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<br />20 INFORMATION AND TECHNOLOGY REpORT--2003-0002
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<br />the system. When cathodes are larger than anodes, most
<br />of the total potential between electrodes is associated
<br />with the anode, and the voltage differential between an-
<br />ode and ambient potential is proportionately greater than
<br />between ambient potential and cathode. If cathodes are
<br />very much larger than anodes, the very low voltage dif-
<br />ferential between the cathode and soil and water in the
<br />vicinity may reduce the risk of severe shock or electrocu-
<br />tion to people or animals that inadvertently approach or
<br />touch the cathode (Smith, 1989). Because cathodic resis-
<br />tance for well-separated electrodes is halved each time
<br />the surface area of the cathode is doubled, Smith (1989)
<br />suggested that 10m2 may be a practical limit to the size of
<br />the cathode. However, according to Temple (personal
<br />communication), A. Kolz maintains that in shore-based
<br />systems with buried cathodes, the earth itself becomes a
<br />very large cathode. With appropriate equipment and wir-
<br />ing on metal boats, cathode size is often maximized for
<br />DC or PDC electrofishing systems by using the boats
<br />themselves as cathodes (Kolz, 1993; Reynolds, 1996); on
<br />fiberglass vessels, cathode size is sometimes maximized
<br />by mounting large metal plates on their bottoms (Vibert,
<br />1967b ).
<br />Kolz (1993) discussed the importance of and proce-
<br />dures for determining electrode and system resistance as
<br />well as making in-water measurements for mapping field
<br />intensity around and between various types of elec-
<br />trodes. Such data are necessary for comparing electrodes
<br />of various shapes, sizes, and designs, optimizing
<br />electro fishing efficiency, minimizing hazardous field in-
<br />tensities, and standardizing electrofishing fields. Kolz
<br />(1993) emphasized that electrofishing fields generated
<br />through different electrode systems cannot be standard-
<br />ized only by output voltage, current, or power. The distri-
<br />bution of field intensity around and between electrodes
<br />depends in large part on the specific size, shape, and
<br />configuration ofthose electrodes and must also be known
<br />or measured.
<br />To this end, Kolz (1993) determined and compared
<br />the electrical resistance and voltage-gradient and volt-
<br />age-differential profiles for 18 commonly used electrodes,
<br />including spheres, cylinders, horizontal loops, Wiscon-
<br />sin-ring dropper arrays, and vertical plates of various
<br />sizes. Measurements were taken in a concrete canal (wa-
<br />ter 1.4 m deep, 3 m wide) with matching electrodes 4 m
<br />apart (except for cylindrical electrodes which were 2.7 m
<br />apart), water conductivities of III to 190 I-lS/cm, and an
<br />electrical output of 100 V nTIS' Electrical resistance data were
<br />normalized for a water conductivity of 100 I-lS/cm but can
<br />be adjusted by calculation for different water conductivi-
<br />ties (electrode resistance is inversely proportional). Simi-
<br />larly, voltage-gradient and voltage-differential profile data
<br />for each electrode can be calculated for different applied
<br />voltages (directly proportional; for unmatched electrodes
<br />
<br />data must also be adjusted by the inverse ratio of their
<br />electrical resistances).
<br />Spherical electrodes are considered electrically su-
<br />perior to other shapes (e.g., cables or narrow cylinders)
<br />and allow more accurate calculation of electrode resis-
<br />tance and voltage gradient maps. Electric fields gener-
<br />ated immediately around well-submerged spheres are
<br />uniform and without the hot spots (localized regions of
<br />higher intensity) produced near the comers and edges of
<br />many other electrode shapes. For example, according to
<br />Sharber et al. (1995), charge is not distributed uniformly
<br />over long thin electrodes but concentrated at their distal
<br />ends. Except near their surfaces where tetanizing voltage
<br />gradients may exist, Novotny and Priegel (1974) and
<br />Novotny (1990) suggested that circular and ringlike elec-
<br />trodes, including dropper arrays, produce electric fields
<br />similar to those of spheres. However, Kolz (1993) docu-
<br />mented that Wisconsin-ring dropper arrays project their
<br />fields somewhat further in a horizontal direction than simi-
<br />lar-size spheres. Spheres, on the other hand, project their
<br />fields more evenly in all directions, including vertically
<br />towards the bottom and, perhaps less advantageously,
<br />upward to the water surface.
<br />In addition to transfer of electrons, the process of
<br />electrolysis at the electrodes results in generation of gases
<br />and, more importantly, loss of metal ions from the anode
<br />to the water and deposition of metal ions from the water
<br />onto the cathode, usually as metallic oxides (Sharber,
<br />personal communication). Periodically, anodes may need
<br />to be replaced and cathodes cleaned (scraped or sanded)
<br />to recover lost surface area and performance (oxide coat-
<br />ings reduce electrode resistance). When electrodes are
<br />of the same size and type, some biologists periodically
<br />alternate their use as anodes or cathodes to reverse the
<br />buildup of metallic oxides (Sharber and Carothers, 1988),
<br />but the effectiveness of this procedure has not been re-
<br />ported.
<br />Riddle (1984) suggested that it was not wise to buy
<br />aluminum punts (boats) second-hand from electro-
<br />fishermen because the gauge of the metal might be
<br />substantially reduced. According to Sharber (personal
<br />communication), this is not a problem when a metal boat
<br />is used as the cathode. But when a metal boat is situated
<br />in an electric field and not used as an electrode, it has an
<br />intermediate electric charge, negative with respect to the
<br />anode and positive with respect to cathode. In this case,
<br />electrolytic reactions result in both formation of
<br />nonconductive metallic compounds on the boat's surface
<br />and loss of structural metal. Over time, the latter reaction
<br />can reduce the structural integrity of the boat. When a
<br />boat is used as a cathode, no metal is lost, but the
<br />nonconductive metallic compounds that form on the
<br />boat's surface can increase its electrical resistance. This
<br />coating can be scraped or sanded away periodically, but
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