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<br />B36 <br /> <br />DROUGHT IN THE SOUTHWEST, 1942-56 <br /> <br />year mean during the recent drought do represent devi- <br />ations of about the same order below the mean for the <br />154-year period. <br />Six of the nine tree-ring indices in table 7 cover <br />periods beginning prior to 1800 (column 12), Column <br />14 shows the ratio of the mean of tree-ring indices for <br />the bllBe period 1904-53 to the mean for periods that <br />range from 305 to 855 years. To the extent that tree <br />rings reflect runoff, this is the ratio of mean runoff :for <br />the period 1904-53 to that for the 305- to 855- year pe- <br />riods, For all the regions, except the headwaters of <br />the Gila River, the ratios are within 1 percent of those <br />given in colnmn 11 for a 154-year period; this small <br />difference suggests that it matters but little whether the <br />mean runoff for 1904-53 is compared to the mean for <br />154 years or for longer periods, <br /> <br />QUALITY OF WATER <br /> <br />By L. R. KISTER <br /> <br />Wherever "water" has been mentioned heretofore in <br />this report, the common usage of the word has been in- <br />tended: something wet and, in fact, the most abundant <br />of wet substances, In discussing the processes of the <br />hydrolog-ic cycle (1" Bl) "water" includes rainwater, <br />river water, soil water, lake water, wel! water, spring <br />water, and even sea water. Now, however, we want to <br />emphasize the great variety that is embraced by the all- <br />inclusive term "water," and to discriminate waters on <br />the basis of their physical and chemieal qualities, <br />To the chemist, water is the chemical compound H,O, <br />Long ago, when the chemistry of water was considered <br />to be relatively simple, it was recognized that pure H20 <br />is not found in nature but must be obtained by such <br />processes as artificial distillation. However, as pointed <br />out recently by Buswell and Rodebush (1956), the for- <br />mula of water is not simply H20, and water is not a <br />single substance, The purest water that can be pre- <br />pared in the laboratory contains three isotopes of hy- <br />drogen and three of oxygen, which can be combined in <br />18 different ways, With the various kinds of ions that <br />can be formed from water's atoms, pure water contains <br />no fewer than 33 substances. Thus the formula H20 <br />for pure water is a group designation, <br />Natural waters are solutions, suspensions, and mix- <br />tures of a great variety of chemical compounds and ele- <br />ments in H20, Water in each phase of the hydrologic <br />cycle is likely to contain measurable amounts of such <br />impurities. Even the water precipitated as rain, snow, <br />fog, frost, or dew commonly contains soluble and sus- <br />pended substances, Analyses show greater concentra- <br />tions of chloride in coastal than in inland areas; so at <br />least part of these soluble substances evidently come <br />from the oceans. In interior areas of the Southwest, <br /> <br />torrential storms wash significant quantities of dust <br />and soluble salts from the atmosphere-materials that <br />were picked up from the land by wind prior to the <br />storm. <br />Surface water and ground water may be only slightly <br />more mineralized, or they may be far more mineral- <br />ized, than the precipitation from which they were de- <br />rived, Wherever we find these waters, their quality is <br />a product of the environment through which the water <br />has passed since it fell as rain or snow, BecaUSe en- <br />vironmental changes over the years are relatively slight, <br />it is likely that the variations in quality of water at any <br />specific point will be less than the great variations that <br />are noted in waters from different geographic locations. <br />Generally we assume a fair degree of uniformity in the <br />quality of water from any individual well or spring, <br />Although the range in quality of surface waters is <br />greater, the water in some streams is characteristically <br />clear; in others it is muddy; in some it is relatively <br />pure; and in others it is charged with mineral matter, <br />Nevertheless, there is abundant evidence of signifi- <br />cant changes with time in the quality of water from <br />specific sources, The quality of water in a flowing <br />stream changes as the discharge chrnges, During pe- <br />riods of low discharge, most stream waters are more <br />mineralized than when flood flows occur, The quality <br />of water in lakes rnd reservoirs changes in response to <br />changes in quality of the inflow and also to the effect <br />of evaporation from the reservoir, The quality of wa- <br />ter from some wells and springs also has chrnged with <br />time; many of these changes have been traced to the <br />effects of increllBing development and use of ground <br />water, but some are clearly the result of fluctuations in <br />the rate of natural recharge. <br />If changes in quality result from changes in quantity <br />of surface water, as indicated previously, climatic fluc- <br />tuations must affect the quality as well as the quantity <br />of water, Thus drought affects directly the quality of <br />water in streams and lakes and also in some ground- <br />water reservoirs. Drought may also have indirect ef- <br />fects upon the quality of both surface and ground wa- <br />ters by changing the environment through which the <br />water moves, In any specific environment, when there <br />is less water to carry sediment or soluble mineral mat- <br />ter, the total amount of sediment or soluble matter car- <br />ried must be less; and as tributaries or springs cease <br />flowing, their contributions of mineral matter to major <br />streams must be nil. On the other hand, the concentra- <br />tion of mineral matter in streams may increase greatly <br />as the volume of water is reduced. Thus the general <br />effect of drought would be to increase the proportion <br />of impurities in water, and yet reduce the total qurntity <br />of those impurities, because of the reduced quantity of <br />water. <br />