<br />B36
<br />
<br />DROUGHT IN THE SOUTHWEST, 1942-56
<br />
<br />year mean during the recent drought do represent devi-
<br />ations of about the same order below the mean for the
<br />154-year period.
<br />Six of the nine tree-ring indices in table 7 cover
<br />periods beginning prior to 1800 (column 12), Column
<br />14 shows the ratio of the mean of tree-ring indices for
<br />the bllBe period 1904-53 to the mean for periods that
<br />range from 305 to 855 years. To the extent that tree
<br />rings reflect runoff, this is the ratio of mean runoff :for
<br />the period 1904-53 to that for the 305- to 855- year pe-
<br />riods, For all the regions, except the headwaters of
<br />the Gila River, the ratios are within 1 percent of those
<br />given in colnmn 11 for a 154-year period; this small
<br />difference suggests that it matters but little whether the
<br />mean runoff for 1904-53 is compared to the mean for
<br />154 years or for longer periods,
<br />
<br />QUALITY OF WATER
<br />
<br />By L. R. KISTER
<br />
<br />Wherever "water" has been mentioned heretofore in
<br />this report, the common usage of the word has been in-
<br />tended: something wet and, in fact, the most abundant
<br />of wet substances, In discussing the processes of the
<br />hydrolog-ic cycle (1" Bl) "water" includes rainwater,
<br />river water, soil water, lake water, wel! water, spring
<br />water, and even sea water. Now, however, we want to
<br />emphasize the great variety that is embraced by the all-
<br />inclusive term "water," and to discriminate waters on
<br />the basis of their physical and chemieal qualities,
<br />To the chemist, water is the chemical compound H,O,
<br />Long ago, when the chemistry of water was considered
<br />to be relatively simple, it was recognized that pure H20
<br />is not found in nature but must be obtained by such
<br />processes as artificial distillation. However, as pointed
<br />out recently by Buswell and Rodebush (1956), the for-
<br />mula of water is not simply H20, and water is not a
<br />single substance, The purest water that can be pre-
<br />pared in the laboratory contains three isotopes of hy-
<br />drogen and three of oxygen, which can be combined in
<br />18 different ways, With the various kinds of ions that
<br />can be formed from water's atoms, pure water contains
<br />no fewer than 33 substances. Thus the formula H20
<br />for pure water is a group designation,
<br />Natural waters are solutions, suspensions, and mix-
<br />tures of a great variety of chemical compounds and ele-
<br />ments in H20, Water in each phase of the hydrologic
<br />cycle is likely to contain measurable amounts of such
<br />impurities. Even the water precipitated as rain, snow,
<br />fog, frost, or dew commonly contains soluble and sus-
<br />pended substances, Analyses show greater concentra-
<br />tions of chloride in coastal than in inland areas; so at
<br />least part of these soluble substances evidently come
<br />from the oceans. In interior areas of the Southwest,
<br />
<br />torrential storms wash significant quantities of dust
<br />and soluble salts from the atmosphere-materials that
<br />were picked up from the land by wind prior to the
<br />storm.
<br />Surface water and ground water may be only slightly
<br />more mineralized, or they may be far more mineral-
<br />ized, than the precipitation from which they were de-
<br />rived, Wherever we find these waters, their quality is
<br />a product of the environment through which the water
<br />has passed since it fell as rain or snow, BecaUSe en-
<br />vironmental changes over the years are relatively slight,
<br />it is likely that the variations in quality of water at any
<br />specific point will be less than the great variations that
<br />are noted in waters from different geographic locations.
<br />Generally we assume a fair degree of uniformity in the
<br />quality of water from any individual well or spring,
<br />Although the range in quality of surface waters is
<br />greater, the water in some streams is characteristically
<br />clear; in others it is muddy; in some it is relatively
<br />pure; and in others it is charged with mineral matter,
<br />Nevertheless, there is abundant evidence of signifi-
<br />cant changes with time in the quality of water from
<br />specific sources, The quality of water in a flowing
<br />stream changes as the discharge chrnges, During pe-
<br />riods of low discharge, most stream waters are more
<br />mineralized than when flood flows occur, The quality
<br />of water in lakes rnd reservoirs changes in response to
<br />changes in quality of the inflow and also to the effect
<br />of evaporation from the reservoir, The quality of wa-
<br />ter from some wells and springs also has chrnged with
<br />time; many of these changes have been traced to the
<br />effects of increllBing development and use of ground
<br />water, but some are clearly the result of fluctuations in
<br />the rate of natural recharge.
<br />If changes in quality result from changes in quantity
<br />of surface water, as indicated previously, climatic fluc-
<br />tuations must affect the quality as well as the quantity
<br />of water, Thus drought affects directly the quality of
<br />water in streams and lakes and also in some ground-
<br />water reservoirs. Drought may also have indirect ef-
<br />fects upon the quality of both surface and ground wa-
<br />ters by changing the environment through which the
<br />water moves, In any specific environment, when there
<br />is less water to carry sediment or soluble mineral mat-
<br />ter, the total amount of sediment or soluble matter car-
<br />ried must be less; and as tributaries or springs cease
<br />flowing, their contributions of mineral matter to major
<br />streams must be nil. On the other hand, the concentra-
<br />tion of mineral matter in streams may increase greatly
<br />as the volume of water is reduced. Thus the general
<br />effect of drought would be to increase the proportion
<br />of impurities in water, and yet reduce the total qurntity
<br />of those impurities, because of the reduced quantity of
<br />water.
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