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<br />20 INFORMATION AND TECHNOLOGY REpORT--2003-0002 <br /> <br />the system. When cathodes are larger than anodes, most <br />of the total potential between electrodes is associated <br />with the anode, and the voltage differential between an- <br />ode and ambient potential is proportionately greater than <br />between ambient potential and cathode. If cathodes are <br />very much larger than anodes, the very low voltage dif- <br />ferential between the cathode and soil and water in the <br />vicinity may reduce the risk of severe shock or electrocu- <br />tion to people or animals that inadvertently approach or <br />touch the cathode (Smith, 1989). Because cathodic resis- <br />tance for well-separated electrodes is halved each time <br />the surface area of the cathode is doubled, Smith (1989) <br />suggested that 10m2 may be a practical limit to the size of <br />the cathode. However, according to Temple (personal <br />communication), A. Kolz maintains that in shore-based <br />systems with buried cathodes, the earth itself becomes a <br />very large cathode. With appropriate equipment and wir- <br />ing on metal boats, cathode size is often maximized for <br />DC or PDC electrofishing systems by using the boats <br />themselves as cathodes (Kolz, 1993; Reynolds, 1996); on <br />fiberglass vessels, cathode size is sometimes maximized <br />by mounting large metal plates on their bottoms (Vibert, <br />1967b ). <br />Kolz (1993) discussed the importance of and proce- <br />dures for determining electrode and system resistance as <br />well as making in-water measurements for mapping field <br />intensity around and between various types of elec- <br />trodes. Such data are necessary for comparing electrodes <br />of various shapes, sizes, and designs, optimizing <br />electro fishing efficiency, minimizing hazardous field in- <br />tensities, and standardizing electrofishing fields. Kolz <br />(1993) emphasized that electrofishing fields generated <br />through different electrode systems cannot be standard- <br />ized only by output voltage, current, or power. The distri- <br />bution of field intensity around and between electrodes <br />depends in large part on the specific size, shape, and <br />configuration ofthose electrodes and must also be known <br />or measured. <br />To this end, Kolz (1993) determined and compared <br />the electrical resistance and voltage-gradient and volt- <br />age-differential profiles for 18 commonly used electrodes, <br />including spheres, cylinders, horizontal loops, Wiscon- <br />sin-ring dropper arrays, and vertical plates of various <br />sizes. Measurements were taken in a concrete canal (wa- <br />ter 1.4 m deep, 3 m wide) with matching electrodes 4 m <br />apart (except for cylindrical electrodes which were 2.7 m <br />apart), water conductivities of III to 190 I-lS/cm, and an <br />electrical output of 100 V nTIS' Electrical resistance data were <br />normalized for a water conductivity of 100 I-lS/cm but can <br />be adjusted by calculation for different water conductivi- <br />ties (electrode resistance is inversely proportional). Simi- <br />larly, voltage-gradient and voltage-differential profile data <br />for each electrode can be calculated for different applied <br />voltages (directly proportional; for unmatched electrodes <br /> <br />data must also be adjusted by the inverse ratio of their <br />electrical resistances). <br />Spherical electrodes are considered electrically su- <br />perior to other shapes (e.g., cables or narrow cylinders) <br />and allow more accurate calculation of electrode resis- <br />tance and voltage gradient maps. Electric fields gener- <br />ated immediately around well-submerged spheres are <br />uniform and without the hot spots (localized regions of <br />higher intensity) produced near the comers and edges of <br />many other electrode shapes. For example, according to <br />Sharber et al. (1995), charge is not distributed uniformly <br />over long thin electrodes but concentrated at their distal <br />ends. Except near their surfaces where tetanizing voltage <br />gradients may exist, Novotny and Priegel (1974) and <br />Novotny (1990) suggested that circular and ringlike elec- <br />trodes, including dropper arrays, produce electric fields <br />similar to those of spheres. However, Kolz (1993) docu- <br />mented that Wisconsin-ring dropper arrays project their <br />fields somewhat further in a horizontal direction than simi- <br />lar-size spheres. Spheres, on the other hand, project their <br />fields more evenly in all directions, including vertically <br />towards the bottom and, perhaps less advantageously, <br />upward to the water surface. <br />In addition to transfer of electrons, the process of <br />electrolysis at the electrodes results in generation of gases <br />and, more importantly, loss of metal ions from the anode <br />to the water and deposition of metal ions from the water <br />onto the cathode, usually as metallic oxides (Sharber, <br />personal communication). Periodically, anodes may need <br />to be replaced and cathodes cleaned (scraped or sanded) <br />to recover lost surface area and performance (oxide coat- <br />ings reduce electrode resistance). When electrodes are <br />of the same size and type, some biologists periodically <br />alternate their use as anodes or cathodes to reverse the <br />buildup of metallic oxides (Sharber and Carothers, 1988), <br />but the effectiveness of this procedure has not been re- <br />ported. <br />Riddle (1984) suggested that it was not wise to buy <br />aluminum punts (boats) second-hand from electro- <br />fishermen because the gauge of the metal might be <br />substantially reduced. According to Sharber (personal <br />communication), this is not a problem when a metal boat <br />is used as the cathode. But when a metal boat is situated <br />in an electric field and not used as an electrode, it has an <br />intermediate electric charge, negative with respect to the <br />anode and positive with respect to cathode. In this case, <br />electrolytic reactions result in both formation of <br />nonconductive metallic compounds on the boat's surface <br />and loss of structural metal. Over time, the latter reaction <br />can reduce the structural integrity of the boat. When a <br />boat is used as a cathode, no metal is lost, but the <br />nonconductive metallic compounds that form on the <br />boat's surface can increase its electrical resistance. This <br />coating can be scraped or sanded away periodically, but <br />