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<br />, <br /> <br />within a short distance of the roadbed as well as escaping into <br /> <br /> <br />the atmosphere. The lead accumulates on the surface of streets <br /> <br /> <br />during dry periods and then is transported to surface streams <br /> <br /> <br />during periods of runoff (EPA, 1972, 1973). Quite naturally <br /> <br /> <br />then, the levels of lead in snow along city roads are roughly <br /> <br /> <br />proportional to the traffic volume. Lead bromide chloride has <br /> <br /> <br />been shown to be the major lead containing product in automobile <br /> <br /> <br />exhaust, with PbC03 and PbO also forming on contact of the exhaust <br /> <br /> <br />fumes with snow. <br /> <br /> <br />The lead appears to be adsorbed on the particulate present <br /> <br /> <br />in the snow, as confirmed by adsorption studies. LaBarre, Milne <br /> <br /> <br />and Oliver (1973) conducted a study of the concentration of lead <br /> <br /> <br />in snow in an urban center, in order to assess the effects of <br /> <br /> <br />snow disposal practices on water quality. They showed the level <br /> <br /> <br />of lead in snow along city roads to be roughly proportional to <br /> <br /> <br />the traffic volume. Also in sampling of lead concentrations of <br /> <br /> <br />snow in 11 city snow dumps the average value was found to be 4.8 <br /> <br /> <br />ppm. Snow collected from city roofs 325 and 40 ft in height, <br /> <br /> <br />contained 0.02 and 0.25 ppm lead, respectively. By comparison, <br /> <br /> <br />snow along roads and in snow dumps is severely contaminated with <br /> <br /> <br />lead from automobile exhausts, as seen in the following table. <br /> <br /> <br />Newton, et al. (1974) presented observations of lead con- <br /> <br /> <br />centrations in street runoff. Data from automotive emissions and <br /> <br />knowledge of daily vehicle travel in the Oklahoma City drainage <br />basin studied provided them with a theoretical value of 0.23 mg/~ <br />based upon uniformity of precipitation over the drainage basin. <br /> <br />21 <br /> <br />... <br />