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<br />This was compared with observations of the lead content in snow, <br /> <br /> <br />water, and ice sampled on road surfaces and adjacent areas. <br /> <br /> <br />Concentrations of lead from road edges averaged 5.5 mg/l, ranging <br /> <br /> <br />from 3.6 to 8.5 mg/l. Again, concentrations of lead in samples <br /> <br /> <br />taken at points away from the roadbed decreased with increasing <br /> <br /> <br />distance from the roadbed. A value of 0.09 mg/l was reported <br /> <br /> <br />for lead concentrations in a sample obtained from an "open field <br /> <br /> <br />surrounded on three sides by heavily traveled streets". Observa- <br /> <br /> <br />tions were compared with the theoretical value and a number of <br /> <br /> <br />factors were suggested to explain the differences. <br /> <br /> <br />Bryan (1970) in his original Durham, N.C. study on urban <br /> <br /> <br />runoff, noticed erratic BOD results. Exploratory work indicated <br /> <br /> <br />"evidence of toxicity to the reaction (BOD) detected in some <br /> <br /> <br />samples which upon further exploraticn revealed presence of lead <br /> <br /> <br />at concentration levels in the order of 1.0 mg/l." A subsequent <br /> <br /> <br />study on the same drainage area revealed lead concentrations in <br /> <br /> <br />the storm water runoff to range from 0.10 mg/l to a maximum value <br /> <br /> <br />of 12.6 mg/l. The yield of lead from the predominantly residential <br /> <br /> <br />area within the drainage basin was one-half of that from the more <br /> <br /> <br />commercially developed area, and was almost exactly in proportion <br /> <br /> <br />to the percentage of paved surfaces (Bryan, 1972). In addition, <br /> <br /> <br />the yield of lead presumed to originate from "internal combustion <br /> <br /> <br />engines operating on and near the basin was determined to be <br /> <br /> <br />0.0006 Ib/day/acre (0.00067 kg/hectare/day)." <br /> <br />C. Effects of Storm Pattern <br />Several researchers have investigated the relationship of <br />duration and intensity of a storm with the resulting runoff <br /> <br />23 <br /> <br />~ <br />