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<br />k' =kCv, <br />x x Y <br /> <br />(x-l , 2 , 3 . . . ) . <br /> <br /><3.2.5) <br /> <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br /> <br />34 <br /> <br />Differential rate expressions can be written for eaoh component of <br /> <br />the process. From eq. 3.2.1: <br /> <br />deN <br />n v <br />dt - -k1CNCy <br /> <br />~ nv a <br />dt - k1CNCy -k2CAE <br /> <br />~ a i v <br />dt - k2CAE -k3CIECV <br /> <br /><3.2.3) <br /> <br />~ i v <br />dt - kSCIECV <br /> <br />de <br />::I n v i v <br />dt - -klCNCy -kSCIECy <br /> <br />These form a system of related equations. Likewise, from eq. S.2.2 <br /> <br />deN n v <br />dt - -k..CNCV <br /> <br />dCDSD n v d <br />dt - k..CNCy -k5CDSD <br /> <br />~ d f v <br />dt · k5CDSD -k6CFDCy <br /> <br /><3.2.4) <br /> <br />~ f v <br />dt · k6CFDCV <br /> <br />dCy n v f v <br />dt - -k4CNCy -k6CFDCy <br /> <br />Two simplifications oan immediately be made. The concentration of water <br /> <br />vapor can be held constant, as it is in the experiments to be described <br /> <br />dCy <br />below, in which oase ~ · 0 and <br /> <br />Secondly, all exponents expressing reaction orders can be assumed to be <br /> <br />equal to one. There is no physioal reason why more than one nuoleus <br />