<br />Hamilton
<br />
<br />Wash, and Big Salt Wash. Butler et ai. (1994) reported that in 1991, water
<br />samples from Reed Wash contained 120 ~g/L of selenium, Little Salt Wash
<br />16 ~g/L, and Big Salt Wash 24 ~g/L. Average selenium concentrations in
<br />whole-body of several fish species at these sites ranged from 8 to 11 ~g/ g (all
<br />sediment and tissue concentrations are given as dry weight). Consequently,
<br />adult Colorado pikeminnow that congregated at these three sites may have
<br />been exposed to substantial amounts of selenium in water and in prey fish. In
<br />the summer of 1995, two Colorado pikeminnow were caught in an irrigation
<br />drain that emptied into the Colorado River just upstream of Adobe Creek near
<br />GrandJunction (B. Osmundson, personal communication, 1996), which showed
<br />these fish continue to use drains.
<br />
<br />mSTORICAL SELENIUM CONTAMINATION IN THE COLORADO
<br />RIVER BASIN
<br />
<br />Because of concerns about selenium toxicosis in livestock and accumula-
<br />tion in irrigated agricultural crops in the Western states in the early 1900s,
<br />numerous DOA and university studies were conducted (reviewed by Trelease
<br />and Beath, 1949). Ancillary to selenium measurements in soil, plants, and
<br />animals, concentrations were also measured during the 1930s in various water
<br />samples, but not in aquatic biota, of the Colorado River basin including
<br />irrigation drains. The 1930s reports of the DOA used a measurement tech-
<br />nique adequate to recover quantitatively 0.01 mg of selenium, as sodium
<br />selenite, from 4 L of distilled water, which corresponds to 2.5 J..lg/L and
<br />qualitative detection as low as 0.25 ~g/L (Byers et al., 1938). Above irrigated
<br />areas, water in the upper parts of the Uncompahgre, Gunnison, and Colorado
<br />rivers contained less than 1 J..lg/L (Byers, 1936). Trace amounts of selenium
<br />were also found in the Dolores River at Cisco, UT, and the Green River at
<br />Green River, UT.
<br />However, below irrigated areas, water from these rivers contained high
<br />concentrations of selenium. In samples collected in 1935, the Uncompahgre
<br />River above its confluence with the Gunnison River contained 220 ~g/L, the
<br />Gunnison River near its confluence with the Colorado River contained 80 J..lg/L,
<br />and the Colorado River near Grand Junction contained 30 J..lg/L (Williams
<br />and Byers, 1935; Byers, 1936).
<br />The high selenium concentrations in the Uncompahgre, Gunnison, and
<br />Colorado rivers were the result of irrigation return flows. Two drains entering
<br />the Uncompahgre River near Montrose, CO, had 320 and 700 J..lg/L selenium,
<br />and a drain near Chipeta, CO, had 1050 ~g/L. Cow Creek in the upper
<br />Uncompahgre River contained 2 J..lg/L, which Byers (1936) concluded, showed
<br />the first traces of selenium because it received drainage from about 486 ha of
<br />irrigated land. In the Grand Valley, one drain near Mack, CO, contained 1980
<br />~g/L in December 1934, and 6 months later in May 1935, it contained 2680
<br />~g/L. A main drain near Loma, CO, contained 630 ~g/L. It is interesting to
<br />note that Byers (1936) concluded "... irrigation, with under irrigation [i.e.,
<br />tiled drains], is a potent influence in decreasing the injurious effects produced
<br />
<br />1170
<br />
<br />Hum. Eco\. Risk Assess. Vo\. 5, No.6, 1999
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