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<br />EVt,J.llt.TIII'; Ill" I.CfJ!.fl\:tCAI. l:HFTI~ il~ !;lI.VI.I: IllilflJE SEEDING AGENT).! <br />POllllld \. r]plll?.' .111.1 1'];'11,11.1 S..hll <br /> <br />ABSTRACT <br /> <br />The possible effects of sUver iodide Sf'f"d 1 liP, af.!ellt <br />accum.ulation in surface soils of the SiW Juan arelt <br />were investigated by use of lAboratory !Hudlefl In- <br />volv1ns Arthrobacter - silver internct Ions, trentmt>lll <br />of .01111 with varied formn And I~V(>JR tlf 1'I11v(>r. hy <br />eX8mination of silver Rr8dlent~ surrolllldlllg 6(!edillp, <br />generator sites, and by use of trClltm~lll pIotR III <br />Rpruce, aspen, and JIIubalplne mefldow cuml1llllllt 11:'." <br />located ill the San Juan snow uugmcntllot lUll IHN" I,nb" <br />oratory studies have shown that on 8 shoTt-term basis, <br />silver iodide or seeding generator burn mixtures nt <br />higher than field concentration show onlY slJght <br />effects on microbial Rrowth or enzyme function, while <br />free silver ions. even at part-per-billlon levels. <br />can cause marked' changes in microbial activities. <br />These etfecu were 1"~8ened in the presence of soil or <br />complexing 10na. However. under field conditions on <br />a 3 year basis. .1Iver iodide appears to have a great- <br />er potential for alterinR soil decomposer functions <br />than silver from .ilver ion. The presence of silver <br />from silver iodide - sodium iodide complexeR. BRAin lit <br />hlfl.her than bac~sround levelR. In the' !inn .1111111 tf1r~p.1 <br />IIreR I(>d ro" graduaJ IlIl'rl'IIRt:' III null 01"1(111111' mllltl'"l <br />content III spruce and aspen 8'Il"fflt"t' sulIs. Nil !411l'h <br />lncr-ellse WIUiI ob..rved In the f1uhn] piliP Inl'lhll1\J plot, <br />Silver from silver nitrAte telld~d tll CO'll:~lltrllt(' mllrr <br />in upper plant portionll thAn ullver from sllvpr 111111111"'. <br />although silver from silver iodide waa more C losl'lly <br />usociated with the plant roots. These effects, were <br />only observed using sUver levels IO-lOOX expected <br />field Accumulation levels. BlIsed on the available <br />Uterature and experiments carried out to date, the <br />accumulation of silver iodide seedJIlR agent tllleA 1I0t <br />Appear to present an ecological thre/lt, altluHIRh cun- <br />tinual monitor ins of test systems should he I:llrrlecl <br />out to extend t:he time period over which thlll ('011<"1,,- <br />slon can be tested. <br /> <br />OBJECTIVES ANT> HYPOTHESES <br /> <br />1. <br /> <br />To monitor soil microbial activities In the Sail <br />Juan area, to determine if possible sIJlv~r~~~c~e- <br />tion is influencing soIl microbial,processes. <br />ro analvzG traatment plot 80!I. to ~~lc~~~~!OUR <br />sUver addItons have been maae-rn-ispen. spruce, <br />;nd grass communities. ---".,-" <br />To measure mlcToblal responses [0 silver jo;\'AdieOlf; <br />p~-~sent In the vicinity of the Pagos.. SprIngs sell;';' <br />era tor site No. 25, and the Emerald t1ounFnl""il:li:e. <br />To-determine the existence ot possiDli"fiiiS=1eflilil <br />e1 fects at variea SlIver l.e\'e1.8 ana Iorms -on---- <br />microbial processes, intluding ertetts on mICfotir= <br />al viability and capabilities to transtorm 9ij6~ " <br />.strates requiting enzymatlc adaptatIon a~~"~~~(~~-, <br />production processes. <br />To determine if soil microbes are capable of <br />transforming silver present as silver iodide'to <br />additional .Uver forms. and to determine phyilo-:" <br />logical mechDnisms which may reBu1l In ~~l~~ <br />transformations. <br />To determine if a"ssoy prot.:edul"cs ro~"_~!..