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Water Quality 13 <br />Turbidity, the cloudiness of water, can foster the growth of <br />microbes and impede the water-disinfection process (Apodaca <br />and Bails, 2000). Turbidity for water samples from all wells <br />except site 1 was less than 5.0 nephelometric turbidity units <br />(NTU), the USEPA treatment technique value for public-supply <br />water (table 2); most were less than or equal to 2.4 NTU. Higher <br />turbidity for water samples from site 1 probably was due to the <br />shallowness of the well and its location in a field that frequently <br />has standing water. The median turbidity for water samples <br />from alluvial aquifer wells was statistically higher than the <br />median turbidity for water samples from wells in the Trouble- <br />some Formation aquifer (table 3). <br />Dissolved Solids, Major Ions, and Trace Elements <br />Dissolved solids, major ions, and trace elements in uncon- <br />taminated ground water are the result of the natural dissolution <br />of materials along the ground-water flow path in soil and rock. <br />Dissolved-solids concentration is used as one indicator of the <br />suitability of water for drinking, residential, and industrial use, <br />and irrigation purposes. The concentrations of dissolved solids <br />in water samples from wells in the Fraser River watershed were <br />low to moderate, ranging from 55 to 269 mg/L (table 2) and <br />indicated that the water is suitable for domestic, municipal, <br />industrial, and agricultural uses. Median dissolved-solids <br />concentrations were lowest in the vicinity of Fraser and Winter <br />Park and were highest around and to the west of Tabernash. <br />Water samples from site 8 had the greatest median dissolved- <br />solids concentration, 252 mg/L. All dissolved-solids concentra- <br />tions were less than the State of Colorado water-quality <br />standard of 400 mg/L (table 2). <br />The dominant water type in the ground-water samples was <br />calcium-bicarbonate type water (fig. 4). Only in samples from <br />site 1 was the water type a mixed-cation (calcium-potassium or <br />calcium-sodium) -bicarbonate type water or a mixed-cation <br />(calcium-potassium or calcium-sodium) -mixed-anion (bicar- <br />bonate-chloride) type water. <br />There were differences among the wells in the concentra- <br />tions of the major ions that formed the calcium-bicarbonate type <br />water. Median concentrations of most major ions were greatest <br />for wells in the Tabernash area, especially site 8. The median <br />chloride concentration for water samples from site 8 was <br />3 times greater than the median concentrations for samples from <br />the other wells, and all sulfate concentrations in samples from <br />site 8 were greater than 10 mg/L. Site 7, located just east of <br />site 8, was the only other well with a sulfate concentration <br />greater than 10 mg/L. The Tabernash area, including sites 7 and <br />8, is the most downgradient part of the study area. Because of <br />this, the ground water would have had a longer residence time, <br />which could cause the increase in specific conductance and <br />higher concentrations of dissolved solids and major ions. Chlo- <br />ride and sulfate concentrations in water samples from all wells <br />were substantially less than the USEPA SDWR of 250 mg/L for <br />each constituent (table 2). Concentrations of chloride, magne- <br />sium, and sulfate in water samples from wells in the alluvial <br />aquifer and urban and ISDS areas were statistically higher than <br />those from wells in the Troublesome Formation aquifer and <br />nonurban and non-ISDS areas, as indicated by median concen- <br />trations of the three ions (table 3). <br />Sources of chloride in ground water can include natural <br />processes (evaporative concentrations in precipitation, brines, <br />dissolution of halite, fluid inclusions in rock) and human activ- <br />ities (fertilizers, septic-system effluent, road salt). In other areas <br />of the Southern Rocky Mountains physiographic province, <br />chloride concentrations have been higher in urban than non- <br />urban areas (Apodaca and Bails, 2000). Magnesium can be a <br />major constituent of igneous and metamorphic rocks, depend- <br />ing on the presence or alteration of ferromagnesian minerals in <br />the rocks, and is present in minerals such as dolomite in sedi- <br />mentary rocks. Most sulfate in ground-water samples from the <br />11 wells probably resulted from the oxidation of sulfide miner- <br />als in igneous and sedimentary rocks in the watershed. Greater <br />magnesium and sulfate concentrations in urban wells as com- <br />pared to the nonurban wells probably resulted from the greater <br />exposure of the ground water to more igneous and metamorphic <br />rocks and sulfide minerals in the more areally extensive water- <br />shed draining to the urban areas. <br />Concentrations of iron in the ground-water samples ranged <br />from less than 10 to 310 µg/L (table 2). Concentrations greater <br />than the reporting level of 10 gg/L only were detected in sam- <br />ples from sites 4, 6, and 7. The highest concentrations occurred <br />in water samples from site 7 (median of 210 µg/L), with one <br />sample exceeding the USEPA SDWR for iron of 300 µg/L <br />(table 2). Manganese concentrations ranged from an estimated <br />2 µg/L to 510 µg/L (table 2), with water samples from four <br />wells having concentrations greater than the laboratory report- <br />ing levels. Elevated concentrations occurred in samples from <br />site 7 (median of 457 µg/L) and site 9 (median of 73.8 µg/L). <br />All seven samples from site 7 had manganese concentrations <br />greater than the USEPA SDWR for manganese of 50 µg/L <br />(table 2), as did four of seven samples for site 9. As discussed <br />in "Field Properties," the solubility of iron and manganese <br />increases when reducing conditions (characterized by very low <br />dissolved-oxygen concentrations) are present in an aquifer. <br />Median dissolved-oxygen concentrations for water samples <br />from sites 7 and 9 were low, 0.2 and 0.5 mg/L, respectively, and <br />indicated the presence of reducing conditions. Manganese con- <br />centrations in water samples from wells in the alluvial aquifer <br />and ISDS areas were significantly higher than those in water <br />samples from wells in the Troublesome Formation aquifer and <br />non-ISDS areas, as indicated by median manganese concentra- <br />tions (table 3). <br />Nutrients and Dissolved Organic Carbon <br />Nutrients (nitrogen and phosphorus) can occur in ground <br />water as a result of natural and anthropogenic factors. Nitrogen <br />is a naturally occurring element in crustal rocks, plants, soil, and <br />the atmosphere, whereas phosphorus is common in igneous <br />rocks and occurs in mineral form as apatite (Hem, 1992).