Laserfiche WebLink
<br />- 50 - <br /> <br />further diminish and the droplet would continue to grow. <br />by points to the right of the peak in curve 2. A droplet <br />its Kohler curve is said to be activated. Once a droplet <br />to form cloud droplets by condensation. <br /> <br />passing through sta~es represented <br />which has passed ov~r the peak in <br />is activated it can ,grow rapidly <br />I <br />I <br /> <br />l5 0.5 <br />~ 0.4 <br />0:: <br />::> <br />~i 0.3 <br />0:: <br />~ O. <br />::> <br />Ol <br /> <br />",~1 <br />>> <br />S~ <br />"'~ <br />0::::> <br />:>:: <br /> <br /> <br /> <br />Fig. 3: Variations of the relative humidity and <br />supersaturation of the air adjacent to droplets <br />of (1J pure water and solution containing the <br />following fixed masses of salt: (2J 10-19 kg of <br />NaCl. (3J 10-18 kg of NaCl. (4J 10-17 kg of <br />NaCl. (5J 10-19 kg of (NH4J2S04; and (6J 10-18 <br />kg of (NH4J2S04' (Adapted from 5.1. Rasool. <br />ed.. "Chemistry of the Lower Atmosphere." <br />Plenum Press. New York. 1973. p: 16.J. <br /> <br />0.01 <br /> <br />0.1 I <br />DROPLET RADIUS (pm) <br /> <br />10 <br /> <br />To specify CCN populations it is necessary to determine their spectrum. :the number of <br />particles activated as a function of applied supersaturation. This is done i~ a thermal dif- <br />fusion chamber. The principle is simple: two wet surfaces. often. but not al~ays horizontal. <br />are maintained at different temperatures. Temperature within the chamber varies linearly <br />with distance from the lower plate (Fig.4J. Water vapour is distributed thr04gh the chamber <br />by mixing and diffusion so that the density of water vapour molecules is uniform. Since the <br />pressure of the water vapour at any point in the chamber is related to temperature by the <br />ideal gas equation. the vapour pressure also varies linearly with distance from the lower <br />plate. The saturation vapour pressure. on the other hand. does not vary lineqrly with tem- <br />perature (Fig. 4b), Consequently. at any point in the chamber the air is slightly super- <br />saturated with respect to liquid water. By changing the temperature difference between the <br />two plates from about 2 to 7.50 C. with the lower plate held at 200 C. the mqximum super- <br />saturation in the chamber can be varied from about 0.2 to 2%. <br /> <br />/WETTED PLATE <br />(T."C ) <br /> <br /> <br />[:::~~~:::J <br /> <br />WETTED PLATE <br /> <br />(0) <br /> <br />IT,"C) <br /> <br /> <br /> <br />Fig. 4: (a) The thermal diffusidn chamber. <br />(b) Water vapour pressure in th~ chamber (---) <br />and the saturation vapour press~re (---J as a <br />function of the air temperature. (From Wallace <br />and Hobbs. 1977). <br /> <br />VAPOR (e. T) <br />PRESSURE IN " <br />CHAMBER " <br /> <br />>" <br /> <br />(e,.1;1 <br /> <br />15 <br />18 20 22 24 26 28 30 32 <br />TEMPERATURE (OCI <br /> <br />( b) <br /> <br />Figure 5 shows a schematic diagram of a static diffusion chamber which has an inner <br /> <br />. <br />