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UCREFRP
UCREFRP Catalog Number
8153
Author
Jacobs, e. L. W.
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USFW Year
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USFW - Doc Type
1989
Copyright Material
YES
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36 MAYLAND ET AL. <br />calculated EF of the 2µm MMAD particle was 2 times that of the 50-µm <br />particle. In another study conducted in the USA (Campbell et al., 1978), the <br />EF for Se in the fine particles compared to larger particles was 9.9, illustrat- <br />ing that some variation occurs between coal plants or in sampling and ana- <br />lytical techniques. <br />High combustion temperatures volatilize some of the Se in the coal, <br />which then leaves the furnace in the gaseous phase. Fly ash and gases begin <br />to condense as they move through the particle scrubbers and ascend the stacks. <br />Most of the larger particles and the Se associated with them are trapped by <br />the scrubbers. However, the remaining Se probably condenses on the smaller <br />particles that escape the stack and enter the atmosphere as aerosols. The <br />degree of preferential enrichment may be a function of the individual power <br />plant and current operating conditions. The amount of Se leaving the stack <br />will be a function of the Se content of the coal, particle size, combustion <br />temperature, efficiency of particle scrubbers, temperature of flue-gases, and <br />exit velocity. <br />Another source of aerosols that can enter the atmosphere and contrib- <br />ute to global cycling of Se is the incineration of refuse. Nationally we gener- <br />ate 16 x 1010 kg of municipal refuse annually in the USA (Lemley, 1987). <br />While incineration of wastes would reduce this mass, it would also be a source <br />of aerosol and ash residues. In the United Kingdom, municipal refuse in- <br />cineration consumed 3 x 109 kg of material annually generating 1 x 109 <br />kg ash residue (Wadge et al., 1986). Unlike coal-fired power plants, more <br />bottom ash is produced than fly ash. Refuse incinerators operate at lower <br />temperatures (800-1100°C) compared to coal furnaces that operate at near- <br />ly 1500°C. Coal fly ash is composed of cenospheres of <20 µm MMAD, <br />whereas refuse fly ash consisted mostly of amorphous particles of < 50 µm <br />MMAD. <br />Wadge et al. (1986) reported that refuse fly ash from an incinerator <br />located in the United Kingdom contained 2.5 to 6.6 mg Se/kg with a mean <br />value of 4.4. The Se in this refuse fly ash had an EF of 93 compared with <br />an EF of 98 reported for refuse fly ash from an incinerator in the USA (Green- <br />berg et al., 1978a). These EF values are similar to those given for coal-derived <br />fly ash of 84 and 132 given above. Greenberg et al. (1978b) reported an EF <br />of 4500 for Se in aerosols above a refuse incinerator in the USA, possibly <br />reflecting the larger particle sizes and cooler incinerator temperatures when <br />compared with data for coal furnaces (Andren et al., 1975). Although the <br />EF values of Se are similar for the two refuse incinerators, one should not <br />assume that all municipal refuse is alike or their Se concentrations the same. <br />Measurable differences may exist among Se concentrations in refuse from <br />rural vs. industrial vs. metropolitan areas. <br />Chiou and Manuel (1986) collected atmospheric particulates at Rolla, <br />MO, using ahigh-volume particle fractionating cascade impactor. This sys- <br />tem gave five sized fractions with a range of 0.01 to > 7.0 µm MMAD parti- <br />cle. They measured 3.6 ± 0.8 µg Se/m3 compared with a range of 2.1 to <br />> 7µg/m3 measured elsewhere in the USA (Ondov et a1., 1982; Pillay et al., <br />
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