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released from the reservoir into the Strawberry River. As <br />part of the Central Utah Project, the reservoir was enlarged <br />in 1973 to a capacity of 1.1 million acre-ft (table 2). <br />However, the remainder of the project has not been com- <br />pleted, and the reservoir had not been filled by 1983. <br />Vermillion Creek near Hiawatha, Colo. (site 35) <br />Vermillion Creek drains an arid, geologically diverse <br />area before emptying into the Green River in the northwest- <br />ern corner of Colorado. Site 35 (table 3, pl. 1) has about <br />one-third the streamflow of Vermillion Creek near its mouth, <br />but the dissolved-solids concentrations are similar. Stream- <br />flow at site 35 is characterized by a small snowmelt-runoff <br />peak, occasional flash floods, and minimal or no flow dur- <br />ing the remainder of the year. Mean annual flow-weighted <br />dissolved-solids concentration averages 921 mg/L (table 7). <br />Sodium and sulfate are the predominant ions. Concentration <br />and chemical composition do not vary greatly throughout the <br />year. <br />Yampa River below diversion, near Hayden, Colo. (site 36) <br />Streamflow at site 36 (table 3, pl. 1) averages about <br />700,000 acre-ft/yr (table 7) and primarily is composed of <br />snowmelt runoff that has minimal dissolved solids. The mean <br />annual flow-weighted dissolved-solids concentration is 90 <br />mg/L. Calcium and bicarbonate are the predominant ions <br />throughout the year. Water from the Elk River, which drains <br />the virtually insoluble Precambrian rocks of the Park Range, <br />dilutes the dissolved-solids concentration of the Yampa River <br />upstream from Hayden, Colo. <br />Wilson Creek near Axial, Colo. (site 37) <br />Wilson Creek is a tributary to Milk Creek and drains <br />a small area underlain principally by the Williams Fork For- <br />mation. The streamflow hydrograph for site 37 (table 3, pl. <br />1) is characterized by a sharp snowmelt-runoff peak in mid- <br />May that is unaffected by reservoirs or diversions (fig. 18A). <br />Although the total runoff from the drainage basin is small, <br />base flow is rather constant. The mean annual flow-weighted <br />dissolved-solids concentration is 787 mg/L (table 7), pre- <br />dominantly as magnesium and sulfate. The proportions of <br />dissolved sodium and chloride are larger than in the main- <br />stem waters of the Yampa River at site 36. During the high- <br />flow season, the concentrations of magnesium, calcium, <br />sodium, bicarbonate, and sulfate are approximately equal. <br />The proportions of sodium, sulfate, and, notably, magnesium <br />increase during the low-flow season. Brine disposal from oil- <br />drilling operations in the upper part of the drainage basin <br />may have contributed substantial quantities of dissolved solids <br />to the stream (Turk and Parker, 1982). <br />Yampa River near Maybell, Colo. (site 38) <br />The mean annual streamflow of the Yampa River at <br />site 38 (table 3, pl. 1) exceeds 1 million acre-ft/yr (table 7). <br />A large snowmelt-runoff peak occurs during May and June, <br />followed by a long period of steady base flow (fig. 18B). <br />Compared to the Yampa River at site 36, streamflow is 54 <br />percent larger and mean annual dissolved-solids load is 162 <br />percent larger, the increase principally being dissolved <br />sulfate, bicarbonate, and calcium. The mean annual flow- <br />weighted dissolved-solids concentration is 152 mg/L (table <br />7). Calcium and bicarbonate are the predominant ions dur- <br />ing the high-flow season, and calcium, sodium, and bicar- <br />bonate predominate during the low-flow season. <br />For 1951-83, annual monotonic-trend analyses indi- <br />cated highly significant increases in median annual dissolved- <br />solids concentration of 0.9 mg/L per year and in median <br />annual flow-adjusted concentration of 1.2 mg/L per year. <br />Trends indicated a significant increase in median annual <br />dissolved-solids load of 3,380 tons/yr (table 8). These in- <br />creases represent a 21-percent change in median annual <br />dissolved-solids concentration, a 29-percent change in flow- <br />adjusted concentration, and a 65-percent change in dissolved- <br />solids load during the 33-year period of record. Highly <br />significant increasing trends were determined for annual <br />flow-adjusted concentrations of magnesium, sodium, and <br />sulfate. Flow-adjusted concentration increased significantly <br />during all months except April and August. <br />Iorns and others (1965) reported that although contribu- <br />tions from rocks of Cretaceous and Tertiary age in the Yampa <br />River basin had large proportions of dissolved magnesium, <br />sodium, and sulfate, the dissolved-solids concentration of the <br />river increased only moderately because the volume of runoff <br />was small. These same constituents have increased flow- <br />adjusted concentrations for site 38. The major land-use <br />change in the Yampa River basin has been the expansion of <br />coal-resource development since the early 1960's (Steele and <br />others, 1979). Both gypsum, a sulfate mineral, and pyrite, <br />which produces sulfate during oxidation, occur in the spoils <br />of surface-mined coal. Turk and Parker (1982) reported that <br />a principal effect of coal mining may be an increase ip the <br />relative concentration of dissolved sulfate in surface water. <br />Increases in dissolved-solids and dissolved-sulfate concen- <br />trations at site, 38 are moderately small, but they are signifi- <br />cant. The proportion of dissolved sulfate increased from <br />about 24 to 36 percent during 1951-83. The increase may <br />have been caused by leaching of soluble minerals from spoils <br />and disturbed lands. McWhorter and others (1975) reported <br />that the dissolved-solids load from spoils at the Edna Mine <br />in Colorado was 10 times greater than that produced upstream <br />along Trout Creek. Runoff from spoils in the Yampa River <br />basin produces three to six times the runoff from undisturbed <br />land, and springs have been observed at the toe of spoils, <br />changing intermittent streams into perennial streams. A <br />typical spoils pile may yield annually 3 to 5 inches of runoff <br />having a dissolved-solids concentration of 1,500 to 2,500 <br />mg/L (R.S. Williams, U.S. Geological Survey, oral com- <br />mun., 1985). Warner (in Steele and Hillier, 1981) reported <br />that leachate from spoils could produce a slow spread of <br />degraded ground water throughout a period of decades. <br />Middle Green Subregion 41