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<br />2826 <br /> <br />Pipeline project was completed in June 1985. Water is <br />released through the Bessemer Ditch outlet during <br />the spring. summer, and fall. During the winter, <br />S!. Charles Mesa obtains its surface water by diverting <br />Arkansas River water downstream from the dam. <br /> <br />In general, at least since 1985, a volume of water <br />comparable to the amount of annual inflow has been <br />released annually from the reservoir outlet works, <br />However, a net increase in storage occurs from Novem- <br />ber to April of each year because of the Winter Water <br />Storage Program. Because of Pueblo Reservoir opera- <br />tion practices, the reservoir has a short residence time, <br />From 1985 through 1989, an average of 12 percent of <br />the reservoir contents was released each month during <br />November to April (the period of the Winter Water <br />Storage Program); an average of 52 percent of the res- <br />ervoir contents was released each month during May <br />and June (the major snowmelt-runoff period); an aver- <br />age of 47 percent of the reservoir contents was released <br />each month during July and August (the upper-basin <br />reservoir-release period and rainfall-runoff period); <br />and an average of 15 percent of the reservoir contents <br />was released each month during September and <br />October. <br /> <br />Water Quality of the Upper Arkansas River <br />Basin <br /> <br />A discussion of the physical and chemical condi- <br />tions of the Arkansas River upstream from Pueblo Res- <br />ervoir is necessary to fully understand the physical and <br />chemical characteristics of the reservoir, because the <br />Arkansas River has a dominant effect on the reservoir. <br />The chemical quality of the upper Arkansas River <br />Basin has been studied by the Federal Water Pollution <br />Control Administration (1968), Moran and Wentz <br />(1974), Wentz (1974), La Bounty and others (\975), <br />Miles (\ 977), Roline and Boehmke (1981), Crouch and <br />others (\ 984), Cain (1987), and Kimball and others <br />(1988). The reader is referred to these reports for a <br />detailed description of the historical water quality in <br />the upper Arkansas River Basin, The following discus- <br />sion is intended to provide an overview of the quality <br />of water in the upper basin and to provide a description <br />of the quality of water entering the reservoir. <br /> <br />The chemical quality of surface water in the <br />Arkansas River Basin is affected by runoff from snow- <br />melt and rainfall, lransmountain diversions, mine <br />drainage, wastewater-treatment-plant effluents, ground <br />water, and land and water use within the basin. Water <br />entering the basin near the headwaters of the Arkansas <br />River and its tributaries is derived mostly from snow- <br /> <br />melt and generally is suitable for most uses (Federal <br />Water Pollution Control Administration, 1968). <br />Dissolved-solids concentrations in the upper <br />reaches of the Arkansas River have been increased <br />by acid mine drainage in the basin headwaters <br />(Cain, 1987), Dilution by tributary inflows results in <br />decreasing dissolved-solids concentrations and specific <br />conductance between Leadville and Buena Vista. Dis- <br />solved solids and specific conductance increase down- <br />stream from Buena Vista because of: (I) dissolution of <br />sedimentary rock minerals, (2) irrigation return flows <br />and saline ground-water inflow, and (3) discharges <br />from wastewater-treatment plants. Dissolved solids <br />and specific conductance increased only slightly <br />between Buena Vista and Canon City (fig. 1), but dis- <br />solved solids increase substantially and specific <br />conductance almost doubles in the 20-mi reach down- <br />stream from Canon City, primarily as a result of saline <br />ground-water inflows and irrigation return flows <br />(Cain, 1987), <br />The limited amount of nutrient data available for <br />the upper Arkansas River Basin indicates that nitrogen <br />and phosphorus concentrations increase downstream <br />(Edelmann and others, 1991). Concentrations of total <br />nitrogen generally are less than I mgIL, and total- <br />phosphorus concentrations generally are less than <br />0.2 mgIL. <br />Acid mine drainage has resulted in relatively <br />large concentrations of cadmium, iron, lead, manga- <br />nese, nickel, and zinc in the upper Arkansas River and <br />is a major source of these constituents to Pueblo Reser- <br />voir (A.J. Medine, Water Science, Boulder, Colorado, <br />written commun., 1991), Weathering of sedimentary <br />rocks in the lower half of the basin seems to be another <br />major source of iron and manganese to the river and <br />reservoir. Chemical precipitation; sorption to iron and <br />aluminum oxides, organics, and clay minerals; sedi- <br />mentation; and dilution contribute to downstream <br />decreases in most dissolved-metal concentrations in the <br />upper Arkansas River. <br />The chemical quality of water entering Pueblo <br />Reservoir can be summarized by using data collected at <br />station 07097000, Arkansas River at Portland (table I). <br />The U.S. Geological Survey has been analyzing water- <br />quality samples collected at this station since 1977. <br />Daily measurements of water temperature and specific <br />conductance have been made since 1979. A summary <br />and discussion of water-quality data collected at this <br />station from 1977 through 1985 are provided in Edel- <br />mann (\ 988). <br />Strong seasonal variations in water temperature, <br />specific conductance, and dissolved-solids concentra- <br />tions occur in the Arkansas River. Mean daily water <br />temperature of the Arkansas River at Portland ranged <br /> <br />INTRODUCTION 7 <br />