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<br /> <br />Pesticides were identified through solvent <br />extraction followed by gel permeation chromatog- <br />raphy, followed by additional alumina-over-silica <br />column chromatography with quantification through <br />dual capillary-column gas chromatography with <br />electron-capture detection (Furlong and others, 1996). <br />PCBs in bottom sediment were identified through dual <br />capillary-column gas chromatography with electron <br />capture detection (Foreman and others, 1995). Pesti- <br />cide and PCB analysis was done at the USGS National <br />Water Quality Laboratory. <br /> <br />PAHs were identified through solvent extraction <br />followed by gel permeation chromatography. The <br />concentration of each compound was determined by <br />capillary-column gas chromatography/mass spectrom- <br />etry (Furlong and others, 1996) at the USGS National <br />Water Quality Laboratory in Arvada, Colorado. <br />Trace elements were analyzed at the USGS <br />National Research Program Laboratory in Reston, <br />Virginia. All trace-element concentrations, except <br />chromium, lead, zinc, and mercury, were determined <br />through inductively coupled plasma-atomic emission <br />spectrometry. Chromium, lead, and zinc were <br />analyzed by graphite furnace atomic absorption and <br />mercury by cold vapor atomic absorption (Lickte and <br />others, 1987; Fishman, 1993). <br /> <br />Only core DLN (fig. 2) was representative of <br />sediment deposited throughout the existence of the <br />reservoir. Determination of the approximate age of <br />each core segment was based on measured porosity <br />(volume of the voids divided by the volume of the <br />solids) and the assumption of a constant sedimentation <br />rate from the pre-reservoir (1963) surface near the <br />bottom of the core to the top of the core (representing <br />1997). The mass of each segment was determined <br />using measured porosity for that segment, thus <br />adjusting for the effects of compaction over time. The <br />length of time to deposit each segment was determined <br />by dividing the segment mass by the average sedimen- <br />tation rate (mass per time). Calculation of the age of <br />each segment was done by subtracting the cumulative <br />deposition time of all segments above the segment <br />of interest from the sampling date. Due to compaction, <br />a segment from the bottom of the core had a lower <br />porosity than the sediment deposited at the top of <br />the core. Therefore, a I-centimeter segment from <br />the bottom of the core spanned a longer time period <br />a than I-centimeter segment from the top of the core. <br /> <br />Streambed-Sediment Samples <br /> <br />Streambed-sediment samples were collected <br />near the reservoir on each of the main three tributaries <br />(fig. 2) and analyzed for trace elements as part of <br />other studies within the UCOL. Samples on the <br />Snake River and Tenmile Creek were collected in <br />1996. Protocols and methods used for these samples <br />are described by Deacon and Driver (1999). The <br />sample from the Blue River was collected in 1995, <br />and protocols and methods are described by Apodaca <br />and others (2000). <br /> <br />Water Samples <br /> <br />Stream-water samples were collected monthly at <br />the three tributary sites and downstream from the dam <br />on the Blue River (fig. 2) over a 13-month period <br />beginning in May 1997. Samples were collected using <br />protocols described by Shelton (1994). Equal-width- <br />increment samples were processed onsite and shipped <br />to the USGS National Water Quality Laboratory in <br />Arvada, Colorado. Samples were analyzed for trace- <br />element concentrations using methods described by <br />Faires (1993) and Hoffman and others (1996). Stream- <br />water analysis data are available in the USGS National <br />Water Information System (NWIS) data base. <br />Reservoir-water samples were collected at <br />discrete depths at four locations in June, August, and <br />November of 1997. Water from a particular depth was <br />pumped to a boat and processed for shipment to the <br />USGS National Water Quality Laboratory. The same <br />laboratory methods used for the stream-water samples <br /> <br /> <br />Collecting water-quality samples on the Blue River <br />upstream from Dillon Reservoir. <br /> <br />STUDY METHODS 7 <br />