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<br />EXAMPLE EXERCISE <br /> <br />The example form on this page can be used for the <br />example exercise. The form can be reproduced and used in <br />the event of a real spill. <br />Assume a pollutant spill of 2,000 pounds of a soluble <br />hazardous material into the Yampa River at Steamboat <br />Springs (site 2, fig. 1, table 3). One immediate concern <br />would be to determine the arrival time and peak concentra- <br />tion of the hazardous material at the Hayden water-treat- <br />ment plant, river mile 164.7 (site 10, fig. 1, table 3). <br />Step i.-By accessing the USGS Internet address <br />http://webserver.cr.usgs.gov (click on Colorado Water Data, <br />Surface Water, Station number 09239500), it is determined <br />that the discharge at streamflow-gaging station 09239500, <br />Yampa River at Steamboat Springs (fig. 1, table 1) is <br />1,000 cubic feet per second (ft3/s). <br />Step 2.-From table 4, for a discharge of 1,000 ft3/s, <br />the traveltime of the peak concentration between sites 2 and <br />site 10 would be 17.2 -1.3 = 15.9 hours. <br /> <br />Step 3.- The traveltime of the leading edge of the <br />hazardous material between site 2 and site 10 is determined <br />by multiplying the traveltime of the peak concentration <br />(15.9) by 0.89 = 14.2 hours. <br />Step 4.-From table 5, the unit-concentration value <br />(Cup) is 82.2 for a streamflow of 1,000 ft3/s at site 10. <br />Step 5.-Compute the most probable peak concentra- <br />tion at the Hayden water plant (site 10): <br />0.016 times 82.2 times 2,000 pounds divided by 1,000 ft3/s = <br />2.63 milligrams per liter at 15.9 hours after the spill. <br />Step 6.-Compute the time the trailing edge of the <br />spill would be expected to arrive at the water-treatment plant: <br />Divide 555.6 by 82.2 (Cup from step 4) = 6.8 hours after <br />arrival of the leading edge, or 14.2 (from step 3) plus 6.8 = <br />21.0 hours after the spill. <br />All of the above computations assume there is no loss <br />of the hazardous material between the spill and the intake. <br />Losses could occur by chemical reactions, volatilization, <br />adsorption on the streambed, or other processes. <br /> <br />Example Form <br /> <br />Step 1 <br /> <br />Determine streamflow at spill location or site upstream from spill location (fig. 1, tables 1 and 3) <br />Determine (estimate) volume of spill in pounds <br />Determine points of interest (fig. 1, table 3) <br /> <br />ft3/S <br /> <br />Step 2 <br />Determine traveltime of peak: concentration between points of interest (table 4) <br /> <br />hours <br /> <br />Step 3 <br />Compute the traveltime of the leading edge of the hazardous material spill at points of interest <br />Traveltime of peak: concentration x 0.89 = hours <br /> <br />Step 4 <br />Determine the unit-concentration value (Cup) from table 5 <br /> <br />Step 5 <br />Compute the most probable peak concentration at downstream points of interest <br />0.016 x (Cup) x (Volume) / (ft3/s) = mg/L <br /> <br />Step 6 <br />Compute the traveltime of the trailing edge at downstream points of interest <br />555.6/ (Cup) = hours after arrival of the leading edge <br />