~I_~v_~~ <br />(orms 1n 8011 ('Rn be Jev~lope~_._" <br /> <br />2. <br /> <br />1. <br /> <br />4, <br /> <br />s. <br /> <br />h. <br /> <br />These ubjectives hav~ <br />hypotheses: <br />""HYPllliletlii9 I. <br /> <br />been Stllnm.ur I z ed <br /> <br />in ,1 !l,~rie. of <br /> <br />Accumulation or NJlver iodide rr... <br />weather modlftca[ion will re.ult in no <br />overt toxicity effect., bot may r~~\llt <br />in a slight delay In bloloS1c.l <br /> <br />Hypothesis 11. I.nborstory studies Cal\ give all 111(11(:;1- <br />tion of the degree of possible dlmin- <br />tllltton of microbial activity which <br />might result (rom sl1ver accumulation. <br />: Ilvpnth"fl!R III. Soil btlcterlA CAn caU8e H change ill <br />~ilver iodide to form8 more ensily <br />111kp.1l lip by plAnt~. ,'blR mntlifjrl1tlnll <br />of l'itlver farm milY mn\<e iL lICCC!5~j,1ry <br />tu carry out experiments tinder field- <br />relnted conditions All much 118 p08Rthlfl. <br /> <br />""""A"' -II" ~'Y'''S ~~C '/-,onS 0,..; rreJ.-' <br /> <br />1l;ISl!J (Ill work carried out on the possible ecoJop.ic.1l <br />effects of silver iodide seeding agent accumulation in <br />soils of the San Juan area, the following conclusions <br />'":111 IH' dralJt\: <br /> <br />I, ]'!,=_sccutJIulation of silver iodide nuclea~J..f.!..~al!!l!~ <br />prf'Sf'nts tlO overt danger to humans. plants or ani-_ <br />mals, hascd on available literature and work ~a~: " <br />~!~_~~.':.._~!!!t1l'l' Llds study for a 3 Year oeriod~~." <br />" ~iJ lVl'r 1"'1 ('nil t'(lllf:P decreased ~ro\.l'th /llId enzymE' <br />fiiJlicf"TOii- ~~"~~ 1ll:?J! Arthrobact:cr _~p'ec~_~~ ~t" i-IO <br />pph free ~liv~r ion. The effect. observed (~ del'N\- <br />d('lIt "" ;tlill:j:" :.;1 i;'IIA Rnd CRt Ions prest'nt. So 11 <br />dccn'AflpfI thp /let jvJty of free Ililver Ions. <br />l. SJlvl'r (rum I'lllvE'r iodide or hurn mixtures dop.tiI <br />uil1 iiftnloiA"iiai-TIrr'ctH on fIllcrot'lanrnilUfcrr lh:':' <br />7.yml-lilr.-iirrfV'rty:--r.enerolly 10-100 _epm" af'Ag! <br />foFiil"iiflvcr-lir'req"iiired to oEi~-eHect$ on <br />growEfi. -vJn6lTIty, and enzyme Induction;-'- <br />I." F'i~P.RfT\i"rIOll from Bllver iodide dIesocial Ion at <br />')-fl pph ('1111 ,';'1116(' l,bservable effects on mfcnl_ <br />orRAllt8ms. To Rchieve this slIver level <br />100-200 "pm or silver A8 sUver iodide i1re re- <br />(Iulr('d. <br />S. Micruoq~Bll16m9 call cause reduction of free stiver <br />Ion or Allver fodJde to metallic silver. Amine- <br />type mAterJalA moy be respansible for this reduc- <br />tion. <br />6, Silver iodide added at 1000 ppm shows no immediate <br />~ffects on 80il resoiratlon processes. <br />1. Attempts to estsblish respiration indices tor test <br />Aoils acr08S the impact area vere not successful <br />due to short-term variability of soilqttoJature and <br />tempf!r4ture. <br />fL Silver accumulation in the vicinity of two seeding <br />generator sites did not cause decreases in m1cro= <br />blal respirAtion. Silver tended to sccumulnte"and <br />remain in the aureate 8011 zone In eplte o(""iH(~ <br />tin~w4ter percolatIon throuRh tha tone. <br />9. ^ ~ sub81pine lIleadow teatp!Oi-fii8t'aUed -tor .1 years <br />using sliVer iodide and stIver nttr.te at 1. 10.-- <br />100 ppm surface soil levels did not show changes <br />~ecomposer functions which could be rel~.te4."-_fo" <br />this treatment. <br />10. STIVir-rr0m-811ver iodide moved to upper plant por- <br />t Ions to a hsser extent than silver from silver <br />nitrate. <br />11. Siiver from silver iodide vas more closely a9socl- <br />."lted wJtll plant roots than silver from silver Ion. <br />12. Artel' 1 years, sHYer from these two differing <br />orlglnHl forms have not equilibrated to forms <br />which w11l gfy~ similar activities. <br />11. In spruce and a.pen plots, imposition with silver <br />Iodide tends to be related to Increased organic <br />m.tt.r r.t.ntlon In the test 8yatems. No such <br />r.tation.hips were observed with equivalent treat- <br />ment. uaing silver from sIlver nitrate (slIver <br />Ion). <br /> <br />J) tn Steinhoif, n.~"., and J.D. hes (Ed.). 1916. F.colo~ical Impact.s of sno\lpack <br />Mountains, Colorado. San Juan Ecolop.y Project, Final Report. Colorado Stllte <br />J/ Present address; Dept. of Hicroblolop.y, Colnudo State Unlv.. ~t. CoJlins, Co. <br /> <br />augm.entation <br />Univ. Publ., <br />80523. ' <br /> <br />l.n the San JUAn <br />Fort ColUns. <br /> <br />12' <br />29 <br /> <br />A-Bd-2 <br />