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between 0.0 and -0.3 my (extremely reducing conditions). <br />Selenium arriving with irrigation drainage waters at the <br />escarpment springs and ground water systems in the northern and <br />southern portion of the study area most likely contain selenate <br />or selenite. <br />Once this water is discharged at the terrace escarpment the <br />selenate and selenite may be biogeochemically reduced to <br />elemental selenium or selenide in the wetlands. These selenium <br />species are biologically unavailable and since they are insoluble <br />they do not occur in the water column. selenite and other <br />selenium species can also be rendered biologically unavailable by <br />formation of metal selenides, or Se-sulfides, or by selenite <br />adsorption to sediments such as Fe oxyhydroxides. Once in the <br />soil, some selenide can be biogeochemically reduced to hydrogen <br />selenide, which like hydrogen sulfide, is a gas that can <br />volatilize and leave the soil and water column to the atmosphere. <br />Thus, some selenium can be naturally removed from wetlands. <br />Our water samples report total selenium, which as described <br />above occur as several different species in the field. The <br />samples which contained high selenium concentrations occur at <br />springs and a ground water station which most likely have oxic <br />conditions. We. suspect that the selenium was in the form of <br />selenate. selenate received by wetlands may be either taken up <br />by plants and invertebrates or biogeochemically reduced to <br />elemental selenium or selenide which, being insoluble, are <br />removed from the water column. <br />Selenium (Se) distribution follows a similar pattern to that <br />of conductivity and sodium, being highest in the north (Figure <br />16). Water collected from two stations, 7 and 15, contained high <br />Se concentrations. High concentrations were also found in a <br />small pond just south of the study area. No wetland station had <br />detectable concentrations of Se. Se most likely is moving in <br />agricultural drainage waters which leached salts from the Mancos <br />Shale and flow in a generally east to west direction in the <br />northern and southern portions of the Escalante Ranch area. The <br />salts are concentrating in the briny waters of small ponds and <br />pools. Aerial photographs of the study area illustrate that the <br />terrace area directly east of the main wetlands does not have a <br />center pivot sprinkler. However, center pivots are present on <br />the terrace to the north and south of the wetland. Thus, salt <br />and selenium distributions may relate to the presence of center <br />pivots and their irrigation patterns. <br />26 <br />