <br />mass of a constituent passing a <br />selected stream location during a <br />given period of time. For example, a <br />nitrogen load calculated for the Pam- <br />lico River at Washington provides an <br />estimate of the total pounds of nitro- <br />gen entering the Pamlico River <br />estuary during the period of interest. <br />Loads from different size basins can <br />be normalized by dividing the load <br />by the basin area, providing a yield <br />(in, for example, pounds per square <br />mile per year), so that export from <br />different basins can be compared. <br />There is some uncertainty in the <br />calculation of floodwater loads <br />because of the small number of <br />water-quality samples used in the <br />calculation. However, as a result of <br />the relatively small variation at a site <br />in constituent concentrations during <br />flooding, the calculated loads seem <br />to provide reasonable estimates of <br />basin export. <br />Nitrogen and phosphorus loads <br />were determined at selected loca- <br />tions for September 15-0ctober 20, <br /> <br />1999, by using calculations of mean <br />daily discharge and periodic mea- <br />surements of concentration. The <br /> <br />('''' <br />'.l ;,~:' .~:.. <br />: ._ ,~f' .:.~:. <br />......"r,r.~ 'i <br />.' ~';;.. :~ s' <br />" <br /> <br />~ <br />t <br /> <br />. '1'(::. <br /> <br />oj <br /> <br />" <br /> <br />mean discharge data were not <br />available, an estimate of monthly <br />mean discharge for September and <br />October and the <br />median of water- <br />quality data from <br />samples collected <br />by the North <br />Carolina Division <br />of Water Quality <br />during September <br />and October <br />(Larry Ausley, <br />Division of Water <br />Quality, written <br />commun" Janu- <br />ary 2000) were <br />used to calculate <br />the nitrogen and phosphorus yield for <br />September and October. <br />The cumulative load of nitrogen <br />in Hurricane Floyd floodwaters <br />ranged from 450 tons in the Lumber <br />River (site 45) to 4,200 tons in the <br />Neuse River near Fort Barnwell <br />(site 32, fig. 15). At Kinston (site 28), <br />a nitrogen load of about 1,700 tons, <br />equivalent to half ofthe mean annual <br />nitrogen (3,400 tons; Harned and <br />others, 1995), was carried by <br /> <br />__ ____,~;-.:,.r-~-- <br /> <br />'~'~~c;l <br /> <br />1011 <br />1999 <br /> <br />Figure 15. Cumulative total nitrogen load at sites near the mouths of the Tar. <br />Neuse. Cape Fear. Northeast Cape Fear. and Lumber Rivers, <br /> <br />Black River near Tomahawk, N.C. <br /> <br />36-day period used for the load <br />calculations includes the rise, peak, <br />and fall of floodwaters from Hurri- <br />cane Floyd. At most sites, subse- <br />quent rainfall from Hurricane Irene <br />(October 17-18) caused secondary <br />flooding (for example, figs. 8 and 10) <br />that was not included in these load <br />calculations because concentration <br />data were not collected during this <br />secondary rise. For the Pamlico <br />River at Washington where daily <br /> <br />4,500 <br /> <br />4,000 <br /> <br />~ 3,500 <br />a <br />~ <br />z <br />~- 3,000 <br />'" <br />g <br />aJ 2,500 <br />~ <br />a <br />~ <br />~ 2,000 <br />w <br />> <br />~ 1.500 <br />~ <br />::; <br />131,000 <br /> <br /> <br />500 <br /> <br />9119 <br /> <br />9123 <br /> <br />9127 <br /> <br />Two :'vlomhs of Flooding in Eastern North Carolina. September-October 1999 <br /> <br /> <br />-NeuseRivernear <br />FtBarnwell <br /> <br />Tar River at <br />Greenvilll! <br /> <br />Northeast Cape Fear River <br />_ Cape Fear River at nearChinqllapin <br />Lock 1 I <br /> <br />Lumber River at Boardman/ <br /> <br />10/5 <br /> <br />10113 10/17 <br /> <br />10/9 <br />