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<br />GROV"Dlf:~lER Ja.-wt:sa TUfF. A.\D RECfU/lGF. Ta{pF.R~nRE Em.\um OF THE DE\l"ER A.\VAI/.-tP..vfOE AQl1Ffk>, DE.\lTR /liSL\, COLORADO <br /> <br /> 12 <br /> 10 ---I-- <br /> a <br />IT <br />. <br />- <br />. <br />, 6 <br />~ <br />~ - -- -- tr - -t-- <br />~ 4 <br />~ <br /> 2 <br /> 0 <br /> 0 5 10 15 20 25 30 35 <br /> Timefka} <br /> <br />Figure 2. Recharge temperature of groundwater ~mples (solid <br />squares) and uncertainty (error narsl, Denver and Arilpilhoe <br />aquifers, Denver Basin, Colorildo, and glacial and Holocene tem- <br />perature estimates (dashed lines) reconstructed from mean annudl <br />modern temperature (solid diamond) and glacial ternper.1ture <br />depression of SSe. <br /> <br />Samples from wells farther toward the cenler of the ba~in. <br />regardless of aquifer, have apparent rt'"~idence times of <br />22,000-24,CXXJ years. The sa.mple from The Pinery (PIN-02) <br />.~howt'd an e~timated residence time of gre;lter than 30,ono <br />years. but there were some prohkm~ a.,..,udated with the <br />analysis of this ~ample. In a qualit.lIive ~n~c. the apparent <br />residence times art' wh;1l would be expened, with the <br />younger water toward the outcrops (R"charge area) and <br />the okkr waters in the middle of tht' basin. <br /> <br />F~"itimatro PaJeotemperalUrt."'!' <br /> <br />The estim:lll.->d temper.llures at the time of recharge are <br />shown in Table 4 They range from 1.5 to 9.irc. nle 1..1 <br />values of all s3mpk.. were lx'low or very nl~.lr j.8.i, the <br />kvel of 95% probahility for the modd. Tht'~t' rt:"Sult~ ~llH- <br />gest that the me3n elt'vation<.; u.<.;('d 3re reasonable, that me <br />exces....-air ('omponent of the ....3mpks is not fr,K1ion;lted, <br />and the estimated recharge tempt'r.ltures are fl.-'a.sonahle. <br />The uncenaimy in derin:"C1 redurgt..' temper.Hurl." rl'<.;ulting <br />from Ihe level of inslmment precision \u:-- caku\att'd :I." <br />0.9'C C\13nning and Solomon, 200},. }kcakubtinK <br />rech3rge temperature with minimum and maximum I;'kva~ <br />tion... was used to estimate um:l'naimy in redlarge tempt'r~ <br />atur!;" resulting from Ihe assumplion of rt"t.:harge elevation <br />(T3ble .n. Tht..' sum of Ihese \\'a.... lISl.-oJ to approximate {he <br />total unn.'Tt.1.inty in redlarge leffipt-'r:llure in this study, <br />Recharge k'mperatures and uTKert3imks werl' ploned <br />with estimates of modern and gbci:ll tl'mperalures (Fig, 2). <br />The S3mple from Donab (DO:'-J-04) j,<.; wry dos\:." to thl' <br />modem lemperatlln.: in the fl.-'('harge ;trea as would be pre- <br />dicteti by 3 residem'l.-' timt' thaI is younger than the end of <br />the last g1adal period. The recbarg\:." k'mper,Hures of tilt" <br />mher s3mples :lre 311 lower than thl.-' modt.'m {emlwr.lIure, <br />The re..idence time." :100 lower rt..'charge temper.ltur\:."s of <br />Ihe.'>C samples ~uAAe...t th\:."Sl' were rechar~t'd during Ihe 1:1"t <br />gbcial period. S3mples PARK-01 amI AL'R..{)7 havt' <br />recharge temperatures that art' significantly grl':Her than <br />the estimated glacial tcmpcralllre. This t'ould reflect signifi- <br />cam tl.'mpcr3ture IluchJ3lion.. within Ihe gbdal period, <br />mixing of Hol(Kenl' Kfoundw:ller and'or lhe dillllion of <br />He activity th3t 11l3ke... lhe gruunowatt,:r 3ppear 'old: The <br />Lltler explanation ,"llggesb Ihal residence times could he as <br />YOllng :IS the t'nd of the Iasl glacial period, <lpproxim.J.tcly <br />12 ka in Colorado, \'(11ik confined conJitions are observed <br /> <br />Table 3, <br />laboratory analysis results and field measurements of groundwater conditions; He reported in percent modern carbon (pmC); <br />relative HC/ne reported as delta 13-carbon per mil VPDB (olle %oj; IOIilI dissolwd gas pressure (Pl[x,J. <br /> <br /> Field <br /> Rel.llive Gas Concentrations DIC Measuremenls <br /> 28N1 ]102 "OAr ~K, lONe 'H. 'H. "C bIle T PTDG <br />Sample Aquifer 10' ,0-' ,0-' ,0-' lO's 10.11 ,.,.. (pmCl 1%.) rCI [alml <br />DQN-04 Arapahoe 0.95 5.]8 1.05 6.98 2.05 0.89 0,1& ]].] -13.0 15.5 0.908 <br />PIN-02 Arap.ahoe 0.99 0.55 1.15 8.49 1.52 1.92 1.5] <2.27 .12.7 22.4 1.119 <br />PARK-Ol Arapahoe 0.97 192.01 1.08 8.00 1.72 ].19 1.11 4.59 -13.0 28.7 1.155 <br />AUR-08 Arapahoe 1.00 3,55 1.14 8.44 0.97 513 2,33 5.&0 -10./! 30.2 1.122 <br />PARK.O] Denver 0.99 0.27 1.07 7.69 1.57 1.65 5.13 ..\.57 -13.2 29.7 1.050 <br />AUR-07 Denver 0.86 ].46 0.95 6.67 0.86 O.B] 2.71 5.00 -9.7 17.9 1.012 <br /> <br />165 <br /> <br />TIlt' l(()("kv ,\Iounum A~"'>CI~h"n oj ("-'O[(~I<ts <br />