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<br />Graf <br /> <br />TABLE 2. Statistics of the Time-Concentration Curves, Glen Canyon Reach, 1989 and 1991. <br />[Average velocity WBI!l computed all velocity of the centroid of the time-concentration curve.] <br /> <br />D10tance <br />From <br />Injection <br />(kiIometero) <br /> <br />Discharge <br />(cubic <br />meters per <br />lI8Oond) <br /> <br />M8.][imum <br />Concentration <br />(micrograDUI <br />per liter) <br /> <br />Time After Injection <br />(bouro) <br />Peak Centroid <br /> <br />Time <br />Variance <br />(bouro <br />oquored) <br /> <br />Average <br />Velocity <br />Coefficient (meter. <br />of Skew per oecornl) <br /> <br />Measurement, 1989 <br /> <br />61.2 1.12 1.35 0.115 1.238 <br />5.78 20.2 21.8 10.4 1.225 0.33 <br />Steady-Flow Measurement, 1991 <br />2.27 9.70 9.84 1.34 .450 .72 <br />Unsteady-Flow Measurement, 1991 <br />1.98 6.60 7.07 0.708 .560 1.0 <br /> <br />1.5 <br />25.9 <br /> <br />144 <br />139 <br /> <br />25.6 <br /> <br />425 <br /> <br />25.6 <br /> <br />651 <br /> <br />Steady and Unsteady Flow, Grand Canyon <br />Reach. The time-concentration curVes generated <br />from samples collected at steady flow are atypical in <br />that although the curves have a slight positive skew, <br />they do not have the long tails typical of natural <br />streams (Figure 4 and Table 3). The time-concentra- <br />tion curves for unsteady flow are similar to those for <br />steady flow in that they do not have long tails, but the <br />shapes of curve8 at individual sites are strongly influ- <br />enced by discharge changes in the reach as the dye <br />passed (Figures 2 and 5). For example, dye curves for <br />sites at which the dye passed during decreasing flow <br />are positively skewed, whereas dye curves for sites <br />where the dye passed on increasing flow are negative- <br />ly skewed (Figure 2 and Table 3). The dye curve at the <br />site above the Little Colorado River, where the dye <br />passed on the trough of the daily hydrograph, is near- <br />ly symmetrical. <br />For the steady-flow measurement, velocity varied <br />slightly from subreach to subreach (Table 3). The low- <br />est velocity (0.75 m/s) was measured in the subreach <br />between Nautiloid Canyon and the sample site above <br />Little Colorado River - the Lower Marble Canyon <br />reach (Schmidt and Graf, 1990, Table 2, p. 55). The <br />highest velocity (1.1 mls) was measured between the <br />site above the Little Colorado River and the site below <br />Nevill's Rapid (Furnace Flats reach) and the two sub- <br />reaches between Mile 118 Camp and Pumpkin <br />Springs (Middle Granite and Muav Gorges). Velocity <br />is not significantly correlated with any of the channel <br />geometry characteristics given in Table 1. Poor corre- <br />lation of velocity with slope and channel geometry <br />probably is caused by the inadequate characterization <br />of the channel by the 199 measured cross sections. <br />Velocity of flow in individual subreaches during <br />unsteady flow ranged from 0.61 mls in the Lower <br /> <br />WATER RESOURCES BULLETIN <br /> <br />Marble Canyon reach to 1.3 m/s in the subreach <br />between the site below Nevill's Rapid and the site at <br />Mile 118 Camp (Granite Gorge). For unsteady flow, <br />differences in velocity through individual subreaches <br />were more strongly influenced by discharge in the <br />reach as the dye passed than by the geometry of the <br />subreach. Velocity was highest in the subreaches in <br />which the dye cloud traveled near the peak discharge <br />of the daily hydrograph - from Lees Ferry to Nau- <br />tiloid Canyon, below Nevill's Rapid to Mile 118 Camp, <br />and National Canyon to Gneiss Canyon (Figure 2 and <br />Table 3). The lowest velocity was measured in the <br />reach between Nautiloid Canyon and the Little Col- <br />orado River, a reach where the dye cloud traveled <br />with the trough of the daily hydrograph (Figure 2 and <br />Table 3). <br />Traveltime of the dye-cloud centroid increased lin- <br />early with distance traveled for both steady and <br />unsteady flow. Although average velocity varied from <br />subreach to subreach during both measurements, <br />velocity differences were not great enough to signifi- <br />cantly affect the linear traveltime-distance relation <br />(Figure 6). Traveltime was slightly less during <br />unsteady flow than during steady flow, but average <br />velocity in the entire measured reach was not signifi- <br />cantly different - 0.98 m/s for steady flow and 1.0 mls <br />for unsteady flow. <br />Downstream changes in peak concentration and <br />dye-cloud variance and duration are all measures of <br />the longitudinal dispersion. For steady flow, peak con- <br />centration decreased as the square root of traveltime. <br />Peak concentration was 12.5 J.lg/l at the first sampling <br />site, 57.7 km downstream from the injection, and 5.3 <br />J.lg/l at the last site, 380 km from the injection (Figure <br />7). Nonlinear regression was used to relate the peak <br /> <br />272 <br />