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WSP10774
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Last modified
1/26/2010 3:14:39 PM
Creation date
10/12/2006 4:31:48 AM
Metadata
Fields
Template:
Water Supply Protection
File Number
8271.200
Description
Colorado River Basin Salinity Control Program - Development and History - UCRB 13a Assessment
Basin
Colorado Mainstem
Water Division
5
Date
1/1/1979
Title
Costs of Wastewater Disposal in Coal Gasification and Oil Shale Processing
Water Supply Pro - Doc Type
Report/Study
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<br />with Occidenta13. We snall fureher ass~e that afte= trea~~ent the water <br /> <br />\-.. , <br />en quality level is consistent with that of Table 4-5, with the possible <br /> <br />~ exception or organics contamination. It may be ~oted that no val~e has been <br />00 <br /> <br />specified for the organic contaminants in the mine water because there is <br /> <br />sL~ply no way or knowing at ~~is time what they migh~ be. <br /> <br />For the relatively low TOS mine water with fluoride contami~at~on, ~~o <br /> <br />processes prevent themselves as t~e most appropriate :or obtaining a high <br /> <br />. 11 12 <br />purity product: electrodialysis and reverse osmos~s ' . However, electro- <br /> <br />dialysis will only separate those molecules which are in ionic fo~ in solution. <br /> <br />Boron, for exanple, :equires that t~e solution ~H be about 8.5 to 9 to become <br /> <br />ionic. <br /> <br />In ge~eral elec~rodialysis also does not have a capabili~y for se?ara~ing <br /> <br />soluble organic molecules. Reverse osmosis. on t~e other ~and, has a wocerat: <br /> <br />capability :or separating soluble orgar.ic ~olecuIes, ~ut a veri poor ca~abilit: <br /> <br />for se?d.!"ating boron frcm acidic waters~ It is onl'l at a quite high ~:i (~.. 9.3-10) <br /> <br />that a 75\ rejection of boron is attained. Fluoride rejection is typically <br /> <br />about 90~. Bot~ of the processes :equire a ~oderate to gOOG level ~: <br /> <br />prefil:ration to :emove suspended solids whic~ will be conCained in ~~e ~ine <br /> <br />~aeer. The mine water is aL<aline ~~d electrodialysis ~ould requi~e pret:eat- <br /> <br />me~t with sul=uric acid to prevent scali~q on ~~e ~embranes. Acid aceitio~ or <br />chelating 3gents wauIe also ~e re~~ired :or ~e reverse osmosis system to <br />prevent precipitation of salts~ We emphasize ~~at ~oth of ehe systems wculd <br />pr~vide a product wit~ a lowe~ toeal dissolved solids t~an recui:~d :0: <br />=isc~arge. As a rule, reverse osmosis would gi~e ~~e lowest T~S product wi~~ <br />a t~~ical value for ~~e mine water considered of =~om 100-200 wg/l, while ~~e <br />electro~ialysis produc~ mi~ht range frcm 200-400 rngjl. T~e5e values are <br /> <br />illustrative only and are controlled by ~~e system economics. <br /> <br />If total <br /> <br />dissolved solids content were ~~e only dischar~e requirement to be met, then <br />a sig~ificant reduction in tredtment cost could be achieved by treating only <br />part of tne water anc blending it with ~~treated water =rom which only ~he <br /> <br />suspended solids ha'le been re~oved. <br /> <br />However, for the contaminar.t levels <br /> <br />shawn in Table 4-6, it is not likely that ~~e discharge limi~s s?ecified i~ <br /> <br />Table 4-5 could be met Nith blending. Of course, sgecific ?ollutan~ =e~aval <br /> <br />might still be practiced whi~h ~culd enable blending. This decision is also <br /> <br />an economic one. <br /> <br />9~, <br />
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