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<br />w <br />w <br />w <br />w <br /> <br />the root zone, as a result of silicate <br />mineral weathering and dissolution of soil <br />lime (Rhoades et al. 1974). Depending on the <br />drainage of the soil-water system, the <br />above processes may redistribute the storage <br />of salts within the soil profile and develop, <br />over long periods of time, a high capacity <br />for Ilbuffering" salts. For soil types such <br />as those encountered in Vernal, Utah (King <br />and Hanks 1975 and Melamed 1975), a charac- <br />teristic soil solution concentration profile <br />emerged. A unique salt concentration devel- <br />oped at each position in the soil profile, <br />and it remained nearly unchanged as waters of <br />various concentrations passed through. <br /> <br />Salt balance studies based on outdoor <br />experiments with lysimeters (Rhoades et aI. <br />1973 and 1974) indicated that, depending on <br />the LF, there could be either a net gain of <br />salts (by dissolution), and a net loss of <br />salts (by precipitation). Both calcarious <br />(with 1% GaG03) and noncalcarious Pachappa <br />sandy loam soils were investigated (Figures <br />2.1 through 2.4). The fact that these lines <br />representing drainage water salinity tend <br />to become horizontal with large leaching <br />fractions suggests that for these soils a <br />threshold leaching fraction (LFT) could be <br />identified beyond which there is neither a <br />net gain nor a net loss of salt relative to <br />the applied water. The estimated drainage <br />water composition, "Threshold Salt Concentra- <br />tion" erSe), corresponding to the LFT for <br />several irrigation waters is shown in Table <br />2.2. Since the data represent tile drain <br />water or the drainage waters as they emerge <br />from the root zone, the above estimates of <br />ECT values correspond to the concentration <br /> <br />of the soil-solution at the bottom of the <br />root zone. The estimated values of TSC for <br />noncalcarious (without lime) soils are <br />higher than the corresponding TSC values for <br />calcarious soils. <br /> <br />TSC values are highly site specific <br />and depend on the quality of irrigation <br />water, soil type, and the leaching status of <br />the soil at the time of determination. For <br />example, soils recently brought into irriga- <br />tion may have a higher TSC than do soils <br />irrigated for many years. Field experiments <br />of the type described in Rhoades et al. <br />(1973) provide in situ TSC for the usual soil <br />types encountered in most parts of the <br />western states where the soils provide <br />a buffering capacity with respect to CaC03. <br />Further investigations are necessary to <br />extend this concept to other soils. Never- <br />theless, the TSC concept is useful for <br />deriving a simple but reasonably reliable <br />hydrosalinity model as described in a <br />subsequent chapter. <br /> <br />Spatial and temporal variability of <br />drainage water concentratIons. Observed <br />salinity concentrations in drainage waters <br />from various irrigated areas change with <br />the time and location of individual drains. <br />The results of a number of research projects <br />shed light on these patterns. <br /> <br />1. The eight studies of drainage water <br />salinity concentrations reported in Table 2.3 <br />indicate that concentrations remained similar <br />throughout the year, suggesting that salt <br />outflow was proportional to the corresponding <br />water flow. Those observations appear, <br /> <br />Table 2.2. Estimated threshold salt concentrations (TSC) for Pachappa sandy loam. <br />Figures 2.1, 2,2. 2,3, and 2.4.) <br /> <br />River type <br /> <br />Estimated LF at which <br />no salt precipitation <br />or dissolution occurred <br /> <br />1 Feather <br />2 Grand <br /> <br />0.285 <br /> <br />3 Missouri <br /> <br />0,17 <br />0,185 <br />0,185 <br />0,145 <br />0,235 <br />0.225 <br /> <br />4 Salt <br /> <br />5 Colorado <br /> <br />6 Sevier <br />7 Gila <br /> <br />0.230 <br />0.235 <br /> <br />8 Pecos <br /> <br />(Based on <br /> <br />Estimated Threshold Salt Concentration, TSC (mnhos/cm) <br /> <br />calcarious lysimeters <br />(with 1% eaQ)3) <br /> <br />noncalcarious lysimeters <br /> <br />2,75 <br /> <br />3.75 <br /> <br />4.25 <br /> <br />7.2 <br /> <br />10.5 <br /> <br />4.25 <br /> <br />4.10 <br /> <br />11.75 <br /> <br />12.25 <br /> <br />5 <br /> <br />, <br /> <br />