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Given a constant supply of conservative chemicals, the concentration decreases <br />with increased discharge and vice versa. <br />Nonconservative constituents are those materials which, because of bio- <br />chemical reactions, change in concentration over time. Typical examples of <br />nonconservative constituents are oxidizable organic material, ammonia, and <br />dissolved oxygen. Nonconservative chemical concentrations are related to <br />streamflow by numerous mechanisms. For example, consider the factors that <br />affect dissolved oxygen concentration. The saturation concentration of <br />dissolved oxygen and the decomposition rate of organic materials are both <br />governed by temperature, and temperature is related to streamflow in several <br />ways. First, there is a greater volume of water to be heated by the sun with <br />more discharge. Second, velocity determines the travel time for a body of <br />water, and the longer it takes for the water to travel through a system, the <br />longer it is exposed to thermal gain (or loss). Third, the larger the ratio <br />between the width and depth of flow, the greater the proportion of the water <br />volume exposed to sunlight. This ratio is often increased with reduced <br />discharge. Reduced discharge generally results in higher water temperatures <br />during the summer, at least until a thermal equilibrium is reached with ambient <br />atmospheric conditions. As temperature increases, the saturation concentration <br />for dissolved oxygen decreases and the rate of oxidation of organic material <br />increases. <br />The dissolved oxygen concentration is also a function of the concentra- <br />tion of oxygen-demanding organic material. Therefore, dilution of organic <br />matter by the total discharge is an important determinant of the dissolved <br />oxygen concentration. In addition, water velocity plays a major role in the <br />dispersion of oxygen-demanding material, both locally and longitudinally. <br />Insufficient velocity allows settling of larger organic particles, which can <br />lead to the formation of sludge deposits. Higher water velocity disperses the <br />organic material over a larger longitudinal distance. This means that a <br />larger area of stream is involved in the oxidation process at higher flows, <br />reducing the demand on reaches closest to the source of the oxidizing material. <br />Finally, the rate of mechanical reaeration is a function of depth and velocity. <br />Temperature alone may have significant effects on a community, in addition <br />to its role as a driving variable in the dissolved oxygen equation. The most <br />obvious effects of temperature are on survival and growth of aquatic organisms. <br />Less obvious is the effect of temperature on the timing of the life history <br />stages of a species or species phenology. <br />The metabolic rate of all coldblooded animals is directly related to <br />temperature. A disruption in the thermal regime of a river may make certain <br />stream reaches uninhabitable for some species, but not for others. In some <br />cases, the temperature may be so high that a reach will be totally uninhabit- <br />able or so low that growth is impaired. Alternately, a source of very warm or <br />very cold water may block the migration of a species into upstream areas where <br />the habitat is satisfactory. The longitudinal distribution of a species <br />implies at least some avoidance of areas where temperature may affect survival. <br />However, suboptimal temperatures, even though nonlethal, may significantly <br />reduce fish production. <br />The determination of the length of stream having suitable water quality <br />and temperature is illustrated in the top half of Figure 4. Several pathway <br />12