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<br />Co) <br />Co) <br />. <br />~ <br /> <br />processes. The representation of the hydrol- <br />ogy component varies substantially depending <br />upon the watershed studied and the desired <br />application. The state-of-the-art of <br />modeling soil-water systems is found in the <br />models outlined in Table 3.3 and described by <br />Oster and Rhoades (1975), <br /> <br />The hydrologic and chemical components <br />are normally modeled separately but inte- <br />gratedly, Huber et a1. (1976) describe <br />the Basin Simulation and Assessment Model <br />(BSAM), a generalized hydrologic model that <br />can be applied to any watershed and also <br />can be coupled to a suitable salinity 8ub- <br />model. As classified in Figure 3.1, the <br />complexity of solute flow models ranges from <br />simple applications of plate theory assuming <br />piston-flow movement of solute and water <br />(Tanji et a1. 1967), to detailed models <br />which attempt to represent the complex <br />chemical reactions within the soil profile by <br />use of both hydrodynamic dispersion and <br />diffusion principles. <br /> <br />Models integrating solute transport with <br />soil-water chemistry were initially pursued <br />by Tanji et a1. (1967), Thomas et a1. (1971), <br />Dutt et a1. (1972), and Narasimhan (1975). <br />Descriptions of specific characteristics of <br />some more recent and more refined models are <br />outlined in Table 3.4. <br /> <br />Models attempting to also integrate <br />groundwater flow came even later. The first <br />models (Konikov and Bredehoeft 1974) cons id- <br />ered reactions within the water but not <br />chemical reactions between the water and the <br />aquifer. As a result, they did not rigor- <br />ously define the relation of groundwater <br />salinity to overlying soil salinity. Helweg <br />and Labadie (1976) computed groundwater <br />salinity (represented by rDS) by meanS of a <br />regression equation using the electrical <br />conductivity (EC) of the soil water and <br />groundwater. Outlined in Table 3.5 are the <br />general characteristics of these groundwater <br />s al i ni ty mode Is. <br /> <br />Assumptions in <br />Salinity Modeling <br /> <br />Solute flow processes <br /> <br />Review of the models presented in Tables <br />3.2, 3.3, 3.4 and 3.5 indicated that solute <br />flow is generally modeled from a few basic <br />relationships. The principle of conservation <br />of mass was generally used, and steady state <br />condi t ions were commonly assumed. The only <br />exception is the model of Wi11ardson et a1. <br />(1979), which assumed transit state condi- <br />tions in modeling the water and solu~e flows. <br /> <br />Solute Flow MJdels of <br />Soil-Water System. <br /> <br />I <br /> <br />ChromatOgraJhic MJdels <br />(Plate Theory) <br />- Dutt (1962) <br />- Tanji (1967) <br /> <br />Discontinuous Plate MOdelsl/ <br />Vander MOden (1956) <br /> <br />Continuous Plate MOdels 2/ <br />Gardner & Brooks (1957) <br /> <br />I <br />Diffusion MOdels <br />(Miscible Displacement Theory) <br />Bresler & Hanks (1969) <br />Biggar & Nielsen (1962) <br /> <br />I <br />Soil-Ion Interaction3/ <br />Systems <br />Rhoades (1975) <br />Shaffer (1977) <br />Dutt (1972) <br />Narasman (1975) <br />Thomas (1971) <br /> <br />I <br />Nousoil-Ion Interaction4/ <br />MJdels <br />Terkeltaub (1971) <br />Hill (1973) <br /> <br />Note: 1. Solution remains in an affective plate of colunn 1.IDtil equilibrium with solid phase is obtained. <br />2, Based on rate theory and ionic equilibrium. <br />3. Equilibrium concentration of constitutent ions, ion pairs and cation exchange considered. <br />4. No chemical reactions are considered. <br /> <br />21 <br /> <br /> <br />Figure 3.1. Development categories of selected solute flow models of the soil-water system. <br />