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<br />CONTENTS <br /> <br />Abstract............................................................................,.... ................................................................................................ <br /> 1 <br /> <br />Introduction........................................................................... ............................................................................................,... <br /> 1 <br /> <br />Purpose and Scope...................................................... ................................................................,............................... 3 <br /> <br />Acknowledgments...................................................... ................................................................................................ 3 <br /> <br />Quality-Control Sampling Program.... ....... ..... ............... ....... . ............. ......... ......................................................................... 3 <br /> <br />Replicate Samples....................................................... ................................................................................................ 4 <br /> <br />Pre-Processing Split Replicates ........................ ............................ ..... ................... ..... ..... ..... .................... .... ..... 6 <br />Comparison of General Chemical Consti uents ...................................................................................... 6 <br />Comparison of Nutrients and Organic C bon ........................................................................................ 9 <br />Comparison of Trace Elements .............. ................................................................................................ 12 <br />Concurrent and Sequential Replicates .............. ................................................................................................ 15 <br />Comparison of General Chemical Consti ents ...................................................................................... 15 <br />Comparison of Nutrients and Organic C bon ........................................................................................ 20 <br />Post-Processing Split Replicates. ............ ..... ..... . ...................... ................................................... ...................... 24 <br />Comparison of General Chemical Consti uents ...................................................................................... 25 <br />Comparison of Nutrients and Organic C bon ........................................................................................ 28 <br /> <br />Field Blanks................................................................ ................................................................................................ 31 <br /> <br />General Chemical Constituents ........................ ................................................................................................ '31 <br />Nutrients and Organic Carbon ............................................................................... ...................... .......... ..... ....... 32 <br /> <br />Conclusions............................................................................................................................................................................ <br /> 34 <br /> <br />References Cited.................................................................................................................................................................... 34 <br /> <br />FIGURES <br /> <br />1. Map showing location of sampling sites.;................................................................................................................... 2 <br />2-5. Graphs showing: <br />2. Distribution of collection of pre-processing sp it-replicate samples, 1995-96................................................ 6 <br />3. Distribution of collection of concurrent- and s quential-replicate samples, 1995-96..................................... 15 <br />4. Distribution of collection of post-processing s lit-replicate samples, 1995-96.............................................. 25 <br />5. Distribution of collection of field blanks, 1995 96......................................................................................... 32 <br /> <br />TABLES <br /> <br />10. <br /> <br />1. Water-quality monitoring sites in the Upper Color do River study unit................................................................ <br />2. Distribution of replicate samPles............................j... ....................................... ....... ............ ....... .......... ..... ............ <br />3. Distribution of field-blank samples ......................... ............................................................................................... <br /> <br />4. ~:e::t~:n~~i;::~;~~~.~~~~. .~~~.~~~.~~~~~~~~~~~.. ~~.~~~~~~~~.~~~~ .~.~~~~~ .~~~..~~~~~.~......... .................................. <br /> <br />5. Summary of differences between environmental a d pre-processing split-replicate samples <br /> <br />for general chemical constituents ... ......... ... ............. ..... ... ....... ....... ..... ....... ..... ..... ................................................... <br /> <br />6. Comparisons of environmental and pre-processing split-replicate samples for nutrients and <br /> <br />organic carbon......................................................... ............................................................................................... 10 <br /> <br />7. Summary of differences between environmental a pre-processing split-replicate samples <br />for nutrients and organic carbon.............................. ............................................................................................... 12 <br />8. Comparison of environmental and pre-processing s lit-replicate samples for trace elements ............................... 13 <br />9. Comparison of environmental and concurrent- and sequential-replicate samples for general <br /> <br />chemical constituents .............................................. ........................................................ ..... .......... ....... .......... ....... 16 <br /> <br />Summary of differences between environmental an concurrent-replicate samples for general <br /> <br />chemical constituents ...... ... ..................... ..... ........... ........ ......... ..... ..... ..... ............ ................................................... 20 <br /> <br />Comparison of environmental and concurrent- and sequential-replicate samples for nutrients <br /> <br />and organic carbon.................................................. ............................................................................................... 21 <br /> <br />3 <br />4 <br />5 <br /> <br />7 <br /> <br />9 <br /> <br />11. <br /> <br />CONTENTSilll <br />