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<br />Table 3.4. Characteristic analysis of detailed hydrosalinity models. <br /> <br />Reference <br />Ayars, J. E. <br />1976 <br /> <br />'" <br />w <br /> <br />Khan, 1. A, <br />and Labadie, <br />J. W., 1979 <br /> <br />Constituents <br />IIDdeled <br />ea+Z, Mg+Z <br />+ - <br />Na ,HCXl3 <br />-Z <br />Cl-, 004 <br />IDS <br /> <br />Individual <br />ions, TDS <br />and SAR of <br />the irriga- <br />ticm rerum <br />flews . <br /> <br />Major Assumptions <br />in salinity IIDdel <br /> <br />Soluble species nove freely <br />with soil segtlEIl.t. <br /> <br />Solute ccmcentrations are <br />constant for any soil segtlEIl.t. <br /> <br />Nitrogen transformations are <br />not considered (as it is not <br />a major pollutant in Grand. <br />Valley) . <br /> <br />Inorganic reactions are <br />based on equilibriun ch5Distry <br />since the reaction tines are <br />less than the residence time <br />of water in a soil segment. <br /> <br />Water flow and content are in- <br />dependent of any chemical <br />process. <br /> <br />Complete mixing occurs at <br />each increren.t in time and <br />space. <br /> <br />Each chemical process is in- <br />dependent of other processes <br />over a time step witll respect <br />to availability of component <br />masses. <br /> <br />Rate of change of mass for <br />each component is constant <br />over a time step. <br /> <br />Mixing cell concept is used <br />to calculate salt transport. <br />The length of cell remains <br />constant. <br /> <br />The tmSaturated zone nodel <br />assumes: (i) steady state <br />conditions, (ii) the pH of <br />the solution is governed by <br />the soil carbonate equili- <br />bria, (iii) soil lime is <br />present in sufficient quan- <br />tities to saturate soil <br />solution, (iv) =lete mixing <br />is assumed. <br /> <br />Temperature effects are not <br />considered. <br /> <br />Input data T:ime <br />requi.rerrents increIIHlt <br /> <br />Irrigation water Daily <br />chemical analysis. <br /> <br />Number, sizes and <br />dapth of chemistry <br />horizons in soil <br />profile. <br /> <br />Initial soil analy- <br />sis of each horizon. <br /> <br />Fertilization and <br />irrigation dates. <br /> <br />CEe, concentration <br />of gypsun in soil, <br />presence of lime. <br /> <br />Average ionic con- Annual <br />centration of irri- <br />gation water, soil- <br />water, and ground- <br />water. <br /> <br />O:Jmn2nts <br /> <br />TDS concentrations were <br />adequately IWdeled, but <br />the individual ionic <br />constituent concentra- <br />tions were not. <br /> <br />CaS04 - Ca003 - Ca(HC03)Z <br />system was not adequately <br />rrodeled for the soils in <br />the Grand Valley. <br /> <br />The rnanagerrent strategy <br />should be based on the <br />tacit assumption that <br />at least a portion of <br />available grotmdwater is <br />still usable for agri- <br />culture. <br /> <br />l~tE <br /> <br />Model <br />Application <br />Grand Valley, <br />Colorado <br /> <br />Lower San Luis <br />Rey River Basin, <br />Southern <br />California <br /> <br />