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<br />Lorch (1998) found a significant correlation <br />(p<O.OOOl) between chloride and manganese concen- <br />trations in 22 stream and runoff samples in and near <br />Black Gore Creek. Lorch attributed this correlation to <br />impurities in the salt material applied to Interstate 70 <br />during snowstorms. Cadmium, chromium, nickel, and <br />zinc concentrations also were highly correlated with <br />chloride concentrations (p<O.OOOl), whereas copper <br />and lead concentrations were not as highly correlated <br />with chloride (p-values were equal to 0.0003 and <br />0.0004, respectively). <br />Silver concentrations exceeded the 0.08-f-lg/L <br />aquatic-life stream standard at two sites in Gore <br />Creek downstream from Red Sandstone Creek in <br />December 1988 (Advanced Sciences, Inc., 1990). <br />The concentrations were 0.2 and 0.3 f-lg/L. Silver <br />was detected at a concentration of 0.1 f-lg/L in four <br />samples in 1989. Silver has not been detected in <br />Gore Creek downstream from Red Sandstone Creek <br />in the 22 samples collected since 1989; however, the <br />reporting limit (0.5 and 1.0 f-lg/L) for most of those <br />samples was higher than all of the previous silver <br />detections. Trace-element sampling programs that <br />may be conducted for sites in Gore Creek in the future <br />should use analytical methods for silver analyses with <br />a reporting limit no higher than 0.05-0.1 f-lg/L to <br />determine whether silver concentrations are still <br />a concern in Gore Creek. <br /> <br />Nutrients. Distributions of concentrations for <br />ammonia, nitrate, total nitrogen, orthophosphate, and <br />total phosphorus for 30 surface-water sites are repre- <br />sented by boxplots in figure 15. Ammonia concentra- <br />tions for all sites were low, with 75 percent of the <br />concentrations equal to or less than 0.10 mg/L <br />(fig. 15). The ammonia data contained a variety of <br />minimum reporting limits, and no discrete median <br />concentration could be determined because more <br />than one-half the data was below one of the reporting <br />limits. The range of nitrate concentrations was <br />the largest (three orders of magnitude) of the five <br />nutrient constituents, and the median concentration <br />was 0.40 mg/L. Four nitrate concentrations in samples <br />collected during winter 1976-77 exceeded the USEPA <br />drinking-water maximum contaminant level (MCL) <br />of 10 mg/L. Only 53 analyses were available for total <br />nitrogen, which had the highest median concentration <br />of 0.6 mg/L. The median orthophosphate concentra- <br />tion was 0.01 mg/L, and 90 percent of the data were <br />0.10 mg/L or less. Total phosphorus concentrations <br />were somewhat elevated. The median concentration <br />was 0.05 mg/L, and 25 percent of the total phosphorus <br />concentrations were greater than 0.12 mg/L, which <br />exceeds the USEPA recommended level of 0.10 mg/L <br />for control of eutrophication in flowing water <br />(U.S. Environmental Protection Agency, 1986). <br /> <br /> 100 <br />a: (388) (619) (53) (308) (287) EXPLANATION <br />W <br />~ (35) Number of samples <br />:J <br />a: Data value <br />w 10 <br />a.. ~h ;J <br />Cf) 75th <br />~ , <br /><( 50th (median) Percentiles <br />a: <br /><.9 ~!J 25th <br />:J 10th <br />...J <br />~ i <br />z ~ <br />Z' 0.1 <br />0 <br />~ dm <br />a: <br />~ " " ~' '- <br />Z 0.01 <br />w <br />U <br />Z <br />0 <br />U <br /> 0.001 <br /> Ammonia Nitrate Total Orthophosphate Total <br /> Nitrogen Phosphorus <br /> <br /> <br />Figure 15. Distribution of nutrient concentrations for all surface-water sampling sites in the Gore Creek watershed. <br /> <br />SURFACE WATER 31 <br />