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<br />expression oan be given as, <br />=". ~. ZJU..:!:4Z.. kUla[Blb"'[Nln <br />dt dt dt dt <br /> <br />(3.1.2) <br /> <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br />I <br /> <br />III. THEORETICAL CONSIDERATIONS <br /> <br />3.1 PrinciDles of Chemioal Kinetic~ <br /> <br />The discipline of chemical kinetios is the study of the rates of <br /> <br />chemical reaotions and physical prooesses. A related study is the <br /> <br />deduction of the meohanism(s) of the reaction or prooess from the <br /> <br />observed rates. _,~~~~~~._~~Iletios differs from oth!~,"~,!.!lQJ'l!!.^,9f <br />physioal ohemistry in that it is an empirical study where observation~ <br />of the progress of a reaction throu&t1 t1JD~,~.@.JIl~5t". The discussion in <br /> <br />....~,......_H..'....,_"""""",..._...,...;..;."..~...._;....,. _ <br /> <br />this seotion is referenced in Espenson (1981). <br /> <br />Ilnetios begins with a knowledge of the reaotants and produots of a <br /> <br />chemical reaction or physioal prooess in the form of a chemical or <br /> <br />physical reaotion equation, <br />k <br />A + B + ... ---+ Y +Z + ... <br /> <br />U .1.1> <br /> <br />where letters denote chemical or physioal species and k is the empirical <br /> <br />reaction rate constant. From the chemical equation, a differential rate <br /> <br />where brackets denote concentrations and lower case letters represent <br /> <br />the empirical order of the reaction with respect to the oorresponding <br /> <br />reaotion species. <br /> <br />A oommon method of ohemical kinetics methodology is to observe the <br /> <br />reaction in a constant-volume, batch reactor where all reactant <br />