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Discussion <br />The following information is provided by the USGS, and may be considered as a draft <br />justification and Scope of Work for this project: <br />Numerous entities have expressed concerns about a wide range of water-quality issues in the <br />Arkansas River Basin in Colorado. In the Upper Arkansas River Basin, water-quality concerns <br />generally are residual metal contamination from historical mining practices, fish and biological <br />integrity issues, or concerns about potential affects associated with storage and movement of <br />water. In the Lower Arkansas River Basin, water-quality concerns are associated with awide- <br />variety of environmental stressors including point and non-point source contamination, <br />population growth, storm-water flows, and future changes in land and water use. <br />As population within the basin increases, demands on the limited water supplies also will <br />increase. Changes in water storage, water releases, and/or transfer of water within or outside of <br />the Arkansas River Basin are likely to occur to accommodate the growing population. These <br />changes in water use and reservoir operations have the potential to affect water quality within the <br />basin by affecting such things as the dilution of chemicals and sediment transport. In addition to <br />changes in water use, water quality within the basin can be affected by land-use changes <br />associated with urbanization and agricultural practices. Urbanization and agricultural practices <br />can increase contaminant loading to ground and surface waters and change ground-water recharge <br />and streamflow characteristics. <br />As the result of continuing water-quality concerns and recognition of the importance of <br />understanding potential affects of changes in land and water uses throughout the Arkansas River <br />Basin, the U.S. Geological Survey (USGS) has been asked by the Southeastern Colorado Water <br />Conservancy District to assess the 'state of knowledge' of water quality throughout the Arkansas <br />River Basin and develop a comprehensive basin-wide strategy to address multiple water-quality <br />concerns. To date this assessment indicates numerous existing data gaps. Additional data are <br />needed to adequately quantify various contaminant sources, as well as the physical, biochemical, <br />and geochemical processes that adversely affect water quality. <br />Rou hg samplin~lan/rationale: <br />- In the upper Basin, samples would be collected in a Lagragian manner (essentially sampling the <br />same water parcel as it flows through the upper basin. <br />- Between Canon City and Pueblo Reservoir, an important issue is to better understand the decay <br />rates and assimilation of nutrients and carbon. To assess this, again we would use a Lagragian <br />approach coupled with the use of auto samplers, and then sub-sample various aliquots of <br />individual samples, then analyze 'a flow-weighted sample' which would provide us an integrated <br />concentration over several hours. <br />- In the lower Basin, given all the diversions - it is very difficult to successfully collect a single <br />sample in a Lagragian manner that provides data that can be used to assess various processes and <br />sources that affect water quality. Frequently, instantaneous samples used to compute loads do not <br />provide a reasonable mass balance (can't balance inflows/outflows or loads even for conservative <br />constituents). Therefore, during irrigation season or when flows are highly variable, we would <br />plan to utilize several auto samplers that would collect about 8 samples per day for 3 days. We <br />would then sub-sample to obtain 3 daily flow-weighted samples. These data would then provide <br />the necessary data to identify the dominant sources/source areas and assess the physical, <br />biochemical and geochemical processes that occur and affect the water quality. <br />Rough methods and costs: <br />New continuous WQ stations -- probably 2 upstream from John Martin Reservoir, maybe 1 below <br />JMR <br />Temporary/interim stations -- about 65 surface water stations, and about 100 wells <br />2 <br />