Water Quality 13
<br />Turbidity, the cloudiness of water, can foster the growth of
<br />microbes and impede the water-disinfection process (Apodaca
<br />and Bails, 2000). Turbidity for water samples from all wells
<br />except site 1 was less than 5.0 nephelometric turbidity units
<br />(NTU), the USEPA treatment technique value for public-supply
<br />water (table 2); most were less than or equal to 2.4 NTU. Higher
<br />turbidity for water samples from site 1 probably was due to the
<br />shallowness of the well and its location in a field that frequently
<br />has standing water. The median turbidity for water samples
<br />from alluvial aquifer wells was statistically higher than the
<br />median turbidity for water samples from wells in the Trouble-
<br />some Formation aquifer (table 3).
<br />Dissolved Solids, Major Ions, and Trace Elements
<br />Dissolved solids, major ions, and trace elements in uncon-
<br />taminated ground water are the result of the natural dissolution
<br />of materials along the ground-water flow path in soil and rock.
<br />Dissolved-solids concentration is used as one indicator of the
<br />suitability of water for drinking, residential, and industrial use,
<br />and irrigation purposes. The concentrations of dissolved solids
<br />in water samples from wells in the Fraser River watershed were
<br />low to moderate, ranging from 55 to 269 mg/L (table 2) and
<br />indicated that the water is suitable for domestic, municipal,
<br />industrial, and agricultural uses. Median dissolved-solids
<br />concentrations were lowest in the vicinity of Fraser and Winter
<br />Park and were highest around and to the west of Tabernash.
<br />Water samples from site 8 had the greatest median dissolved-
<br />solids concentration, 252 mg/L. All dissolved-solids concentra-
<br />tions were less than the State of Colorado water-quality
<br />standard of 400 mg/L (table 2).
<br />The dominant water type in the ground-water samples was
<br />calcium-bicarbonate type water (fig. 4). Only in samples from
<br />site 1 was the water type a mixed-cation (calcium-potassium or
<br />calcium-sodium) -bicarbonate type water or a mixed-cation
<br />(calcium-potassium or calcium-sodium) -mixed-anion (bicar-
<br />bonate-chloride) type water.
<br />There were differences among the wells in the concentra-
<br />tions of the major ions that formed the calcium-bicarbonate type
<br />water. Median concentrations of most major ions were greatest
<br />for wells in the Tabernash area, especially site 8. The median
<br />chloride concentration for water samples from site 8 was
<br />3 times greater than the median concentrations for samples from
<br />the other wells, and all sulfate concentrations in samples from
<br />site 8 were greater than 10 mg/L. Site 7, located just east of
<br />site 8, was the only other well with a sulfate concentration
<br />greater than 10 mg/L. The Tabernash area, including sites 7 and
<br />8, is the most downgradient part of the study area. Because of
<br />this, the ground water would have had a longer residence time,
<br />which could cause the increase in specific conductance and
<br />higher concentrations of dissolved solids and major ions. Chlo-
<br />ride and sulfate concentrations in water samples from all wells
<br />were substantially less than the USEPA SDWR of 250 mg/L for
<br />each constituent (table 2). Concentrations of chloride, magne-
<br />sium, and sulfate in water samples from wells in the alluvial
<br />aquifer and urban and ISDS areas were statistically higher than
<br />those from wells in the Troublesome Formation aquifer and
<br />nonurban and non-ISDS areas, as indicated by median concen-
<br />trations of the three ions (table 3).
<br />Sources of chloride in ground water can include natural
<br />processes (evaporative concentrations in precipitation, brines,
<br />dissolution of halite, fluid inclusions in rock) and human activ-
<br />ities (fertilizers, septic-system effluent, road salt). In other areas
<br />of the Southern Rocky Mountains physiographic province,
<br />chloride concentrations have been higher in urban than non-
<br />urban areas (Apodaca and Bails, 2000). Magnesium can be a
<br />major constituent of igneous and metamorphic rocks, depend-
<br />ing on the presence or alteration of ferromagnesian minerals in
<br />the rocks, and is present in minerals such as dolomite in sedi-
<br />mentary rocks. Most sulfate in ground-water samples from the
<br />11 wells probably resulted from the oxidation of sulfide miner-
<br />als in igneous and sedimentary rocks in the watershed. Greater
<br />magnesium and sulfate concentrations in urban wells as com-
<br />pared to the nonurban wells probably resulted from the greater
<br />exposure of the ground water to more igneous and metamorphic
<br />rocks and sulfide minerals in the more areally extensive water-
<br />shed draining to the urban areas.
<br />Concentrations of iron in the ground-water samples ranged
<br />from less than 10 to 310 µg/L (table 2). Concentrations greater
<br />than the reporting level of 10 gg/L only were detected in sam-
<br />ples from sites 4, 6, and 7. The highest concentrations occurred
<br />in water samples from site 7 (median of 210 µg/L), with one
<br />sample exceeding the USEPA SDWR for iron of 300 µg/L
<br />(table 2). Manganese concentrations ranged from an estimated
<br />2 µg/L to 510 µg/L (table 2), with water samples from four
<br />wells having concentrations greater than the laboratory report-
<br />ing levels. Elevated concentrations occurred in samples from
<br />site 7 (median of 457 µg/L) and site 9 (median of 73.8 µg/L).
<br />All seven samples from site 7 had manganese concentrations
<br />greater than the USEPA SDWR for manganese of 50 µg/L
<br />(table 2), as did four of seven samples for site 9. As discussed
<br />in "Field Properties," the solubility of iron and manganese
<br />increases when reducing conditions (characterized by very low
<br />dissolved-oxygen concentrations) are present in an aquifer.
<br />Median dissolved-oxygen concentrations for water samples
<br />from sites 7 and 9 were low, 0.2 and 0.5 mg/L, respectively, and
<br />indicated the presence of reducing conditions. Manganese con-
<br />centrations in water samples from wells in the alluvial aquifer
<br />and ISDS areas were significantly higher than those in water
<br />samples from wells in the Troublesome Formation aquifer and
<br />non-ISDS areas, as indicated by median manganese concentra-
<br />tions (table 3).
<br />Nutrients and Dissolved Organic Carbon
<br />Nutrients (nitrogen and phosphorus) can occur in ground
<br />water as a result of natural and anthropogenic factors. Nitrogen
<br />is a naturally occurring element in crustal rocks, plants, soil, and
<br />the atmosphere, whereas phosphorus is common in igneous
<br />rocks and occurs in mineral form as apatite (Hem, 1992).
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