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<br />1788 <br /> <br />Trace-element concentrations in the upper Arkansas River exhibit marked temporal variability due to the <br /> <br />. influence of streamiiow regime. The downstream, seasonal variability of trace-element concentrations in the upper <br /> <br />basin is described in terms of four distinct seasonal streamiiow regimes. The periods depicted include the follow- <br /> <br />ing: pre-snowmelt runoff (April), snowmelt runoff (May-June), post-snowmelt runoff (July-September), and low <br /> <br />flow (October-March). During the low-flow period, streamflow is relatively small and is maintained by natural <br /> <br />baseflow and reservoir releases. During pre-snowmelt runoff, streamflow begins to increase, as lower elevation <br /> <br />snowmelt commences and begins to flush the abandoned mines, mine dumps, and tailing piles of trace-element <br /> <br />enriched water. The volume of water that actually flows into the river from these sources during the pre-snowmelr <br /> <br />period is relatively small, but because flow in the river is also small, the impact on trace-element concentrations <br /> <br />can be very substantial. During snowmelt runoff, streamflow is at its annual maximum and increases substantially <br /> <br />in the downstream direction because of reservoir releases and tributary inflow. The post-snowmelt runoff period <br /> <br />includes the receding limb of the snowmelt runoffhydrograph in July and a period dominated by releases of stored <br /> <br />water from Twin Lakes Reservoir (plate 1) in August and September. Additionally, during the post-snowmelt run- <br /> <br />. off period, streamflow can increase substantia\Iy over short periods of time following intense rain storms. This def- <br /> <br /> <br />inition of seasonal streamflow regimes serves as a general guideline for the interpretation of seasonal trace-element <br /> <br />concentrations and is subject to some degree of variability due to year-to-year variability in weather conditions and <br /> <br />reservoir operations. <br /> <br />The primary cause of elevated trace-element concentrations in the upper Arkansas River is acidic, metal- <br /> <br />laden drainage from abandoned mines and mine tailings. The most substantial sources of mine drainage are <br /> <br />located in the Leadville area and include the Leadville Mine Drainage Tunnel (Li\<IDT) and the Yak Tunnel <br /> <br />(Moran and Wentz, 1974; Wentz, 1974; Bunting, 1989; Clements, 1991). Nonpoint sources ofrrace-element <br /> <br />enriched drainage in the upper basin are also substantial because of the wide distribution of mine tailings and <br /> <br />mine waste piles throughout the upper basin. The LMDT discharges to the East Fork of the Arkansas River . <br /> <br />upstream from Leadville (plate I) and the Yak Tunnel discharges to California Gulch near Malta (plate I). In the <br /> <br />. <br /> <br />spring of 1992, water-treatment plants were installed at both sites. This action coincided with-the last year 'Of data <br /> <br />collection for this study. Both plants utilize a Chemical-preciPitation'PfUr~~rrlRMl <br />Subject to Revision <br />pO ~OT QUOTE OR RElEAS;:: <br />;- ,;;rldmg Approval by Director, <br />. .' U.S. Geological Survey <br /> <br />18 <br />