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<br />Hamilton <br /> <br />Wash, and Big Salt Wash. Butler et ai. (1994) reported that in 1991, water <br />samples from Reed Wash contained 120 ~g/L of selenium, Little Salt Wash <br />16 ~g/L, and Big Salt Wash 24 ~g/L. Average selenium concentrations in <br />whole-body of several fish species at these sites ranged from 8 to 11 ~g/ g (all <br />sediment and tissue concentrations are given as dry weight). Consequently, <br />adult Colorado pikeminnow that congregated at these three sites may have <br />been exposed to substantial amounts of selenium in water and in prey fish. In <br />the summer of 1995, two Colorado pikeminnow were caught in an irrigation <br />drain that emptied into the Colorado River just upstream of Adobe Creek near <br />GrandJunction (B. Osmundson, personal communication, 1996), which showed <br />these fish continue to use drains. <br /> <br />mSTORICAL SELENIUM CONTAMINATION IN THE COLORADO <br />RIVER BASIN <br /> <br />Because of concerns about selenium toxicosis in livestock and accumula- <br />tion in irrigated agricultural crops in the Western states in the early 1900s, <br />numerous DOA and university studies were conducted (reviewed by Trelease <br />and Beath, 1949). Ancillary to selenium measurements in soil, plants, and <br />animals, concentrations were also measured during the 1930s in various water <br />samples, but not in aquatic biota, of the Colorado River basin including <br />irrigation drains. The 1930s reports of the DOA used a measurement tech- <br />nique adequate to recover quantitatively 0.01 mg of selenium, as sodium <br />selenite, from 4 L of distilled water, which corresponds to 2.5 J..lg/L and <br />qualitative detection as low as 0.25 ~g/L (Byers et al., 1938). Above irrigated <br />areas, water in the upper parts of the Uncompahgre, Gunnison, and Colorado <br />rivers contained less than 1 J..lg/L (Byers, 1936). Trace amounts of selenium <br />were also found in the Dolores River at Cisco, UT, and the Green River at <br />Green River, UT. <br />However, below irrigated areas, water from these rivers contained high <br />concentrations of selenium. In samples collected in 1935, the Uncompahgre <br />River above its confluence with the Gunnison River contained 220 ~g/L, the <br />Gunnison River near its confluence with the Colorado River contained 80 J..lg/L, <br />and the Colorado River near Grand Junction contained 30 J..lg/L (Williams <br />and Byers, 1935; Byers, 1936). <br />The high selenium concentrations in the Uncompahgre, Gunnison, and <br />Colorado rivers were the result of irrigation return flows. Two drains entering <br />the Uncompahgre River near Montrose, CO, had 320 and 700 J..lg/L selenium, <br />and a drain near Chipeta, CO, had 1050 ~g/L. Cow Creek in the upper <br />Uncompahgre River contained 2 J..lg/L, which Byers (1936) concluded, showed <br />the first traces of selenium because it received drainage from about 486 ha of <br />irrigated land. In the Grand Valley, one drain near Mack, CO, contained 1980 <br />~g/L in December 1934, and 6 months later in May 1935, it contained 2680 <br />~g/L. A main drain near Loma, CO, contained 630 ~g/L. It is interesting to <br />note that Byers (1936) concluded "... irrigation, with under irrigation [i.e., <br />tiled drains], is a potent influence in decreasing the injurious effects produced <br /> <br />1170 <br /> <br />Hum. Eco\. Risk Assess. Vo\. 5, No.6, 1999 <br />