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LAKE WATER-QUALITY DATA <br />Water-quality samples were collected from <br />Vallecito Reservoir for analysis of selected metals, <br />bacteria, nutrients, alld field parameters. Field <br />parameters were measured by the volunteers in <br />profiles of lake depth using aHydro-Lab Surveyor 4 <br />with multi-parameter Data Sonde. Before each day <br />of field work, the instrument and data sonde were <br />calibrated using fresh calibration standards obtained <br />form the USGS. Depth of the sonde in the lake was <br />determined using a transducer in the data sonde. <br />Lake profiles for specific conductance aild dissolved <br />oxygen are shown in Figures 11 and 12. Selected <br />historical lake-profile data are shown for comparison. <br />Samples were al~alyzed for total iron, total <br />manganese, dissolved anunonia, and dissolved <br />nitrate. Sammples for total iron aid manganese were <br />acidified after collection, alld the samples were <br />digested before analysis. Digestion consisted of <br />adding 2.5 mLs of concentrated nitric acid to 25 mL,s <br />of sample (10 percent acid), then heating the sample <br />to 160°F using a microwave oven (EPA Method <br />3015). Digested, or total recoverable, samples were <br />then filtered and the samples brought between pH 3 <br />a«d 5 using sodium hydroxide before analysis. Iron, <br />manganese, ammonia, aild nitrate analyses were <br />analyzed by spectrophotometiy. Sample results are <br />shown in Table 2, a«d graphs of water-quality data <br />for the lake are shown in Figure 13. <br />Bacteria samples were collected for analysis of <br />total coliform a11d E. coli (Eschericlua coli) from <br />Vallecito Lalce. Samples were collected at site DS-1, <br />Pine River inflow, Vallecito Creek inflow, and <br />Graham Creek inflow Samples were collected on <br />July 13, August 23, and September 6, 2006. Bacteria <br />samples were analyzed by San Juan Basin Health. <br />The index method used on July 13 provided results <br />that indicated total coliform and E. coli were <br />"present" in the water samples. The results were <br />questioned by the volLU7teers. A request was made to <br />provide a more quantitative analysis. On August 23, <br />total coliform results were all greater than 2,419 <br />colones per 100 mLs; for the Pine River inflow site, <br />E. coli result of 4.1 colonies per 100 mL,s was <br />reported. On September 6, total coliform results <br />ranged from 178 to 344 colones per 100 mLs, and E. <br />coli results were all less than 1. <br />SUMMARY <br />The spring of 2006 was a relatively dry period, <br />and very few precipitation events occurred between <br />April and June; therefore, soil moisture conditions <br />were dry in the study area. Rainfall events bega« to <br />occur on a regular basis by early July, but the dry <br />soils soaked up most of the rain. Despite several <br />substantial rain storms, the volunteer stream gaging <br />data do not indicate that high flow events occurred. <br />This would at first appear to indicate that there has <br />been forest and vegetation recovery in the buried <br />areas. However, due to the flashy nature of rainfall <br />runoff in mountain strean~s, several of the high flow <br />events were missed by the volunteers. The crest- <br />stage gages indicated that increased streamflow <br />events did occur, but the dates and times are <br />uncertain. The data collected as part of this study, <br />therefore, do not indicate that floods or high-flow <br />events will not occur in the future. Given saturated <br />soil conditions, the flood potential could be entirely <br />different. The Vallecito Creek valley remains the <br />most vuh~erable for floods. <br />Water-quality samples from streams draining <br />the burned area reveal varying iron and manganese <br />concentrations in rainfall runoff. The site called <br />"2100 CR500 Creek" represents a backgroLU~d site. <br />High iron and manganese concentrations were <br />exhibited in water from Grimes Creek and Lost <br />Creek (which is a tributary to Grimes). Total <br />mercury concentrations of 27 and 53 ng/L <br />(nanograms per liter, or parts per trillion) were <br />reported i11 turbid rainfall nuloff samples from <br />Grimes Creek. Since iron, manganese, and mercury <br />are problems in Vallecito Reservoir, the burned areas <br />in Grimes Creek and Lost Creek need to be explored <br />for reclamation potential. <br />Water quality conditions in Vallecito Lake <br />appear to be fluctuating somewhat after the fire. <br />During 2005, there were high manganese <br />concentrations in the reservoir, ranging from 1,750 to <br />1,910 µg/L (micrograms per liter, or parts per <br />million). During 2006, the manganese <br />concentrations were surprisingly low, ranging from 7 <br />to 114 µg/L. The total iron concentrations, however, <br />increased from 50 µg/L in 2005 to 500 µg/L during <br />2006. Iron and mai~gai~ese are, therefore, both of <br />concern ill the lake, aid these metals may play a role <br />in mercury availability for fish. Other metals not <br />a«alyzed are also probably entering the reservoir. <br />These metals may be accumulating iii the lake <br />sediments. <br />S ~.~, ~ s <br />